Transcription
QUALITY ANALYTICALLABORATORIES, INC.R E F * VE DOCT28October 27, 1994ENGINEERING CO.LMG10002.XYMs. Marti Harding-SmithBarr engineering Company8300 Norman Center DriveSuite 300Minneapolis, Minnesota 55437-1026fp/ .v"1Q 1334RX: Analytical Data for 15/07-004DXR024LMG Laboratory Reference No. M8029Dear Ms. Harding-SmithtOn October 22, 1994, CH2M HILL'S Quality Analytical Laboratories, Inc.,Montgomery Laboratory (LMG) received three samples with a request for analysisof selected organic and inorganic parameters.The analytical results and associated quality control data are enclosed.Any unusual difficulties encountered during the analysis of your samples arediscussed in the case narratives.Under our policy, your samples will be stored for up to 30 days afterreporting. If you have not given us prior instructions for disposal, we willcontact you if any samples require disposal as hazardous waste.Quality Analytical Laboratories, Inc. appreciate your business and lookforward to serving your analytical needs again. If you should have anyquestions concerning the data, or if you need additional information, pleasecontact your client services representative.Sincerely,s:\,Quality Analytical Laboratories, Inc.Xnclosurescc: Mr. Wayne MattsfieldS00074683SUPERFUND RECORDSQuality AnalyticalLaboratories inc.2567 Foirtone Drive. Montgomery. AL36116-1622P.O. Box231148. Montgomery. AL 36123-U48205271 -2440Fax No. 205271-3428
Of OOMTOTSQuality Analytical Laboratories Ref. Bo. MB029Pag*Ho.List of Organic Data Qualifiers . iList of Sample ID Qualifiers . iiClient Sample Cross-Referen-. . iiiCATIONS DATACase Narrative(s) . 1Sample Results . 2Blank Results . 4WTT CHKMISTRY DATACase Narrative(s) . 5Sample Results . 6Blank Results . 8VOLATILE DATACase Narrative . 9Sample Results . 11Blank Results . 14Surrogate Recovery . 16US/USD Recovery . 17SKMIVOLATILK DATACase Narrative .Sample Results .Blank Results .Surrogate Recovery .18202223MS/NSD Recovery . 24Copy of COC Documentation . 25
DATA QOALIFI*RSV —Indicates the confound was analyzed for but not detected. The numberadjacent to the -U" qualifier indicates the reporting limit for thatcompound. The reporting limit can vary from sample to sample dependingon dilution factors or percent moisture adjustment when indicated.J — Indicates an estimated value. It is used when the data indicates thepresence of a compound below the stated reporting limit.C — This flag applies to GC pesticide results only. The "C" flag indicatesthe presence of this compound has been confirmed by OC/MS analysis.(This definition is still being reviewed and discussed).B — This flag is used when the analyte is found in the associated blank aswell as the sample. This notation indicates possible blankcontamination and suggests the data user evaluate these compounds andtheir amounts carefully.C — This qualifier indicates that the value reported exceeds the linearcalibration range for that compound. Therefore, the sample should bereanalyzed at an appropriate dilution. The «" qualified amount is anestimated concentration, and the results of the dilution will bereported on a separate Form I.D — This qualifier indicates compounds which have been identified during adiluted reanalysis. "D" qualifiers are used for samples that have beenanalyzed initially at a lesser dilution than required for accuratequantitation.* — This qualifier indicates that the response for the compound exceeded thelinear range of the instrument. Therefore, this is an estimatedconcentration.P — This qualifier is used for a pesticide/Aroclor target analyte when thereis greater than 25% difference for detected concentrations between thetwo GC columns. The lower of the two values is reported on Form I andflagged with a "P".N — This qualifier indicates presumptive evidence of a compound. This flagis only used for tentatively identified compounds, where theidentification is based on a mass spectral library search. It isapplied to all TIC results. For generic characterization of a TIC,such as chlorinated hydrocarbon, the "«" qualifier is not used.A — This qualifier indicates that a TIC is a suspected aldol-condenaationproduct.
