Cue' Erginici - California State Water Resources Control Board

Transcription

a ' 29/0829/93TLTÈTUE; :i11:325916FAXFAX 203.,203 57.5645f1r.,, ; ea0CUST SERVICE1lL4ÇDER)iID ,CUSTMACDERIfID11) ISOPREP 184 (1997)(1997)07-1SHEETMATERIAL. SAFETY DATA SHEEFMATERIALcue' erginiciartini:.t Ert.1,.INCORPORATED 75-srooçr 05702o5762 Cam) 675-5700Wt7E?BÚiijr, CTa. s'if WATERENRY,REPHT ST:245f243 pRElet-sra ''''''''''''''''''''''''''''''''''-:; -;sxtw,» ::,; s,:' »,a;;. "1vi:gì:n»h9 r: ä:rt-e,w -i.w,-- iÿv;:,;,.5%.1414p47.3girglilitggr VOIV.15;410Z;;V,4.,t ,5, ''ÿ.i,',,i.;ór.,,ÑM}4f41rzr.''s ''''''''''',., :,'. :.H:K::::: n"si'¿;á)niySS,vr s - 3Issue Date:Issue-Revised Date:24 HR. Emilipmgc-r;4EMERGENCY /19970CIiEMTRECCHEr411-FtEc11(800) 424 -8900(cci),04:93004:,4:'sazPRoDUcTREOARD1N 0 THIS PRODUCTINaUIRiES:R OARRINOALL INOUIRIC4GODE MUST AccONiPAts'YA-COMPAti 7 AU.Mo-00crP0f4cTc9DEPRODUCT IDENTIFICATIONSECTION INettie:TradeTrade Narrre:7841SOPREP 184ACIDÄC1)Chérnicál Family:ChemicalProprietaryproprietary MixtureFormulaFormula:. .CO OTHERp FLAMMABILITY bO.REACTIVITREACTIVITY331-IEA,LTHHEALTH 0.}iMiS:Rátirig:1-liAISRating:Extrétne)d Extreme)High and d-7 HighModerater 33 Insignificant, i1 Slight,Síighí, 227ez Mciderate,(o(0 Intgnficant,"v*.-SECTION 2,SECTION/HAZARDOUS INGREDIENTS;I -Ingreclient(S) 'as haiardoUs.chemical ingrédïetlt(s)'ashazardous:.fallowing 'chemicalhas indentified the followingInc, .hasMaçDerritiif; Inc.ItilacDerread,SvWeight-%By WeightCAS%.CAS#x.-371-7.indTédieiit .In1-edient,2fJ. 3020.--SO10028,22751 0028 22-5Ferric isúlf.atj1:107697,37-2769737-21-.1ßNitri Acid5 14.4157664,93-97864-:93-9Sulfuric : 'AcidSulforioAcid4,:t' 3SECTION 3.PHYSICALPHYSICAL. .DATADATAForm: LIQUID41avIDFtgrp:Density: iblgálDensity::113441pH:12-1.4Gravity:: 1.430Specific Gravitypij1;430NA00 CFlash Point: NA-25:00Freezing Point -13.0.0 F1 -25Volatile %: Not r Pressure: Not DeterminedChemical Oxygen Demand (COD):(CaD): Not DeterminedComplete SolubititySolubility 16Wáter: Cómplete.Solubilityin water!.amber-brown/acidicClear ambér-bràvyn/acidicOdor: giberColor 1 'Odor:Coterfvalues for this product)areproduct.)are typical(Nate:These physicalPhysical properties'(Note'' SECTION 44.--FIRE AND EXPLOSION DATA:NAPoint; NAFlash Pointweterw8ys. Water, carbon dioxide;.dioxide; dry chemical, foam,or waterways.run off to enter sewers orMedia. Never allowallow run-offExtinguishing Media;Extingoisbidsmaterial.halon. As appropriate for surroundingHazards:: ReactsReads with metals to form hydrogen gas which is explosive Wear self&ExplosionExplosion HazardsUnusual FireFire:&apparatus/Protective clothingclothingbreathing apparatus/protectivecontaied breathingcontained4:SECTION 5AID DATAFIRST AID'DATArenderingown safety priorprior to:renderingexposure, -Firstcases. of exposure.First alders should provide for their ownin ali casesphysíc an'inallContact aa physicianassistance:assistance.Linder slowlyslowly runningrunning waterwaterthe.nearest eyewash or shower Wash affected eyes undervictim immediately to theEyes : Take the victimImmediately.attention immediatelySeek medical :attentionfor iSminutes Seeki S .minutesWash skin with soap & water. If irritation develops, contact a physician.clothing MittSkin; Remove contaminated clothing.rmrThIMPOIMP-R8TAÑY H& SAFETY INFORMATIONTN :&-SAFETYINFOILIIIIATIi)1%1

