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Page: 1Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID82234829 CFR 1910.1200 (OSHA HazCom 2012)SECTION 1. PRODUCT AND COMPANY IDENTIFICATIONProduct identifierTrade name: Valvoline ATF 4 FULLSYNTHETIC AUTOMATIC TRANSMISSION FLUIDRecommended use of the chemical and restrictions on useUse of the Substance/Mixture : Engine, gear & lubricating oil.Details of the supplier of the safety datasheetEmergency telephone numberProduct InformationSECTION 2. HAZARDS IDENTIFICATIONGHS ClassificationSkin sensitization: Category 1GHS Label elementHazard pictograms:Signal Word: WarningHazard Statements:May cause an allergic skin reaction.Precautionary Statements:If medical advice is needed, have product container or label athand.Keep out of reach of children.Read label before use.Prevention:Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.Contaminated work clothing must not be allowed out of theworkplace.Wear protective gloves.Response:IF ON SKIN: Wash with plenty of soap and water.1 / 15
Page: 2Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348If skin irritation or rash occurs: Get medical advice/ attention.Wash contaminated clothing before reuse.Disposal:Dispose of contents/ container to an approved waste disposalplant.Other hazardsNone known.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSSubstance / Mixture: MixtureChemical nature: DefatterHazardous componentsChemical NameHYDROTREATED LIGHTPARAFFINIC DISTILLATECAS-No.64742-55-8ClassificationNot a hazardoussubstance or mixture.Concentration (%)59.33HEAVY PARAFFINICDISTILLATE64742-54-7Asp. Tox. 1; H30425.66Mineral OilAsp. Tox. 1; H3043.10BENZENE, POLYPROPENEDERIVATIVES, SULFONATED,CALCIUM SALTSEye Irrit. 2A; H3190.77Skin Sens. 1; H317DODECYL HYDROXYPROPYLSULFIDE67124-09-8POLYMERSkin Sens. 1; H3170.77Skin Sens. 1; H3170.38SECTION 4. FIRST AID MEASURESGeneral advice: Move out of dangerous area.Show this safety data sheet to the doctor in attendance.Do not leave the victim unattended.2 / 15
Page: 3Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348If inhaled: If breathed in, move person into fresh air.If unconscious place in recovery position and seek medicaladvice.If symptoms persist, call a physician.In case of skin contact: Remove contaminated clothing. If irritation develops, getmedical attention.If on skin, rinse well with water.First aid is not normally required. However, it isrecommended that exposed areas be cleaned by washingwith soap and water.Wash contaminated clothing before re-use.In case of eye contact: Flush eyes with water as a precaution.Remove contact lenses.Protect unharmed eye.If eye irritation persists, consult a specialist.If swallowed: Do not give milk or alcoholic beverages.Never give anything by mouth to an unconscious person.If symptoms persist, call a physician.Most important symptomsand effects, both acute anddelayed: Acute aspiration of large amounts of oil-laden material mayproduce a serious aspiration pneumonia. Patients whoaspirate these oils should be followed for the development oflong-term sequelae. Repeated aspiration of small quantitiesof mineral oil can produce chronic inflammation of the lungs(i.e. lipoid pneumonia) that may progress to pulmonaryfibrosis. Symptoms are often subtle and radiological changesappear worse than clinical abnormalities. Occasionally,persistent cough, irritation of the upper respiratory tract,shortness of breath with exertion, fever, and bloody sputumoccur. Inhalation exposure to oil mists below currentworkplace exposure limits is unlikely to cause pulmonaryabnormalities.Signs and symptoms of exposure to this material throughbreathing, swallowing, and/or passage of the material throughthe skin may include:acnestomach or intestinal upset (nausea, vomiting, diarrhea)irritation (nose, throat, airways)May cause an allergic skin reaction.Notes to physician: No hazards which require special first aid measures.SECTION 5. FIREFIGHTING MEASURESSuitable extinguishing media: Use extinguishing measures that are appropriate to localcircumstances and the surrounding environment.Water spray3 / 15