OMQABTC LAB SAMPLE IDThe qualifier* that may b* appended to the Lab Sample ID for organic analysesar« defined belowsDL—Dilution Run. Indicates the sample contained compoundsexceeding the calibration range. The sample was diluted andreanalyzed. Both results are reported.R—Rerun. The sample was reanalyzed. The "R* is not used if thesample was also re-extracted.KB—Re-extraction Analysis. The sample was re-extracted andreanalyzed.MS—Matrix Spike (may be followed by a digit to indicate multiplematrix spikes within a sample set)MSD—Matrix Spike Duplicate (may be followed by a digit to indicatemultiple matrix spike duplicates within a sample set)ii
Quality Analytical Laboratories Raf. Mo. K8029QALClienta IDSanmla TDMS029001M8029002M8029003WW-1PB-1TB-1iii
CASE NARRATIVECationsLaboratory: QAL MDNTGOMEpyLab Ref. NO: 8029Client/Project: BAREI.Holding Time:All holding times were met.II.Digestion Exceptions:None.III.Analysis:A.Calibration:All acceptance criteria were met.B.Blanks:All acceptance criteria were met.C.ICP Interference Check Sample:All acceptance criteria were met.D.Spike Sample(s):All acceptance criteria were met.E.Duplicate Sample(s):All acceptance criteria were met.F.Laboratory Control Sample (s) .All acceptance criteria were met.G.ICP Serial Dilution:Not required for this level QC.H.Other:None.IV.Documentation Exceptions:None.V.I certify that this data package is in compliance with the terms andconditions agreed to by the client and Quality Analytical Laboratories,Inc., both technically and for completeness, except for the conditionsdetailed above. Release of the data contained in this hardcopy datapackage has been authorized by the Laboratory Manager or his designee,as verified by the following signature.SIGNED:/kJAM V\J * \ W DATE:Kaye Walk rCations Supervisor000001
Report of Analytical ResultsINORGANICSDate Collected:Date Received:Sample Matrix:10/21/9410/22/94WattrClient SaMple ID: WW-1Lab ReferenceNum: M8029Lab Sample ID:Sample Description: COUPCATEGORY NAMEAnalytical ParameterResultUnitsM8029001Reporting Date of AnalyticalLevelAnalysis Method(s)CATIONSChromic*CopperLeadNickelZinc( 10.040.727.2 200.7/SW60102169)Quality Analytical Laboratories (QAL). Inc. -- Montgomery000002
Report of Analytical ResultsINORGANICSDate Collected:10/21/94Date Received:10/22/94Sample Matrix:WaterSample Description: OCClient Sample ID: FB-1Lab ReferenceNun: M8029Lab Sample ID:M8029002CATEGORY NAMEAnalytical lZinc 10.0 25.0 3.0 40.0 20.0ug/Lug/Lug/Lug/Lug/LReporting Date of AnalyticalLevelAnalysis ality Analytical Laboratories (QAL), Inc. Montgomery000003
Report of Analytical ResultsINORGANICSDate Collected:NoneDate Received:Sample Matrix:NoneWaterClient Sanple ID: METHOD BLANKLab ReferenceNum: LABQCLab Sanple ID:METHOD BLANKSanple Description:CATEGORY NAMEAnalytical ParameterResultUnitsReporting Date of AnalyticalLevelAnalysis Method(s)CATIONSChroniunCopperLeadNickelZinc 7/SW6010EPA200.7/SU60102169)Quality Analytical Laboratories (QAL), Inc. -- Montgomery000004