11:32TUE 1132o9'/20/98 MEod/2s/6859152b3575575 5915FAX, 203FAX.oosZoosSERVICEii)1091NOW169S9F11)15&1044169 9FI SERVICEIncorporatedMacDermid IncorporatedFAx (203)675-56304435011 -- FAx(203)575-5630TELEPHOÑE (203)576-5700(203)575-5700 -- TELEX 4436011WATE8BuRY, CT 0670206702 -- TELEPHoNE245 FREIGHTFREIGHT STREET - WATERBURY,245MATERIAL SAFETY DATA SHEETProduct:code:Product code:Issue Date:Revised Date:ISOPREP 184HEAD PRDCHEAD C 0-800-424-9300(1-800-424-9300)HootHour Emergency Number: CHEMTRECFIRST AID DATASECTION 5SECTIONSamounts ofof water.water. Nevervomiting. If consciotis,conscious, havehave victim rinse mouth, then drink large arnOuntsIngestion: Do NOT induce vOrnittng.person. Call a physician iriirriediatAly,immediately.give anything by mouth to an unconscious perSon.call a physidianphysician imrnediately.to mouthimmediately. ifgive mouth toRemove *CMIf not breathing giveto fresh air and callvictim toInhalation: :Convulsions do not induce vomiting or give water.unconscious having trouble breathing-or in COnVulsionsCAUTION : 1flf unconSCioas-haVingCAUTJONprior to retiSe.reuse, NEVER administer anything to an unconscious person.clothing and gear priorAlways clean contaminated clothingAlways24SECTION 6 - I-IEALTH EFFECT DATASEOTItif4:6IngestionPrimal] reute(s)route(s) Ofof EXposure;aPPsure: Eyg,'.§kin;inhalatibriPrimaryaye, Skin, Inhalation and ingestionirritation or burns on direct(Acute) : Chemical irritation follows initial mechanical irritation Can cause irritationEye Contact -(ACtrte):eyes will Odoroccurtéring of eyescontact Intenstritetisd inrk6ririginjury which may persist for several days. Prolonged contact may causeEye Contact ¡phrcirile):{Chronic): May cause eye injuryye injury (blindness)permanent eyeMay cause irritationwill result ininitation and damage to skin Exposure toto skin willin burning sensation(Acute)Skin Contact (Acute):occurPainful sensation will gc,turproiongeci exposure/-"Skin Contact (Chronic): Profound damage to tissues may occur with prolongedabdominal cramps with distension of stomachStomach May causeo-ause abdorninalingestion (Acute) : May bum mouth/throat and ctincludingDamage to digeStive tractt.-bums to entire respiratory system.syttem. May experience general feeling ofof discomfortInhalationInhalathin (Acute): May cause burns(Cheonic):may result In rapid breathingProlonged inhalation Mayinhalation (phronjc):InhalationSECTION 7 .-- PERSONAL PROTECTIVE DATA-SECTIONRespiratoryforOSHAPEL/ACG1H-TLVin section 1313 and it is exceeded, it isis. a value forOSHA-PEIJACGIH-TLV -inIf there isRe.spiratory Protection:rbspiiitor be used Consult WithNIOSH approved respiratorwith OurInciustial Hygienist for apprepnateappropriateyour Industrialrecommended that a NOSHFer large spills, entry into large tanks, vessels or enclosed small spaces with inadequatecartridge selection and use Forself contained breathing apparatus is recommended:recommended.a pressurepressure demand,demands selfventilation,ventilation, AIsrecommeaded.locallocalexhaust VentilationAdditionally,Ventilation: General.ventilation is recommended whereGeneral ventilationventilation recoMmended. Additionally,be released.released,aerosols maymay beduits, mists or aerosolsvapors, dusts,Safetyan byesafety glasses and/orsplasharid/or splash proof goggles, face ShieldsaVallal*ty of aneye washshields and the availabilityProtective s.PVC, On;construction PVC;materialChemicallyofIsrecerhMendad.is reCOmmendeel.,is recorninended,recommended :Ifneoprene.shower isThe availability ofIf Clothingclothing is contaminated, remove clothing andneoprene Thepf aa safety showerarea Lai.ir0be00410114.