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Imprimatur:Date, Signaturetc1719ss.fmReviews and Full Papersin Chemical SynthesisSynthesis 2019, 51, 3171–3204DOI: 10.1055/s-0037-16118222019Vol. 51, No. 17September ITransition Metal-Catalyzed Directed C(sp3)–H Functionalization ofSaturated HeterocyclesD. AntermiteJ. A. Bull*Directed C-HActivationImperial College London, UKFGDGFGDGnX[M]HXX NR, O, STransition MetalCatalystDGnDGFG[M] iateAcOAcOFGODGFGDGFGDGFG acyl, alkyl, (hetero)aryl, alkenyl, alkynyl,-F, -NR, -ORSyn thesisSynthesis 2019, 51, 3205–3213DOI: 10.1055/s-0039-1689917W. Erb*T. RoisnelV. DorcetUniv Rennes, FranceNNRPractical Chromatography-Free Synthesis of 2-Iodo-N,N-diisopropylferrocenecarboxamide and Further TransformationsPSP3205This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Syn thesisSyn thesis8/13/19

VISyn thesisPhotoredox Fischer Indole SynthesisPaper3214Synthesis 2019, 51, 3214–3220DOI: 10.1055/s-0037-1611535A. KagaT. FukushimaJ. Shimokawa*M. Kitamura*Syn thesisSynthesis 2019, 51, 3221–3230DOI: 10.1055/s-0037-1611835W. SunM. ZhangP. LiY. Li*Jinan University, P. R. of ChinaSyn thesisSynthesis 2019, 51, 3231–3240DOI: 10.1055/s-0037-1611548A. DasA. MaitiM. Kundu*K. K. RoyI. Ansary*The University of Burdwan, IndiaTCG Lifesciences Pvt. Ltd., IndiaOne-Pot Synthesis of Polysubstituted Imidazoles Based onPd(OAc)2/Ce(SO4)2/Bi(NO3)3 Trimetallic Cascade of Decarboxylation/Wacker-Type Oxidation/Debus–Radziszewski ReactionPhOHOH Ar3221PhPdII/CeIV/BiIIIPhPh R-NH2 NH4OAcNONRAr25 examples72–88% yieldDibenzo[b,e]azepin-6-ones and Seven-Membered Sultam Derivatives:Convenient Synthesis via Palladium-Catalyzed Regioselective Intramolecular Heck Reaction and Application towards Drug-Like SmallMoleculesR1XNPaperR1BrN XPd(OAc)2 (5 mol%), PPh3 (10 mol%)TMEDA (2.0 equiv), DMF, 110 C, 5 hR2OCCOR2R1 Me, Et, nPr, CH2CH2NMe2R2 OMe, OtBu, NMe2, N-methylpiperazineX CO, SO213 examples51–75% yieldPaper3231This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Nagoya University, JapanKyoto University, Japan

VIISyn thesisSynthesis 2019, 51, 3241–3249DOI: 10.1055/s-0037-1611819Reactivity of 3-Bromofuran in Pd-Catalyzed C–H Bond Arylationtoward the Synthesis of 2,3,5-TriarylfuransPaperRhodium-Catalyzed Double Isocyanide Insertion via a VinylcarbodiimideIntermediate for the Synthesis of 2H-Pyrrol-2-iminesPaper3241A. SasmalT. RoisnelJ. K. BeraH. Doucet*J.-F. Soulé*Syn thesisSynthesis 2019, 51, 3250–3258DOI: 10.1055/s-0037-1611830Y. WangZ. LiH. Zhao*Z. Zhang*Inner Mongolia University, ChinaChina Agricultural University,P. R. of ChinaSyn thesisSynthesis 2019, 51, 3259–3268DOI: 10.1055/s-0037-1611564X. JiangH. JinT. WangH. YooS. Koo*East China University of Scienceand Technology, P. R. of ChinaR1 N3viaR2 NC[Rh(cod)Cl]2 (2.5 mol%)DPPE (5 mol%)R3 NC1,4-dioxane, rt to 120 CNRCNHN R3R1R1NNR2up to 95%Synthesis of Phenyl-2,2′-bichalcophenes and Their Aza-Analogues byCatalytic Oxidative DeacetylationOEtOOOOO2OYMnIIIEtOY O, SR H, CN, OMe, FCoII CoIIIO2OPaal–KnorrOEtOXYMnIIRR3250YRX O, S, NH15 examplesup to 86% yieldPaper3259This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Univ Rennes, France