CASE NARRATIVEGeneral ChemistryLaboratory:QAL MONTGOMERY Lab Ref. No.- M8029Client/Project: BARR ENGINEERINGI.Holding Time :The pH was received outside of holding time. All other holding timeswere met .II .Analysis:A.B.Calibration:All acceptance criteria were met.Blanks :All acceptance criteria were met.IV.C.*frtr x Spike Sample (s) :All acceptance criteria were met.D.Duplicate Simple (s) :All acceptance criteria were met.E.Lab Control Sample (s) :All acceptance criteria were met.F.Other:None.G.Documentation Exceptions :None .I certify that this data package is in compliance with the terms andconditions agreed to by the client and Quality Analytical Laboratories,Inc., both technically and for completeness, except for the conditionsdetailed above. Release of the data contained in this hardcopy datapackage has been authorized by the Laboratory Manager or his designee,as verified by the following signature.SIGNED:* *i r DATE:Xoe BasileGeneral Organic/Inorganic Supervisor000005
Report of Analytical ResultsINORGANICSDate Collected:Date Received:Sample Matrix:Sample Description:10/21/9410/22/94WaterCOMPClient Sample ID: MMLab ReferencaNun: M8029Lab Sample ID:H8029001CATEGORY NAMEAnalytical ParameterResultUnits8.1units1470ug/LReporting Date ofLevelAnalyticalAnalysis Nethod(s)GENERAL10/22/94 EPA150.1AN IONSCyanide, Distilled(50.010/25/94 EPA335.2I LOG2174}Quality Analytical Laboratories (QAL). Inc. -- Montgomery000006
Report of Analytical ResultsINORGANICSDate Collected:Date Received:10/21/9410/22/94Sample Matrix:WaterClient Sample ID: FB-1Lab ReferenceNum: M8029Lab Sample ID:M8029002Sample Description: DCCATEGORY NAMEAnalytical , DistilledC 5.0ug/LReporting Date ofl«velAnalyticalAnalysis Method(s) W10/22/94 EPA150.15-010/25/94 EPA335.22174)Quality Analytical Laboratories (QAL), Inc. -- Montgomery000007
Report of Analytical ResultsINORGANICSDate Collected:NoneDate Received:NoneSample Matrix:WaterSample Description:Client Sample ID: METHOD BLANKLab ReferenceNum: LABOCLab Sample ID:METHOD BLANKCATEGORY NAMEAnalytical ParameterANIONSCyanide, Distilled(Result 5.0Unitsug/LReporting Date of AnalyticalLevelAnalysis Method(s)5.010/25/94 EPA335.22174)Quality Analytical Laboratories COAL), Inc. -* Montgomery000008
CASE NARRATIVEGC/MS VOLATILE SAMPLESLABORATORY: QAL MONTGOMERYCASE NO.: N/ACLIENT:CONTRACT NO.: N/ALAB REF. NO.: M8029I.BARR15/07-004DERSDG NO.: N/ARECEIPTA.Date:October 22, 1994B.Sample Information:LABSAMPLE IDCLIENTSAMPLE IDM8 WATER10/21/9410/21/9410/21/94N/AWATERN/AEXTRACTION 24/9410/24/9410/25/94C. DocumentationExceptions: As per your request, a special target list isreported for the above samples.No other exceptions were encountered.000009