*cOOttilhgLaunder pontarnInated clothing before reuse.b.os, !roa.wash the affected bodythoroughlythoroughly washconditions.1ev1 oof protection forfor various trittti*material handling toricIltionsrecommendations to provide aa safe levelgeneral recommendationsThese are .0004applioations at your facilityfacility,Prefessionat/Industrial Hygienist for speCifidinforMatiorispecific information regarding applicationsConsultwith your Safety PrefeSSiOneOhdirStriali-ijigleitik'fbrConsult with:.:SECTION 8sgOloNt:TOXI[COLOGY DATADATATOXICOLOGYtoxicity literature surveyson this productproduct. However,TOXICITYSTUDIES:Toxicity stuclies have notOXICITY STIVIEO.:ToxiPiV1-1.61Neyer. toxicityOrtdU0ed prPOO conductedl.r:0; beenSection 2.1. TheThe resultsresults are as follows:been conducted on the ingredient(s)ingredient(s) in Sectionhave beenLD50 2140 2140 mg/kg(Rat)mg/kg (Rat)itfuric Acid:Acid: LD50.-.Acute OralTemiCity: SulfuricOral Toxicity:(.Acute

0729198.0/29/98Ti3ETUE5916"293 575 5916FAX 20.344-:3311:33. AXDLACDERIiIÄ CUSTMST SERVICE1A.A.CDtriMIljISOPREP 184 (1997)11) ISOPREP@Icog009NiacDermid IncorporatedMacDermidn.44.36011cT 08702 - TELEPI-(6.14ETELEX 44.360'11VVATERBURY, CTTELEP.H.ONE (23)575-5700245 FREIGHTFREIGHT STREET -- WATERBURY,(203)575 -5700 r TO:8XFAX(203)575.5620(203)576.5630MATERIAL SAFETY DATA SHEETIssue Date:Revised Date:54ISOPREP 184HEAD PRDCProduct:code:Product cadet5/01/19941/31/1997Page:3(1 -800- 424 -9300)Emerncy Number: CHEMTREC (1-800-424-9300)24 Hour EmergencyTOXICOLOGY DATASECTION /38UnknownToxicity: UnlinownDermal TOX1C4::Acute pep-PalAciite(Rat)/m3 /2H (Rat)mg/m2/2H510 mgAcute Respiratory Toxicity: Sulfuric Acid: LC50 :510ingestions. nt: Extremely(THR):A severe eye irritantToxicity Hazard Review ;(THR):secondary torejoict destruction oftissues.tissues. There are systemic effects Secondaryirritating; corrosive and toxic to tissues resulting in rapidirritáting;tissue damage,OSHA:: NpNTP: NoOSHAIARC: NoNTP;NYListed as suspected carcinogen by !ARC:.aREACT[VITJ!.;DATAREACTIVITY DATAmaterials.Incompatibility: Alkaline rnateiials.Incompatjb¡lity:Products; Oxides of sulfur and nitrogenHazard Decomposition Products:StableStability:with cyanidesConditions To Avoid: Contact withHazardous Polymerization: No hazardous polymerization.SECTION. 9SECTION.mu.SPILLS '&fi DISPOSAL DATA10SECTION étc!CHEMTREC {14301:1,4211-93013).'fi case of Transportationnumber: c14ENITI3FP(1-800 - 424 -9300).Pail 4)0the if4lIcriiiiingfollowing U24 hOUrhour tetePhOnetelephone nurrOer:Tr4rip.POrtatiOn:ACCidorits,Accidents, 001)Spill ControlCnrttral and RecoveryRecovery: Wear protective clothing and equipment duringcleanupAbsorboleant.ip,duringspills on an inertvermiculite sweep up and dispose of in accordance Withwith federal, state and localmaterial :0.01:slick asearth, sand or vortuoulite;.fis spose of in accordance with all applicable federal, state and local regulatiyos.check youryourNEVER:wastetreatDue to more restrictive waste disposal regulations, NEVERW6SletrO* or dispose of material until you :check& federal regulations for requifernents.local, state &requirements. Spills may REQUIRE notification to FOOERAL,FEDERAL, STATEappropriate 166.51,and/or I.:DOALLOCAL oNTRANSPORTATION. DATATRANSPQRTATIQN11:Shipping "Name:DOT Proper shippingName:sal.CORROSIVE 'LIQUID,:LIQUID, ACIDIC, INORGANIC, N.O.S.(CONTAINS FERRIC SULFATE/SULFURIC ACID)HazardHazard:5/CORROSIVE MATERIALUN /NA#LININAtt:UN3264Grp:Pkg Grp;IIIl(RO): 204DOT Reportal?leReportable Quantity (RC):294CORRoSIVÈLIQUID,IMÓ: CORROSIVEIMO:' LIUID, ACIDIC, INORGANIC.iÑORGANIC.N.O:S.N.O.S.IMOClass/Subimp Claass/SubClass:CORROSIVE/8/0Pkg Grp:IlIIPkg Grp:liIIülüllVA# : UN8284/8147-1Ú1V3254/8147-1tifsl/NA#compwpUID.! ACIDIC, INORGANIC, N.O SLIQUID,N.O,SIAIl"A CORROSIVE LIQ1ATA:IATAClass/Sub Class:CiasiStibUN3264--.;IINÌNA# t UN8284.--NUN/NA#(.CóRRO.SIVFJ8/0CORROSIVE/8/0