VIIISyn thesisSynthesis 2019, 51, 3269–3276DOI: 10.1055/s-0037-1610712Z.-Z. JiangY.-J. JiangJ. DuD. ChenC.-H. Ding*B. Xu*X.-L. Hou*Palladium-Catalyzed Asymmetric Heck–Matsuda Reaction of1,4-Dihydroquinolines with Aryl Diazonium SaltsPd(dba)2 (10 mol%)L (20 mol%)R ArPaper3269RN2BF4NaOAc (2.0 equiv)MeCN, 23 CNBocL:BnOONNNArBocup to 84% yieldup to 90% eeBnSyn thesisSynthesis 2019, 51, 3277–3286DOI: 10.1055/s-0037-1611563Manganese(III)-Based Oxidative Cyclization of N-Aryl-2-oxocycloalkane-1-carboxamides: Synthesis of SpiroindolinonesR4S. KatayamaH. Nishino*OR2ORnR alkylR1, R2, R3, R4 H, Me, OMe, Cl, Fn 0–2Synthesis 2019, 51, 3287–3294DOI: 10.1055/s-0037-1610711A. ArcadiS. CacchiG. FabriziA. FochettiF. GhirgaA. Goggiamani*A. Iazzetti*F. MarinelliUniversità di Roma, ItalyMn(OAc)3R3AcOH, refluxorAcOH/HCO2H (1:4)r.t.R2R4OONR1Syn thesis3277nR3Kumamoto University, JapanPaperNR1R25 examples69% to quant.Palladium-Catalyzed C12-Selective Direct Arylation hos NNHRR2R1TBACl, CsOAcDMA, 120 COX Br, Cl, I; 22 examples, 10–93%R1 H, Me; R2 H, MeR o-, m-, p- EWG and EDG, HNNHOPaper3287This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Shanghai University,P. R. of ChinaShanghai Institute of OrganicChemistry, P. R. of China

IXSynthesis 2019, 51, 3295–3304DOI: 10.1055/s-0037-1611530Synthesis of 1-Palmitoyl-2-((E)-9- and esOA. LehrA. FrankW. MünchU. DietzU. Nubbemeyer*two-step sequenceX Cl, 2,4,6-trichlorobenzoylOX( )7101. activationJohannes Gutenberg-UniversitätMainz, GermanyNO2( )79O10( )7H O2. ester formationH31C15 H OHH31C15OOR1OR1Synthesis 2019, 51, 3313–3319DOI: 10.1055/s-0037-1611787G.-H. LiD.-Q. DongQ. DengS.-Q. YanZ.-L. Wang*Qingdao Agricultural University,P. R. of ChinaOPO0.5 mol% Zn catalyst0.25 equiv MeOHH2 equiv HSi(OEt)3N Me3( )7N 1R2PhHHOHR1R1: Alkyl, ArylR2: ArylHR2HN NNZnH3CSPhZn catalystCopper-Catalyzed Deoxygenative C2-Sulfonylation of QuinolineN-Oxides with DABSO and Phenyldiazonium Tetrafluoroborates for theSynthesis of 2-Sulfonylquinolines via a Radical ReactionN2BF4CuOTf (10 mol%) DABSOR1 CH2Cl2, 100 CNOPaper3305OHtoluene, 60 CBrock University, CanadaSyn thesisO10New Zinc Catalyst for Hydrosilylation of Carbonyl CompoundsSynthesis 2019, 51, 3305–3312DOI: 10.1055/s-0037-1611824I. D. AlshakovaG. I. Nikonov*ONO2( )7 9OOPO O–O O–OSyn thesis3295NO2( )7 9HOPaperR2OR1NSR2O18 examples, 60–88% yieldPaper3313This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Syn thesis