VOLATILELAB REF. NO. M8029PAGE 2II.Ill.EXTRACTIONA.Holding Times:B.ExtractionExceptionsNot applicable.: Not applicable.ANALYSISA.Holding times: All holding times were met.B. AnalyticalExceptions: All water volatile samples were analyzed using theHC1-preserved vial.No exceptions were encountered.IV.QUALITY CONTROLA. Method BlankB.C.v.SurrogateRecoveriesMatrix SpikeResultsThe associated method blanks met acceptable QCcriteria. The contamination detected in thelaboratory blanks was near or below the detectionlimit and/or not detected for the common laboratorycontaminants (Acetone, Methylene Chloride, and 2Butanone).All surrogate recoveries were within QC limits.The matrix spikes were performed using a sample fromsample delivery group M7989 (M7989001MS andM7989001MSD). A copy of the MS/MSD results areincluded in this package.I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness,except for the conditions detailed above. Release of the data containedin this hardcopy data package has been authorized by the LaboratoryManager or his designee, as verified by the following signature.Deborah BosargeGC/MS SupervisorDateOOOOlf
1AVOLATILE ORGANICS ANALYSIS DATA SHEETLab Name: CH2M HILL/LMGLab Code: LM3EPA SAMPLE NO.WW-lContract: MS029Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: M8029001Sample wt/vol:Lab File ID:Level:(low/med)5.0 (g/mL) MLLOWDate Received: 10/22/94% Moisture: not dec.Column:C1V0033262.DData Analyzed: 10/25/94(pack/cap) CAPDilution Factor: 1.0CONCENTRATION UNITS:CAS NO.COMPOUND(ug/L or ug/Kg) UG/L74-87-3------ - - -Chloromethane75-01-4------ ---Vinyl Chloride75-00-3------ - - -Chloroethane7c nq./ j \j y o. - - -Methylene Chloride75-35-4------ - - - 1 , 1-Dichloroethene75-34-3------ - - - 1 , 1 -Di Chloroethane67-66-3------ - - - Chloroform107-06-2----- ---1,2 -Dichloroethane71-55-6------ - - -1, 1, 1-Tri Chloroethane56-23-5------ ---Carbon Tetrachloride---1,2- Dichloropropane7fl - fl7- i?- - - - * .10061-01-5--- - - - cxs x, j ' ui c n i Oiu mj fsns"7QHIC.- - -Trichloroethene79-00-5------ ---1,1, 2 -Trichloroe thane71-43-2BtrllZellc10061-02-6--- - - -trans-1, 3-Dichloropropene17*71 fl - A . . - - -Tetrachloroethene-L ,/-xo't----Ha* —V Ni nfl - flp - T - - - .---Toluene-- - -Chlorobenzene100-41-4----- - - -Ethylbenzene107-13-1----- - - -Acrylonitrile156-60-5----- - - - trans - 1 , 2 - Di chl oroe t hene1 OR- QO-7-FORM I UU7?1/87 Rev.nnnm 1
LAVOLATILE ORGANICS ANALYSIS DATA SHEETEPA SAMPLE NO.FB-1Lab Name: CH2M HILL/LM3Lab Code: LM3Contract: M8029Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: M8029002Sample wt/vol:Lab File 3D:Level:(low/med)5.0 (g/mL) MLLOWDate Received: 10/22/94% Moisture: not dec.Column:C1V0033247.DData Analyzed: 10/24/94(pack/cap) CAPDilution Factor: 1.0CONCENTRATION UNITS:CAS NO.*7d.-P*77-----it- O i jCOMPOUND(ug/L or ug/Kg) UG/L- - -Chloromethane75-01-4------ ---Vinyl Chloride75-00-3------ - - - Chloroethane75-09-2------ -- -Methyl ene Chloride75-35-4------ ---1,1- Dichloroethene75-34-3------ - - - 1 . l -Dichloroethane67-66-3------ - - - Chloroform107-06-2----- --- 1 , 2 -Dichloroethane71-55-6------ - - - 1, 1, 1-Trichloroethane56-23-5------ ---Carbon Tetrachloride 7QQTC- - - 1 , 2 -Dichloropropane10061-01-5--- - - - cis -1,3 -Dichloropropene79-01-6------ - - -Trichloroethene79-00-5------ ---1,1, 2 -TrichloroethaneT3fvTn *Ff)Tl &71-43-2-----10061-02-6--- - - - trans- 1 , 3 -Dichloropropene1O*7-1Q-4----- - - Tetrachloroethenei no. PA . *a - - - - ---Toluene1 nQ qn-7- - - Chlorobenzene100-41-4----- - - -Ethylbenzene107-13-1----- - - -Acrylonitrile156-60-5----- - - - trans -1,2- DichloroetheneFORM I UU1/87 Rev.0000.12