(19/29/98r19%29/98203 575575 5916591611:33 FAX 203TOE 11:33TUE11)SERVICEISAMA99FIT SERYICEISC7PRM19997;STl?j1o[a o010WiacDermid IncorporatedMacDermid4.5-36011TELEPHPNE (203)575-S700(203)575 -5700 - TELEX 4435011cT 06702 - TELEPHONEVlidkTEI131.113Y, CTFREIGHT STREET - WATERBURY,245 L SAFETY DATA SHEETProduct:Product code;Date:Issue :Date:Revised Date:ISOPREP 184HEAD FRDCL HEADDPRPC5/01/19941/31/1997.Page: 41-800-424-9300enc .Nurìlber:Number: CHEMTREC .1-800424-9300Emer. eri.c24 Hour Err.iérTRANSPORTATION DATASECTION 11product.license may be:be required to export this prod .ict.Export ,licenseEzppifGENERAL STORAGE DATASECTION 12(3 -C)C)Minimum: 37 F (348.88CMinimum:119.98F / imum;Storagestoragestored in the properly sealed original containerMaterial should be storedoxidizersCorrosive materials Must riotnot be above;above, below or adjacent to flammables or oxidizers.MATERIAL: Corrosive:CORROSIVE MATERIALwith acids.lóadéd or stored withCyanides oror cyanide mixtures must not be loadedTOXICS:TOXICS:Cyanides1.REGULATORY DATA3SECTION .113product,apply to this -product.TheThe follovvingfollowing regulations applyREGULATIC:INS:FEDERAt. REGULATIONS:FEDERALfollowing ingredients in thison ourevalLiation,our evaltiation, the followingCernmunication Rule, 29 CFR 1910.1200: Based onHazard çórrrinuri1cationOSHA HaZ0.4rule:product are subject to this cute:OSHA-PELOSH,.-A PELACGIH-TLVACGIHTL3/%By Weight 'JttCAS .#IngredientIngredient2 00PPM2.00PPM2:OOPPM7697-37-21 - 107697372,:OOPPM110Acid-2"'Nitric-Tliuic Acid1.00MG/M3- 151,0bMG/M35 lftiricfUric AddI117, 302304:CFR, :177cREcLA/Superfund, 40 CFRCRSCLAÌSuperfund,preduct is required.Notifications of spills of this product312 &REAUTHORIZAT1ONS ACT:ofACT of 1986 (TITLE Ill)III) Sections 302, 311, 312& .313:313:SIJPERFUND AMENDMENTS & REAUTÑOR1ZAT(ONSSARA SUPERFUND359); This productcontainsinproduct contains ingredients listed inCER 3SS):Hazardous Substances (40 CFRibi: Extremely HazárriousSection 302:Sectiöriextremely hazardoussubstance (ÉHS):(ENS):haZardous siibstancé40 CFR 355 as an extrernelyAPPENDIX A of 4.0IByWeiqtCAS #%By Weight %IngredientlAgredien78g7,37-2I::1 - 5 -1ß- 15SAcidSulfuric AddCFR 370):370):S,D.S ::RpCWIREMENTSM.S.D.S.REQUIREMENTS (40 ;FR312 - Ñi311 && 312.SECTIQMSECTION 311ingredient(s)listedofAPPENDIXinA40 CFRAPPENDIXCPR 355 and hazardous chemicals under 29 CFRThis product containscategories.E.P,A. hazard :categories.1200 (c). The product should be reported under the followingfollowint3E.P.A.'1910,120019111260X Delayed (Chrome)Chrorlic) health hazardX Immediate (Acute) health hazardhazardSudden release of pressure hazardhazardFireFire hazardReactive hazardReictiveMsiDS or a:a listfist ofof product names toto the local emergency planning commission, state311 submittal of IVISDSUnderSection 311.,linderSection1987- Consult the regulation foris required after October 17, 1987;emergency response commission, the local fire department isend .updates.updates.ctianges andpertinent changesproduct .containscontains the following ingredients listed under 40372)!This product- List of Toxic Chemicals (40 CFR 372)ThisSection 313 -listSeçfionCFR 372.65IngredientfrThIngrë.dientOM*.CASCAS.##. BYBy%Weight %