Page: 4Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348FoamCarbon dioxide (CO2)Dry chemicalUnsuitable extinguishingmedia: High volume water jetSpecific hazards duringfirefighting: Do not allow run-off from fire fighting to enter drains or watercourses.Hazardous combustionproducts: carbon dioxide and carbon monoxideHydrocarbonsAldehydesSpecific extinguishingmethods:Product is compatible with standard fire-fighting agents.Further information: Fire residues and contaminated fire extinguishing water mustbe disposed of in accordance with local regulations.Special protective equipmentfor firefighters: In the event of fire, wear self-contained breathing apparatus.SECTION 6. ACCIDENTAL RELEASE MEASURESPersonal precautions,protective equipment andemergency procedures: Use personal protective equipment.Persons not wearing protective equipment should be excludedfrom area of spill until clean-up has been completed.Environmental precautions: Prevent product from entering drains.Prevent further leakage or spillage if safe to do so.If the product contaminates rivers and lakes or drains informrespective authorities.Methods and materials forcontainment and cleaning up: Soak up with inert absorbent material (e.g. sand, silica gel,acid binder, universal binder, sawdust).Keep in suitable, closed containers for disposal.Other information: Comply with all applicable federal, state, and local regulations.SECTION 7. HANDLING AND STORAGEAdvice on safe handling: Do not breathe vapours/dust.Do not smoke.Persons susceptible to skin sensitisation problems or asthma,allergies, chronic or recurrent respiratory disease should notbe employed in any process in which this mixture is beingused.4 / 15
Page: 5Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348Container hazardous when empty.Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes.Smoking, eating and drinking should be prohibited in theapplication area.For personal protection see section 8.Dispose of rinse water in accordance with local and nationalregulations.Conditions for safe storage: Keep container tightly closed in a dry and well-ventilatedplace.Containers which are opened must be carefully resealed andkept upright to prevent leakage.Electrical installations / working materials must comply withthe technological safety standards.SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONComponents with workplace control parametersComponentsCAS-No.Value type(Form ofexposure)HYDROTREATED LIGHTPARAFFINIC DISTILLATE64742-55-8RELSTELPELEngineering measuresControlparameters /Permissibleconcentration5 mg/m3Mist.10 mg/m3Mist.5 mg/m3Mist.BasisNIOSH/GUIDENIOSH/GUIDEOSHA TRANS: Provide sufficient mechanical (general and/or local exhaust)ventilation to maintain exposure below exposure guidelines (ifapplicable) or below levels that cause known, suspected orapparent adverse effects.Personal protective equipmentHand protectionRemarks: The suitability for a specific workplace should be discussedwith the producers of the protective gloves.Eye protection: Not required under normal conditions of use. Wear splashproof safety goggles if material could be misted or splashedinto eyes.Skin and body protection: Wear as appropriate:impervious clothingSafety shoesChoose body protection according to the amount andconcentration of the dangerous substance at the work place.Discard gloves that show tears, pinholes, or signs of wear.5 / 15
Page: 6Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348Wear resistant gloves (consult your safety equipmentsupplier).Hygiene measures: Wash hands before breaks and at the end of workday.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: liquidPhysical state: liquidColour: redOdour: No data availableOdour Threshold: No data availablepH: No data available: No data available: No data availableFlash point: 390 F / 199 CMethod: Cleveland open cupEvaporation rate: No data availableFlammability (solid, gas): No data availableUpper explosion limit: 6 %(V)Calculated Explosive Limit: 1 %(V)Calculated Explosive Limit: 0.0133333 hPa (21.11 C)Calculated Vapor PressureLower explosion limitVapour pressureRelative vapour density: No data availableRelative density: 0.854 (15.6 C)Density: 0.8508 g/cm3 (15.56 C)Solubility(ies)Water solubility: negligibleSolubility in other solventsPartition coefficient: noctanol/water: No data available: No data available6 / 15