1AVOLATILE ORGANICS ANALYSIS DATA SHEETEPA SAMPLE NO.TB-1Lab Name: CH2M HILL/LM3Lab Code: LM3Contract: M8029Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: M8029003Sample wt/vol:Lab File ID:Level:5.0 (g/mL) ML(low/med)LOWC1V0033248.DDate Received: 10/22/94% Moisture: not dec.Data Analyzed: 10/24/94Column:Dilution Factor: 1.0(pack/cap) CAPCONCENTRATION UNITS:CAS NO./**Of3COMPOUND(ug/L or ug/Kg) UG/L- - - Chloromethane75-01-4------ ---VinylChloride* j '* t j i * * » * **75-00-3-----75-09-2------ -- -Methyl ene Chloride75-35-4------ - - - 1, 1-Dichloroethenet JL l Xv-aiXCJXlJtsLJJiCtllC75-34-3-----67-66-3------ - - - Chloroform107-06-2----- ---1,2 -Dichloroethane71-55-6------ ---1,1,1- Trichloroethane56-23-5------ - - -Carbon Tetrachloride*7QO "7 C- - - 1 , 2 -Dichloropropane10061-01-5--- - - - cis - 1 , 3 -Dichloropropene79-01-6------ - - -Trichloroethene79-00-5------ ---1,1,2 -Trichloroethane71-43-2------ * - - Benzene10061-02-6--- - - - trans- 1 , 3 -Dichloropropene127-18-4----- - - - Tetrachloroethene---Toluene- - - Chlorobenzene100-41-4----- - - - Ethylbenzene107-13-1----- - - -Acrylonitrile156-60-5----- - - - trans -1,2 -Dichloroethene1 HP- flP - } - - - - -1 Oft- QO - 7- - - - -FORM I uu1/87Rev.000013
EPA SAMPLE NO.1AVOLATILE ORGANICS ANALYSIS DATA SHEETVBLKALLab Name: CH2M HILL/LM3Lab Cede: LM3Contract: M8029Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: X10244B5Sample wt/vol:Lab File ID:Level:(low/med)5.0 (g/mL) MLLOWDate Received: 10/24/94% Moisture: not dec.Column:CBV0033246.DData Analyzed: 10/24/94(pack/cap) CAPDilution Factor: 1.0CONCENTRATION UNITS:CAS NO.COMPOUND(ug/L or ug/Kg) UG/LIA.m - T - - - - - - - - - Chlorome thanef't -OIJ75-01-4------ ---Vinyl Chloride75-00-3------ - - - Chloroethane75-09-2------ ---Methylene Chloride75-35-4------ ---1,1- Dichloroethene75-34-3------ - --1,1-Di chloroethane67-66-3------ - - - Chloroform107-06-2----- - - -1, 2 -Di chloroethane71-55-6------ ---1,1, 1 -Trichloroethane56-23-5------ - - -Carbon Tetrachloride*7fl/ O fl"7O / - -3 - - ----1,2- Dichloropropane10061-01-5--- - - - cis- 1, 3 -Dichloropropene79-01-6------ - - -Trichloroethene79-00-5------ - - - 1, l, 2 -Trichloroethane71-43-2-----0C?I1Z6X1 10061-02-6--- - - - trans -1,3- Dichloropropene127-18-4----- - - -Tetrachloroethenei nfl- flfl- 's . . .---TolueneiUO-OOJi.LUGnp - y\jon - /----7- - - - -- - - Chlorobenzene100-41-4----- - - - Ethylbenzene107-13-1----- - - -Acrylonitrile156-60-5----- - - - trans -1,2- DichloroetHeneFORM I UU1/87 Rev.0000.1