7014/29/93. 'TIM09/29/44.TUE1133FAX Zò3203 576575sate5916.aigLanaMAMERMID cusTiCUsT SERVICE.11)11) IS1SOPREP 184 (1997)( 1997)-MacpermidMacDerrnid incorporatedIncorporatedCT 14702 - TELEPHONE (203)574700245 FREIGHT STREET - WATERBURY, CT(203575-5700-TZLE436011TELEX 4436011-FA XFAX(203)575-5630(203)57S-5630MATERIAL SAFETY DATA SHEETProduct:Product code:1SOPREP 184ISOPREPHEAD PRDCHEAD PRDCIssue Date:Revised Date:5/01/19945101/19941/31/19971/3111997Page:55-l .,.141TREC24 Hour EnterEmer enc Number: CHEMTREC 1-800424-93001-800-424-9300SECTION 13U LATORY DATAREGREGULATORYNitric 27664-93-97684-93-9--101011s-is -15TOXIC SUBSTANCE CONTROL ACT (TSCA): TheTOXICThe chemical ingredient(s)ingredient(s) inin this product are listedlisted on theLit5(C) lnyentárY(40 CFRCFR 710).is(b)Inventory List. O710),CONSERVATION & RECOVERY ACT (RCRA), 40RESOURCE CONSERVATION]4o CFR SUBPARTS CC & D:refer to Section 10, disposal information for PertinentPlease Wert)pertinent datadataTotal Toxic Organics:does riotnot contain ingredients Onon the list of Total Toxic Organics.This product dotsOrganics.(1910,119):This product doesOSHA processProcess Safety (1910.119):does riotnot contain ingredients listed in Appendix A .ofof 29 CFR1910.119 list of highlyhighly Hazardous Chemical,Chemicals, Toxics and ReactIVeSReactives of OSHAOSHA process safetysafety management.Clean Air Act:(G)(G),,This product containsContains ingredients listed on the HazardousHazardous Air Pollutants (HAPS)(1-1APS) of CAACM 40 CFR 11211 2-IngredientIndredient/Thlitric AcidOzone Depleting Substances:82,of CAA 40 CFR 82.CAS #7697-37-27697-37-2By13v%Weight Va1-10101This product does not contain ingredient(s)ingredient(s) listed on the Ozone Depleting SubstancesSTATE REGULATIONS:REGULATIONS:California Proposition 65:This product complies with the MSDSSS:ThislvISDS and labeling requirementsrequirements of the SafeSafe DrinkingDrinkingWater andand ToxicToxic Enforcement Act of 1986. ThisThis product does notnot containcontain ingredientslisted onon California Prop95ingredients listedProp65 List.Michigan Critical Materials:This peciductproduct does nötnot Containcontain ingrtdientsingredients listed on the Michigan CriticalCritical MaterialsMaterialsRegister.does not include all Federal, State,The information listed above doesState. and InternationalInternational regulations.regUlations. The regulationregulations listedlistedtime; Itsabove maychange from time toto:time;me}, changeits the usersabOveusers responsibility to keep advised of current regulatory requirements.'PreparedPrepared by MacDerrnid,Mad:Der-mid, Inc.inc. Safety & Regulator Compliance Department, based uponupon publiclypublicly available referencereferenceinformatiOn,informatiOn,SECTION 14USER NOTIFICATIONTo the best afhrof orrnatIo6 OcintIgned hereirils'oOryebt.herein Ls coryect AllAli chemicals may presentpresent .unIcnown.unIclOwn healthand should beheath hazardshazai-ds.ándbe. used withotttiStaii: nktzBitis" are described bereiri,hrtwi we Cii(nhOtjUarantee thatnnot guaranteethat these are.the.ehly:haáardsare the ortly-haiards which a*lat.-exist. Final Oeterrhinahop,ofdetermination of sUltibilityst(Itibility ororthe sthe solecif.the UsettSer.: Uerz Oi! inyOarrika1th0410fesPónsibílity Of-theusetiser.:1j**.0(any Ohernicäl should satietyan mathodSOfsetisfy themselvesthemseIves thatthat thettmelitioriathe e.dnditions andmethods of use assure that theorlérn¡coiisosos¡fejy.it,ipChemical is ilaetiSaraly,'Vo REPRESENTATIONS ORoRWARRENTIES,wARlit 110, EiTHER.I:XORssgooREITHER- EXPRESSED OR trinigoORii.01414.T.P.dapre,1114ESS FORAIMPL1EP OR MERÇHANTi11B1LITY, -FITNESSPARTICULAR PURPOSE OR AN.Y.OTiiERNATUREANY.0111ER NATURE ARE MADEMADE HERETrie INFORMATION CONTAINED HEREIN ORHERE UNDER WITH RESPECT TO ThETHE CHEMIg4T9 1h(1-,041ThgVVHIpl-ITHE 1NFORMATID.N:-REFERS,THE.c14EMIDA(tpINF2RMATION. REFERS,".