Page: 7Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348Thermal decomposition: No data availableViscosityViscosity, dynamic: 10,000 mPa.sMethod: BrookfieldViscosity, kinematicOxidizing properties: ca. 34 mm2/s (40 C): No data availableSECTION 10. STABILITY AND REACTIVITYReactivity: No decomposition if stored and applied as directed.Chemical stability: Stable under recommended storage conditions.Possibility of hazardousreactions: Product will not undergo hazardous polymerization.Conditions to avoid: excessive heatIncompatible materials: Strong oxidizing agentsHazardous decompositionproductscarbon dioxide and carbon monoxideHydrocarbonsSECTION 11. TOXICOLOGICAL INFORMATIONInformation on likely routes ofexposure: InhalationSkin contactEye ContactIngestionAcute toxicityNot classified based on available information.Components:HEAVY PARAFFINIC DISTILLATE:: LD 50 (Rat): 15 g/kgAcute oral toxicityAcute dermal toxicity: LD 50 (Rabbit): 5 g/kgDODECYL HYDROXYPROPYL SULFIDE:: LD50 (Rat): 5,000 mg/kgAcute oral toxicityGLP: yesAcute dermal toxicity: LD50 (Rabbit): 2,000 mg/kg7 / 15
Page: 8Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348Skin corrosion/irritationNot classified based on available information.Product:Remarks: May cause skin irritation in susceptible persons.Result: Repeated exposure may cause skin dryness or cracking.Components:HYDROTREATED LIGHT PARAFFINIC DISTILLATE:Result: Mildly irritating to skinHEAVY PARAFFINIC DISTILLATE:Result: Mildly irritating to skinBENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS:Result: Possibly irritating to skinDODECYL HYDROXYPROPYL SULFIDE:Species: RabbitResult: Not irritating to skinPOLYMER:Result: Not irritating to skinSerious eye damage/eye irritationNot classified based on available information.Product:Result: Slightly irritating to eyesRemarks: Expected based on components.Remarks: Unlikely to cause eye irritation or injury.Components:HYDROTREATED LIGHT PARAFFINIC DISTILLATE:Result: Mildly irritating to eyesHEAVY PARAFFINIC DISTILLATE:Result: Not irritating to eyesBENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS:Result: Irritating to eyesDODECYL HYDROXYPROPYL SULFIDE:Species: RabbitResult: Not irritating to eyesPOLYMER:Result: Not irritating to eyesRespiratory or skin sensitisationSkin sensitisation: May cause an allergic skin reaction.Respiratory sensitisation: Not classified based on available information.Components:8 / 15Print Date: 5/28/2015SDS Number: R0382635Version: 1.1
Page: 9Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348BENZENE, POLYPROPENE DERIVATIVES, SULFONATED, CALCIUM SALTS:Assessment: May cause sensitization by skin contact.DODECYL HYDROXYPROPYL SULFIDE:Assessment: May cause sensitization by skin contact.Result: May cause sensitization by skin contact.POLYMER:Assessment: May cause sensitization by skin contact.Germ cell mutagenicityNot classified based on available information.CarcinogenicityNot classified based on available information.Reproductive toxicityNot classified based on available information.STOT - single exposureNot classified based on available information.STOT - repeated exposureNot classified based on available information.Aspiration toxicityNot classified based on available information.Components:HEAVY PARAFFINIC DISTILLATE:May be fatal if swallowed and enters airways.Mineral Oil:May be fatal if swallowed and enters airways.Further informationProduct:Remarks: No data availableCarcinogenicity:IARCNo component of this product present at levels greater than orequal to 0.1% is identified as probable, possible or confirmedhuman carcinogen by IARC.OSHANo component of this product present at levels greater than orequal to 0.1% is identified as a carcinogen or potentialcarcinogen by OSHA.NTPNo component of this product present at levels greater than orequal to 0.1% is identified as a known or anticipated carcinogenby NTP.SECTION 12. ECOLOGICAL INFORMATIONEcotoxicityHEAVY PARAFFINIC DISTILLATE:: LL50 (Fish): 100 mg/lToxicity to fish9 / 15