IAVOLATILE ORGANICS ANALYSIS DATA SHEETEPA SAMPLE NO.VBLKAMLab Name: CH2M HILL/LMGLab Code: LM3Contract: M8029Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: X10254B1Sample wt/vol:Lab File ID:Level:5.0 (g/mL) ML(low/med)LOWCBV0033261.DDate Received: 10/25/94tr Moisture: not dec.Data Analyzed: 10/25/94Column:Dilution Factor: 1.0(pack/cap) CAPCONCENTRATION UNITS:CAS NO.COMPOUND(ug/L or ug/Kg) UG/L74-fl7/*» O / 1J - - .-- .-Chloromethane75-01-4------ ---Vinyl Chloride75-00-3------ - --Chlorrxath Ti**- - -Methylene Chloride7C HQ- 9- - - - - -75-35-4------ - - - 1 , 1-Dichloroethene75-34-3------ - - - 1 , 1 -Dichloroethane67-66-3------ - - - Chloroform107-06-2----- - - - 1 , 2 -Dichloroethane71-55-6------ ---1,1,1- Trichloroe thane56-23-5------ - - -Carbon Tetrachloride"7QQT---1,2- DichloropropaneC10061-01-5--- ---cis-l,3-Dichloropropene"7Qrtl C/y-UJ.-o.- - -Trichloroethene79-00-5------ ---1,1,2- Trichloroe thane1 « "i * *71-43-2----Ud. i CX AC10061-02-6--- - - - trans -1,3 -Dichloropropene127-18-4----- - - -Tetrachloroethenei nfl - BR ").--.- - - Toluene1 nfl- QO - 7xuo-su/ - -- ------- - - ChlorobenzeneJ.UO-OOJ--"B* VM rl V sTl TATI 100-41-4----107-13-1----- - - -Acrylonitrile156-60-5----- - - - trans -1,2- DichloroetheneFORM I U1/87 Rev.000015
2AWATER VOLATILE SYSTEM MDNITORINS COMPOUND RECOVERYLab Name: CH2M HILL/LM3Lab Code: LM3Contract: M8029Case No.: M8029EPASAMPLE NO.01 S No.:SDG No. M8029SMC2SMC1SMC3 OTHER(TOL)# (BFB)# 31021415161718192021222324252627282930QC LIMITSSMC1 (TOL) - Toluene-d8SMC2 (BFB) - BrocnofluorobenzeneSMC3 (DCE) - l,2-Dichloroethane-d4(88-110)(86-115)(76-114)# Column to be used to flag recovery values* Values outside of contract required QC limitsD Surrogates diluted outpage 01 of 01FORM II VOA-11/87 Rev.000016
3AWATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERYLab Name: CH2M HILL/LMGLab Code: LM3Contract: M7989Case No.: M7989SAS No.:SDG No.: M7989Matrix Spike - EPA Sample No.: NSP-1SPIKEADDEDCOMPOUND(ug/L)1 , 1 -DichloroetheneTri chloroetheneBenzene5050505050TolueneChl TION CONCENTRATION%LIMITSREC # REC.(ug/L)(ug/L)(ug/L)1 , 1 -DichloroetheneTri chloroetheneBenzeneTolueneChl L)REC # RPD -14571-12076-12776-12575-130QC -130# Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limitsRPD: 0 out of 5 outside limitsSpike Recovery: 0 out of 10 outside limitsCOMMENTS:FORM III VOA-11/87 Rev.000017
CASE NARRATIVEGC/MS SEMIVOLATILE SAMPLESLABORATORY: QAL MONTGOMERYCASE NO.: N/ACLIENT:CONTRACT NO.: N/ALAB REF. NO.: M8029I.BARR15/07-004DERSDG NO.:N/ARECEIPTA.Date:October 22, 1994B.Sample Information:LABCLIENTSAMPLESAMPLE IDSAMPLE /25/9410/25/94N/ADocumentationExceptions: No exceptions were encountered.000018
SEMIVOLATILELAB REF. NO. MS029PAGE 2II.EXTRACTIONA. Holding Times: All holding times were met.B. ExtractionExceptionsIII.ANALYSISA.Holding times: All holding times were met.B. AnalyticalExceptionsIV.: No exceptions were encountered.: No exceptions were encountered.QUALITY CONTROLA. Method Blank : The associated method blank met acceptable QCcriteria.B.C.SurrogateRecoveries: All surrogate recoveries were within QC limits.Matrix SpikeResults: The matrix spikes were performed using a sample fromsample delivery group M7976 (M7976001MS andM7976001MSD). The percent recovery for 