13/MgDdrifikl.-çamimyMacDermid.com'of 8Page I1 VÓfV812) ISOPREP 184 (2003)12)1SOPREP184(2003).!Materialateti 41SSafetyafé.ty Data SheetsShe*'MSDSMSDS0 MaeDermidMacEllermid 3 0 '0aNicrFeeoRATEDINCORPORATE 245 Freight243Freight StreetStreet. - Waterbury,Wateibury, CTCT- 0670206702:Telephone (03)575 -5700 - FAX (203)575-5630.TeiePtime'(2Q3/575.57"F.4) (263)57'54(j3k HealthFlammabllltyHelt)flarnmabIllty ReactivltyOtherReaCtI9ItyattiMATERIALMATERIAL SAFETY DATA SHEETISSUE DATE 05/01/946/13/2002REVISEDDATE24 Hour EmergencyErriergency Number:CHEMTREC(1 -800- 424 -9300) 7Nurnher;CHEMTREQ(1.-800"424-4306ISOPREP 184PRODUCT12617PRODUCT CODE -407SECTION:PRODUCT IDENTIFICATION:4:0ROblitTIDENTIFICATION1TRADE NAMENAMECHEMICALFAMILYFORMULAHMIS RATING;RATING:3 Health- Q0, P 184Proprietary Mixtureivficture,OFlammabilityOtherOther'22 :- COMPOSITION / INFORMATION ON INGREDIENTSMacDermid Inc.MadbêmnidInc has identified the followingfOliowing chemicalchernicál ingredient ngedent(s) -aS'as hazardous.,.IngredientFerric sulfateFerric:.sulfáteNitric acidSulfuricSulfuric acidacidSECTION3CAS#; -,,,-:By Weight %%1515, 252533-- 5121;1610028-22 -5101)28-22-57697 -37 -2:7697-37-2,76647664-93-9-93 -9:- PHYSICAL DATA/G111.926 AVITYc FLASHPOINT -13 .00 FF / -25 CNOT LE %!toPRESSUREPRESSUREUnkflownBOILING POINTPOINT UnknownMELTING POINT NACHEMICAL OXYGEN DEMANDmg /1 mgDEMAND 'UnknownUnknown mg/1/1mg/1/1 mgmg/1(COD)Unknown1ril(119wITBIOLOGICAL OXYGENBIOLOGICALOXYGENDEMAND (BOD)(BOO)Complete SolubilitySolubilityWATER.SOLUBILITY IN WATER'ClearClear amber-brown /acidicamber-brown/acidicCOLOR/ODORThese physics).physical propertiesproperties atéare typical values for thisNOTENOTE:TheseV-;n1r,r.rr.w.4An,144 i1 116nnnr.1riVAlAAn-c i¡so w»itA ,

inyMacDermid.com1-4M4Pantid.poirt'PagePage 22-ofof 88'12) ISOPREP 184 (2003)Prctluctproduct.SECTION 4 :- FIRE AND EXPLOSION DATAFLASH POINTNOT APPLICABLEEXTINGUISHINGt)(T1NQUISH1i40,MEDIAcarbon dioxide,Water,, ,o-dpbodry chemical,dioxide, drydheMibäL foam,fOaMthalon. -Ashalori,As appropriateappropriate forfor R allowallOw run -off toto enter sewersseWera ororwaterways.Waterways,rùn-'ofentettReacts withwith metals4eabLafletaIs tOto formform hydrogenUNUSUAL FIREFIRE &hydrogen -gaSgas whichwhibhis- explosiveexplosive Wear selfself-containedcontained breathingbreathingEXPLOSION HAZARDS isapparatus /protective N5:.1- FIRST AID DATAteitallContactntact aa physicianphysician in all casesbaSeS ofof exposure.eXpostixe-7, FirstFirst24-tder.Saidersshouldshould provideprovide forr their own safetyafety./iriorprior toto renderingrenderingassistance;assistance.tliethe victimTake the:victini itmddiatelyimmediately to the nearestnearest. eyewasheyewash orórshower Wash affectedaffected dyeseyes underunder slowlySlowly runningrunning waterwater,for 15 Minutesminutes Seek medicalmedical attention immediately.'f'OriMmediately.EYESattentionwith largeFlushlarge amountsPlush withamounts' ofof waterwater for15 Minutes.for 15'minutes.Contact aa physicianContactphysician- immediately.immediately.SKINDo NOTinduce vomiting.MI' inducetOmit3,ng.