Page: 10Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348Toxicity to daphnia and otheraquatic invertebrates: EL50 (Aquatic invertebrates): 10,000 mg/lToxicity to algae: EL50 (Algae, algal mat (Algae)): 100 mg/lToxicity to fish (Chronictoxicity): NOEC (Fish): 10 mg/lToxicity to daphnia and otheraquatic invertebrates(Chronic toxicity): NOEC (Aquatic invertebrates): 10 mg/lDODECYL HYDROXYPROPYL SULFIDE:: LC 50 (Oncorhynchus mykiss (rainbow trout)): 0.75 mg/lToxicity to fishExposure time: 96 hTest Type: semi-static testMethod: OECD Test Guideline 203GLP: yesToxicity to daphnia and otheraquatic invertebrates(Chronic toxicity): EC 50 (Daphnia magna (Water flea)): 0.5 mg/lExposure time: 21 dEnd point: see user defined free textTest Type: see user defined free textMethod: OECD Test Guideline 211GLP: yesPersistence and degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableOther adverse effectsNo data availableProduct:Additional ecologicalinformation: An environmental hazard cannot be excluded in the event ofunprofessional handling or disposal., Harmful to aquatic lifewith long lasting effects.SECTION 13. DISPOSAL CONSIDERATIONSDisposal methodsGeneral advice: The product should not be allowed to enter drains, watercourses or the soil.Do not contaminate ponds, waterways or ditches withchemical or used container.Send to a licensed waste management company.Dispose of in accordance with all applicable local, state and10 / 15
Page: 11Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348federal regulations.Contaminated packaging: Empty remaining contents.Dispose of as unused product.Empty containers should be taken to an approved wastehandling site for recycling or disposal.Do not re-use empty containers.SECTION 14. TRANSPORT INFORMATIONInternational transport regulationsREGULATIONID NUMBERPROPER SHIPPING NAME*HAZARDCLASSSUBSIDIARYHAZARDSU.S. DOT - ROADNot dangerous goodsU.S. DOT - RAILNot dangerous goodsU.S. DOT - INLAND WATERWAYSNot dangerous goodsTRANSPORT CANADA - ROADNot dangerous goodsTRANSPORT CANADA - RAILNot dangerous goodsTRANSPORT CANADA - INLAND WATERWAYSNot dangerous goodsINTERNATIONAL MARITIME DANGEROUS GOODSNot dangerous goodsINTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGONot dangerous goodsINTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGERNot dangerous goods11 / 15PACKINGGROUPMARINEPOLLUTANT /LTD. QTY.
Page: 12Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS ANDWASTESNot dangerous goods*ORM ORM-D, CBL COMBUSTIBLE LIQUIDMarine pollutantnoSECTION 15. REGULATORY INFORMATIONSARA 311/312 Hazards: Acute Health HazardSARA 313Component(s)SARA 313: This material does not contain any chemical components withknown CAS numbers that exceed the threshold (De Minimis)reporting levels established by SARA Title III, Section 313.Pennsylvania Right To KnowHYDROTREATED LIGHT PARAFFINICDISTILLATE64742-55-850.00 - 70.00 %HEAVY PARAFFINIC DISTILLATE64742-54-720.00 - 30.00 %POLYMERNot Assigned5.00 - 10.00 %LUBRICANT ADDITIVENot Assigned1.00 - 5.00 %Mineral OilNot Assigned1.00 - 5.00 %New Jersey Right To KnowHYDROTREATED LIGHT PARAFFINICDISTILLATE64742-55-850.00 - 70.00 %HEAVY PARAFFINIC DISTILLATE64742-54-720.00 - 30.00 %POLYMERNot Assigned5.00 - 10.00 %LUBRICANT ADDITIVENot Assigned1.00 - 5.00 %Mineral OilNot Assigned1.00 - 5.00 %California Prop 65Proposition 65 warnings are not required for this productbased on the results of a risk assessment.The components of this product are reported in the following inventories:TSCA: On TSCA Inventory12 / 15