1,2,4Trichlorobenzene was lower than advisory QC limitsin the matrix spike duplicate. All other percentrecoveries were within advisory QC limits. A copyof the MS/MSD results are included in this package.V.I certify that this data package is in compliance with the terms andconditions of the contract, both technically and for completeness, forother than the conditions detailed above. Release of the data containedin this hardcopy data package has been authorized by the LaboratoryManager or his designs , as verified, by the following signature./oDeborah Bosarge/]DateGC/MS Supervisor000019
IBSEMIVOLATILE ORGANICS ANALYSIS DATA SHEETEPA SAMPLE NO.WW-1Lab Name: CH2M KELL/LMGLab Code:Contract:Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: M8029001Sample wt/vol:Lab File ID:Level:1000 (g/mL) ML(low/med)LOW% Moisture: not dec.Extraction:Date Received: 10/22/940Date Extracted:10/24/94dec. Date Analyzed: 10/25/94(SepF/Cont/Sonc) SEPFGPC Cleanup:H0001684.D(Y/N) NDilution Factor: 1.0pH: 8.0CONCENTRATION UNITS:CAS NO.(ug/L or ug/Kg) UG/LCOMPOUND541-73-1---- ----1,3 -Dichlorobenzene106-46-7---- . . . . it 4 -Dichlorobenzene95-50-1----- ---- 1 , 2 -Dichlorobenzene67-72-1----- - - - - Hexachloroethane. -Nitrobenzene- - -- 2 - Ni trophenolQQ - 7 ;. P. .91-20-3----- - - - -Naphthalene- - - -Hexachlorobutadiene91-57-6----- - . . -2-Methylnaphthaleneonp yoQC P. .4\jo o- - - -Acenaphthylene- - - -Acenaphtheneci TO e----2,4- Dini trophenol100-02-7---- . . 4 . Ni trophenol- - - -DibenzofuranP ?. . piuorene534-52-1---- - - - -4, 6-Dinitro-2-methylphenol118-74-1---- - - - - Hexachlorobenzene- - - -Phenanthrene120-17-7- - - - - - - -Anthraceneone. AA n - - - - Fluoranthene129-00-0---- - - - - Pyrene56-55-3----- - - - - Benzo (a) anthracene91 fl-Dl -Q- - - - - - - - Chrysene- - - - Benzo (b) f luorantheneon7 na Q- - - -Benzo (k) f luorantheneP"! O-Q n 19 a193-39-5---- - - - - Indeno (1 , 2 , 3 -cd) pyrene53-70-3----- - - - -Dibenz (a , h) anthracene1 Q1 -9A-9- - - -Benzo (g, h, i) peiyleneFORM I 71011196108UUUUUUUUJUUJUUJUJ1/87 Rev.000020
EPA SAMPLE NO.IBSEMTVOLATILE ORGANICS ANALYSIS DATA SHEETFB-1Lab Name: CH2M HILL/IMSLab Code:Contract:Case No.: M8029SAS No.:SDG No.: M8029Matrix: (soil/water) WATERLab Sample ID: M8029002Sample wt/vol:Lab File ID:Level:1000 (g/mL) ML(low/med)LOW% Moisture: not dec.Extraction:Date Received: 10/22/940dec.Date Extracted:10/24/94(SepF/Cont/Sonc) SEPFGPC Cleanup:H0001683.D(Y/N) NDate Analyzed: 10/25/94Dilution Factor: 1.0pH: 5.0CONCENTRATION UNITS:CAS NO.COMPOUND(ug/L or ug/Kg) UG/L541-73-l--------l,3-Dichlorobenzene106-46 -7- - - - - - - phthylene83-32-9--------- Acenaphthene51-28-5---------2,4-Dinitrophenol100- 02-7- -------4-Nitrophenol132 - 64-9--------Dibenzofuran86-73-7--------- Fluorene534-52 -- Hexachlorobenzene85-01-8--------- Phenanthrene120-12 - 7--------Anthracene206-44-0-------- Benzo(b)fluoranthene08-9--------Benzo(k) f z (a, h) anthracene191-24-2--------Benzo (g,h,i)peryleneFORM I 10101010101010uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu1/87 Rev.000021