-- Ifconscious, havetf.:cOnsciouShave victimvictimINGESTIONINOESTION-Dorinserinse mouth,then drinkdrink large amounts of water',water. Nevermouth, thOnNévox:'-rnout4 togiveiva anything byby mouthto anau unconsciousperson. Callairlooppo pp,A :Physician,aphysician irninediSte/yimmediately.pro,vic;tirn toto coolcCol Ut.C-Oiltarifiliateduncontaminated areaarea. -146riltINHALATIONRemove the victimMonitorINHÁLATIÒ1V.eiiipVethe patient,thq,patient forfor xeSpitatoryrespiratory distressdistressCAUTIONÇ'4UTION.itit- having troubletrc5Upreeathishgbreathing -z oror inconvulsions ,doconvulsionsdo ha;not induceinduce vomitingVoirti;Eing oror givegive water.water,If UncOnatiOdsunconsciousAlways cleanAlWayaclean -contaminatedcontaminated ,clot,hingclothing ,andgear pri)5i-1:StOand gearprior to rdusd*reuse.NEVER ',administeradminister anythinganything toto .anan linconsciOUSunconscious PeriOn,person.SECTION'SECTION6' :- HEALTH6HEALTH EFFECTSDATAPrimaryRoute(s) of Exposure Eye, Skin, Inhalation and látiorrandintleAtiorlBrief contactcontact withWith liquidliqui:d orEYE'CONTACTCr' mistsEYE CONTACT (ACUTE)mists willACUTE) ,Briefwill,severelyseverely burnburn eyes.eyes.,perststMay causecause eyeeye iiijArryinjury whichwhich' may persist forforseveralseveral days.days. Prolongedilrolonged contactcontact maycauseTray causepermanentpermanent eyeeye injuryinjury (blindness)(blindness)EYE CONTACT(CHRONIC).-"-*7vv," v*v.:4pi-tt,t7 4,441,1 n0;11-7-"i- JT1AAnr11n0nT77AT)A1L O'0 0C/1O/!19¡PI0 /fl

myMacDermid.comtoOfacDetiriid,ciVIPage 33 of 88-12) ISOPREP 184 (2003)CausesSKIN CONTACT re skinandburna.'and, burns.Profound damage;Profounddamage, totO tisSNIestissues 'maymay occurOccur withprolongedeXposureprolonged exposureSKIN CONTACT(CHRONIC)'(CHRONIC)Wi11 cause- Willctse. severerete burnSburns totO allail -areasareas ofOfINGESTION OtI (CHRONIC)No data available.lIsiHÄLATIONIACUTE)1INHALATION (ACUTE)Inha-latiOn ofInhalationof Mist&mists will'will burnbUrn mucousmucous.membranes and,MernbrarieSiAnsi respiráttiryrespiratory system.system.,:- PERSONAL PROTEbTIVE'SECTION 7 PERSONALPROTECTIVE DA ADATA7v; SÈ'CTIONIfIf therethere isisavalue fOra-xValuefor OSHA-PEL/ACGIli-TI,VOSHA- PEL /ACGIH -TLVinin sectionsection 13 and it is exceeded,exceeded, it isisrecommended that aa NIOSH&IQSff approvedapproved respiratorbebe used.used. ConsultConsUlt withwith youryour IndustrialHygienistHygienist fir:5rfor appropriateappropriate cartridgeselection andarid use.use. See 29CFR 1910.134191(t,I.34 forFor largedetails. Z'orlarge stpillS,spills, entryentry iiitointo largetanks, vesselsvessels oror enclosedencIoged smallsmall spacesspaces withwìtinadequate ventilation, a:a pressureinadequatepressure detpand,demand,self containedcontained breathingbreathing apparatusapparatus isis-RESPIRATORYPROTECTION'thatdetails,tank,selfit on,recommended.recommended.VENTILATIONVENT ATI N'.'QeneralGeneral ventilation mis ly, locallocal exhaustexhaust ventilationventilation-isisrecommended wherewhere vapors,Vaporsi dusts,dusts, mistsmists ororaerosols maybe released.aerosoltlAY bèieased.-Chemically resistant aprOri,eiiefitically'-resiStantapron, bootsf).66E,s,. anda'tioglOves.gloves. RecommendedReCOmMended materialmaterial ofofconstructionconstruction::: PVC,PVC, rubber,rubber, neoprene.neppreneirTheTheavailability ofavailabilityçf.áa Safetysafety ahoWerfsshower isrecommended. If clothingrecommended.clothing isis contaminated,.contaminated,remove clothing-removeclothing andand. thcirOUghl,ythoroughly wash thetheaffected body arealaffectedarea. Lau:riderLaunder contaminatedcontaminatedclothingclothing beforebefore reuse.reuse.SafetySafety glasseslasses and/orand /or splaShsplash pròofproof goggles.goggles,faceface .shieldsshields and thethe availabilityavailability Ofan eyeof aneyeWashwash isis recommended.'recommended,are generalThese aregeneral reccominendationareccommendations