XSyn thesisCobalt-Catalyzed Cycloisomerization of N,N-DiallylanilinesPaper3320Synthesis 2019, 51, 3320–3326DOI: 10.1055/s-0037-1611832J. LiuZ. YangM. ZhengH. WuN. Chen*J. Xu*Co-I (10 mol%),Et3Al (33 mol%),PhCl (33 mol%)RNNRNNtoluene (0.3 M)CoNClCl15 examplesmoderate to good yieldsBeijing University of ChemicalTechnology, P. R. of ChinaSyn thesisSynthesis 2019, 51, 3327–3335DOI: 10.1055/s-0037-1611547H. ChenC. WangD. WenY. DengX. LiuX. LiuJ. Zhang*W. Yan*Lanzhou University,P. R. of ChinaSyn thesisSynthesis 2019, 51, 3336–3344DOI: 10.1055/s-0037-1611536X. LiN. Chen*J. Xu*Beijing University of ChemicalTechnology, P. R. of ChinaThe Catalytic Asymmetric Construction of TrifluoromethylatedQuaternary Carbon-Containing ThiochromansOONHNHPaper3327CF3NH HCF3MeOOR2R1SH F3CR1 H, 5-Me,3,5-Me2OHNOR3catalyst (10 mol%)C6H5Cl, –20 CR2 aryl, alkylR3 aryl, alkylR3OCF3R1SR225 examples, up to 91% yield 20:1 dr, 97% eeMicrowave-Assisted CuCl-Catalyzed Three-Component Reactions ofAlkynes, Aldehydes, and Amino AlcoholsR4R4R1NHOH( )n2 R CHO R5n 0, 1R1 alkyl, arylR2, R3, R4, R5 H, alkyl, arylR3( HC CH )CuCl (10 mol%)PhMe, MW(40 min to 2 h)R1R2OH( )nNR5PhNOR3yield: up to 98%readily available catalystgram-scale24 examplesOOPaper3336This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Co-I

XISyn thesisSynthesis 2019, 51, 3345–3355DOI: 10.1055/s-0037-1611837F. YuanW. DuanZ. LiX. LuoM. ZhangH. DengL. Song*One-Pot Synthesis of Trifluoromethylated Pyrazol-4-yl-pyrrole-2,5dione DerivativesCF3OR2CHON CH3 AcOH (solvent) NR1HNOORNNH3CR1, R2 Alkyl, ArylCF3O90 CPh33452R1HNNPaperNOOHPh71–90%, 26 examplesSyn thesisSynthesis 2019, 51, 3356–3368DOI: 10.1055/s-0037-1611531L-Prolinal Dithioacetal: A Highly Effective Organocatalyst for the DirectNitro-Michael Addition to Selected Cyclic and Aromatic KetonesOP. PomarańskiZ. Czarnocki*ONO2yield 46–99%dr up to 99:1ee up to 99%ArArnUniversity of Warsaw, PolandNO2nn 1–4 n 1–4cat (5 mol%)ONO2OORSNHRSOSyn thesisAryield 29–78%ee up to 99%Paper3356This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited.Shanghai University,P. R. of ChinaShanghai Institute of OrganicChemistry, P. R. of China

Date, Signature tc1719ss.fm 8/13/19 Reviews and Full Papers in Chemical Synthesis 2019 Vol. 51, No. 17 Syn thesis September I Syn thesis Syn thesis Synthesis 2019, 51, 3171-3204 DOI: 10.1055/s-0037-1611822 D. Antermite J. A. Bull* Imperial College London, UK Transition Metal-Catalyzed Directed C(sp3)-H Functionalization of Saturated .