Page: 13Revision Date: 05/27/2015SAFETY DATA SHEETPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1Valvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348DSL: All components of this product are on the Canadian DSL.AUSTR: On the inventory, or in compliance with the inventoryNZIOC: Not in compliance with the inventoryENCS: Not in compliance with the inventoryKECL: On the inventory, or in compliance with the inventoryPICCS: On the inventory, or in compliance with the inventoryIECSC: On the inventory, or in compliance with the inventoryInventoriesAICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL(Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)SECTION 16. OTHER INFORMATIONFurther informationRevision Date: 05/27/2015NFPA:HMIS ILITY1PHYSICAL HAZARD00 not significant, 1 Slight,2 Moderate, 3 High4 Extreme, * ChronicSpecial hazard.NFPA Flammable and Combustible Liquids ClassificationCombustible Liquid Class IIIBFull text of H-Statements referred to under sections 2 and 3.H304May be fatal if swallowed and enters airways.H317May cause an allergic skin reaction.H319Causes serious eye irritation.Sources of key data used to compile the Safety Data Sheet13 / 15
Page: 14Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUIDPrint Date: 5/28/2015SDS Number: R0382635Version: 1.1822348Ashland internal data including own and sponsored test reportsThe UNECE administers regional agreements implementing harmonised classification for labelling(GHS) and transport.The information accumulated herein is believed to be accurate but is not warranted to be whetheroriginating with the company or not. Recipients are advised to confirm in advance of need that theinformation is current, applicable, and suitable to their circumstances. This SDS has been prepared byAshland's Environmental Health and Safety Department (1-800-325-3751).List of abbreviations and acronyms that could be, but not necessarily are, used in this safety datasheet :ACGIH : American Conference of Industrial HygienistsBEI : Biological Exposure IndexCAS : Chemical Abstracts Service (Division of the American Chemical Society).CMR : Carcinogenic, Mutagenic or Toxic for ReproductionFG : Food gradeGHS : Globally Harmonized System of Classification and Labeling of Chemicals.H-statement : Hazard StatementIATA : International Air Transport Association.IATA-DGR : Dangerous Goods Regulation by the “International Air Transport Association” (IATA).ICAO : International Civil Aviation OrganizationICAO-TI (ICAO) : Technical Instructions by the “International Civil Aviation Organization”IMDG : International Maritime Code for Dangerous GoodsISO : International Organization for StandardizationlogPow : octanol-water partition coefficientLCxx : Lethal Concentration, for xx percent of test populationLDxx : Lethal Dose, for xx percent of test population.ICxx : Inhibitory Concentration for xx of a substanceEcxx : Effective Concentration of xxN.O.S.: Not Otherwise SpecifiedOECD : Organization for Economic Co-operation and DevelopmentOEL : Occupational Exposure LimitP-Statement : Precautionary StatementPBT : Persistent , Bioaccumulative and ToxicPPE : Personal Protective EquipmentSTEL : Short-term exposure limitSTOT : Specific Target Organ ToxicityTLV : Threshold Limit ValueTWA : Time-weighted averagevPvB : Very Persistent and Very BioaccumulativeWEL : Workplace Exposure LevelCERCLA : Comprehensive Environmental Response, Compensation, and Liability ActDOT : Department of TransportationFIFRA : Federal Insecticide, Fungicide, and Rodenticide ActHMIRC : Hazardous Materials Information Review CommissionHMIS : Hazardous Materials Identification SystemNFPA : National Fire Protection AssociationNIOSH : National Institute for Occupational Safety and HealthOSHA : Occupational Safety and Health AdministrationPMRA : Health Canada Pest Management Regulatory Agency14 / 15
Page: 15Revision Date: 05/27/2015SAFETY DATA SHEETValvoline ATF 4 FULL SYNTHETIC AUTOMATICTRANSMISSION FLUID822348RTK : Right to KnowWHMIS : Workplace Hazardous Materials Information System15 / 15Print Date: 5/28/2015SDS Number: R0382635Version: 1.1
Valvoline ATF 4 FULL SYNTHETIC AUTOMATIC TRANSMISSION FLUID 822348 Version: 1.1 1 / 15 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline ATF 4 FULL SYNTHETIC AUTOMATIC TRANSMISSION FLUID Recommended use of the chemical and restrictions on use