IBSEMTVOLATILE ORGANICS ANALYSIS DATA SHEETEPA SAMPLE NO.SBLKBRLab Name: CH2M HILL/LMGLab Code:Contract:Case No.: M8029SAS No.:SDG NO.: M8029Matrix: (soil/water) WATERLab Sanple ID: W10244B1Sanple wt/vol:Lab File ID:Level:1000 (g/mL) ML(low/med)Extraction:Date Received: 10/24/94LOW% Moisture: not dec.0Date Extracted:10/24/94dec.Date Analyzed: 10/25/94(SepF/Cont/Sonc) SEPFGPC Cleanup:(Y/N) NH0001680.DDilution Factor: 1.0pH: 6.0CONCENTRATION UNITS:CAS NO.COMPOUND(ug/L or ug/Kg) cenaphthylene83-32-9--------- 132-64-9--------Dibenzof nitro-2-methylphenol118-74 -1 --------Hexachlorobenzene 07-08 -B--------Benzo (k) f luoranthene50-32- 8---------Benzo(a) pyrene193-39-5--------Tndeno(1.2 3-cd)pyrene53-70-3---------Dibenz (a, h) anthracene191-24-2- -------Benzo (g, h, i) perylene5010105010101010101010101010101010FORM I SV-1uuuuuuuuuuuuuuuuuuuuuuuuuuuuuu1/87 Rev.000022
2CWATER SEMTVDLATTLE SURROGATE RECOVERYLab Name: CH2M HILL/LMGLab Code:Contract:Case No.: M8029EPASAMPLE NO.OTHEK TOTS2S5S6SIS4S3OUT(NBZ)# (FBP)# (TPH)# (PHL)# (2FP)# (TBP)#01 SBLKBR80746802 FB-103 27282930515253545556SDG No. : M8029SAS No.:(NBZ)(FBP)(TPH)(PHL)(2FP)(TBP)8878709287101Ni t 88000QC LIMITS(35-114)(43-116)(33-141)(10- 94)(21-100)(10-123)# Column to be used to flag recovery values* Values outside of contract required QC limitsD Surrogate diluted outpage 01 of 01FORM II SV-l1/87 Rev.000023
3CWATER SEMTVDIATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERYLab Name: CH2M HILL/LM3Lab Code: LM3Contract: M7976Case No.:M7976SAS No.:SDG No.:M7976Matrix Spike - EPA Sample No.: DSN002SPIKECOMPOUNDADDED(ug/L)Phenol2 - Chlorophenol1 , 4 -DichlorobenzeneN-Nitroso-di-n-prop. (l)1,2, 4 -Trichlorobenzene4 -Chloro- 3 -MethylphenolAcenaphthene4-Nitrophenol2 , 4 QC.SAMPLE%LIMITSCONCENTRATION CONCENTRATION(ug/L)REC ft REC.(ug/L)(ug/L)Phenol2 - Chl orophenoll , 4 -DichlorobenzeneN-Nitroso-di-n-prop. (1)1,2,4 -Trichlorobenzene4 -Chloro- 3 -Methylphenol4 - Nit rophenol2 , 4 109097830000MSDMSD%CONCENTRATION%(ug/L)REC # RED 71214151514202091648 12-11070 27-12344 36- 9783 41-11642 39- 9870 23- 9769 46-11855 10- 8090 24- 96489-10383 26-127QC L:EMITSRPDREC.42 12-11040 27-12328 36- 9738 41-11628 39- 9842 23- 9731 46-11850 10- 8038 24- 96509-10331 26-127(l) N-Nitroso-di-n-propylamine# Column to be used to flag recovery and RPD values with an asterisk* Values outside of QC limitsRPD: 0 out of 11 outside limitsSpike Recovery: 1 out of 22 outside limitsCOMMENTS:FORM III SV-11/87 Rev.000024
Barr.Chuin of8300 Norman Ctmitr DrtvtMimmtapoUt. MN 55437-1026(612) 832-2600Distribution: While-Original Accompanies Shipment to Lab; Yellow - Field Copy; Pink - Lab Coordinator
QUALITY ANALYTICAL LABORATORIES, INC. R E F * VE D OCT28 October 27, 1994 ENGINEERING CO. LMG10002.XY Ms. Marti Harding-Smith Barr engineering Company fp/. 8300 Norman Center Drive "v 1Q 1334 Suite 300 Minneapolis, Minnesota 55437-1026 RX: Analytical Data for 15/07-004DXR024 LMG Laboratory Reference No. M8029 Dear Ms. Harding-Smitht