totO;provideprovide -aa safeSafe levellevel ofof protectionprotection forforvariousvarious Materialmaterial handlinghandling conditions.conditions.CohsUltConsult Withwith youryOUr 4fé:tySafetyProfessional /Industrial HygieniatPrOfessibnalAindUStrialHygienist forforspecific information'Specificinformation reguardingreguarding a,pplicationsapplicationsat youratk)tix. facility.PROTECTIVEEQUIPMENTItare generalTheseThese. aregeneral recommendationsredOmmendationS toto provideprbvide aa safesafe leveloflevel ofprotectionfor variousprotection forvarious materialmaterial handlinghandling conditions.conditions. ConsultConsultwithwith youryour SafetySafety Professional/Industrial HygienistProfessional/IndustrialHygienist forfor specificspecificinformation regardingregarding applicationsat yourbiformationapplications atyour facilityfacilitySECTIONSECTION- 8 :- TOXICOLOGY DATA,/. - 1L,--1L.rs/TN nAnn1no7T71A'rv1-ii601:17n AnA 1COe /ryo /nn

niygàcDprrriid,cömmyMacDermid.comPageAge: 4 -pfof 8S.12) ISOPREP 184 (2003)TOXICITY STUDIES:Toxicity studies haveTÒx Cïty'tiiEfhave riotnot beenbeen conductedcOnaticted 6h,on thisthis product.ÌA'6cluct ,However toxicitytoxicity literature surveyssurveys haveha-ve beenbeen conducted onon thethein sectioningredientingredient(s)Cs.) UT2,1- --Theseptic:1n, 2.The resultsresultS areare asa-6 T)4SulfuricSUIfuilC Acid:Acid, LD50Lri54 21402140 mg/kg (Rat)mq/kg(Rat),UnknownACUTE DERMAL TOXICITYTOXICITY UnknownACUTE RESPIRATORY'ACUTETOXICITYSulfuricSurfurit Ad-341Acid: LC50Listed assuspected carcinogenas'suspactedcarCinogen byIARC NONTPNTP 510timP1mg /m3 /2H (Rat):OSHAOSHANONOiTÒSECTION 9 :REACTIVITY:- REACTIVITY DATAINCOMPATIBILITYINCOMPATIBILITYAlkaline materials.materials,'of sulfurHAZARD 'DECOMPOSITIONulfur andand nitrOgenDECOMPOSITION Oxides NDITIONSTO AVOIDOOND1rie.*T6.AVO10-Contact withwith o hazardoushazarc164a OLYMERIZATION SECTIONS1EQTION 10;I.,SPILLS'SPILLS & DISPOSAL DATADATA.-"-In 'caseIncase ofOf TransportationAtcident callIt the followingfit 11Oking 24 hour telephoneTr.aPSIjortátion Accidents,number:numberCHEMTREC (14M-424-9300y(1- 800.424 -9300)tHEMTREC'SPILLSPILL :CONTROLCONTROL AND,ANDSoak'Soak up into anáñ oil absorbant,shovel upabsoi.bant, shoVelRECOVERY.RECOVERYand place inin closedclosed containers fordisposal,disposal. Dike to contain largelarge quantitieSquantities'andandpumppump into drumsdrUms forfor use ,otor e of in accordanceacCorclance Vtthwith allapplicable federal,federal, stateatate andand locallOcal't.egulations.regulations.'SECTION11 :-,TRANSPORTATION DATADOT PROPER SHIPPINGSHIPPINGNAMENAMECORROSIVE LIQUID, ACIDIC, INS FERRIC .SULFATE/SULFURICSULFATE /SULFURIC ACID).mnn All no1V2nDn1cO[Pli? //11

myMacDermid.commyMaeDeitlid.eciniPage 5 of 812)12) ISOPREP 184 (2003)(2003)"HAZARDCORROSIVECORROSIVE, MATERIALuN/Nik#UN/NA#uN32'64,.UN3264DOT REPORTABLE:'REPORTABLE294'PkgPkg GroTTGrpliGL(RC))QUANTITY0VANTITY(RQ)IMO NAME1MO:NAMECORROSIVE LIQUID,LI QUID I ACIDICACIDIC, INORGANIC, }LOS.N.O.S.ÚN32641.1N3'2 6 4IMOIMO UN/ÑÁ#/NA#UN3264UN3264IATA NAMENAME.FORBIDDEN- VENTED CoNTAINgRCONTAINERPkgGpGrpliIATAIptiA CIs /Sub CIscfs,000000Ob000b:UN /NA#:UN/NA#

11) ISOPREP 184 (1997) NiacDermid Incorporated 245 FREIGHT STREET - WATERBURY, CT 08702 - TELEP.H.ONE (203)575 -5700 r TELEX 44.36011 MATERIAL SAFETY DATA SHEET Product: ISOPREP 184 Product cadet HEAD_PRDC Issue Date: 5/01/1994 Revised Date: 1/31/1997 24 Hour Emergency Number: CHEMTREC (1 -800- 424 -9300) SECTION 8 TOXICOLOGY DATA