Industrias AlEn 2 Research & Development 1 0 Safety Data Sheet

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2Industrias AlEnResearch & DevelopmentSafety Data SheetSAP Code01ALKSDS FP-6050451SECTION 1 – IDENTIFICATIONManufacturerMexico emergency telephoneFaxALEN DEL NORTE S.A. DE C.V.01 800 834 33 00 52 (81) 81221099AddressEmergency telephone number (US)CHEMTRACBlvd. Díaz Ordaz No. 1000, Los Treviño, Santa Catarina, N.L.C.P. 66150, MéxicoFor domestic shipments800 424 9300For shipments outside US703 527 3887Product NameMULTIPURPOSE CLEANER PINALEN ORIGINALChemical NameCAS NumberNANASynonyms/Trade NamesPine oil emulsionApplicationRestrictions on useHousehold multipurpose cleanerThis product is not intended for industrial uses or as a sanitizing agent.SECTION 2 – HAZARDS IDENTIFICATIONClassification: Skin Irritation Cat. 3Eye Irritation Cat. 2BAquatic Acute Toxicity Cat. 3This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).Signal word:WarningHazard Statements:H316 Causes mild skin irritation.H320 Causes eye irritation.H402 Harmful to aquatic life.Pictograms:No pictogram required.

Precautionary Statements Prevention:Avoid contact with skin, eyes and clothing. Wash handsthoroughly after handling. Avoid release of large quantities tothe environment. Storage:Keep out of reach of children. Keepcontainers closed when not in use. Storein a cool, dry area. Keep away from heat,sparks or open flame. Response:IF IN EYES: Hold eye open and rinse slowly and gently withwater for 15-20 minutes. IF ON SKIN: Take off contaminatedclothing. Rinse skin with plenty of water for 15 – 20 minutes.IF SWALLOWED: Get prompt medical attention. Give aglassful of water. Do not induce vomiting. Disposal:Dispose in accordance with all applicablelocal, state and federal regulations.Hazard not otherwise classified:Repeated or prolonged contact may cause skin sensitization.Unknown Toxicity: Not applicable.SECTION 3 – COMPOSITION / INFORMATION ON INGREDIENTSHazardous IngredientsChemical/Common NameComposition RangeCAS NumberPine oil2.0 – 8.08002-09-3Lauric acid, sodium salt (dodecanoic acid, sodium salt)1.2 – 2.5629-25-4SECTION 4 – FIRST-AID MEASURESFor treatment advice, call a Poison Control Center or a doctor.Ingestion Do not induce vomiting.Drink large quantities of water or milk.Apply other supportive measures as indicated by the patient’s clinical condition.Get immediate medical attention. Remove patient from exposure to fresh air.Get medical attention if respiratory irritation is present or if breathing is difficult. Remove patient from exposure.Rinse affected area with plenty of water and soap for at least 15 minutes, while removing all soiled clothing.Get medical attention if irritation develops or persists. Remove patient from exposure.Remove contact lenses if necessary and immediately irrigate the affected eye thoroughly with water or 0.9%saline for at least 10-15 minutes, until no evidence of chemical remains.Get medical attention.Inhalation SkinEyes Most important symptoms and effects:Irritation of eyes and/or skinIndication of any immediate medical attention andspecial treatment needed:Treat symptomatically.MULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451Rev. 1Page 2 of 7

SECTION 5 – FIRE-FIGHTING MEASURESFlash Point ( C)Test methodNot determined----FlammabilityExplosive limits in airNANAExtinguishing media:Water spray XCO2 XFoamOtherUnusual fire and explosion hazards: NASpecial protective equipment: Full breathing apparatus and fire-fighting equipment.Special fire-fighting procedures: Use water spray to keep containers cool.Conditions to avoid: Heat, sparks, open flame and other sources of ignition.Hazardous combustion products: Carbon monoxide and carbon dioxide.SECTION 6 – ACCIDENTAL RELEASE MEASURESPersonal precautionsGloves XLatexGoggles XBoots XApron XOtherEmergency Procedures in case of release or spillage:Large spills: Wear protective equipment, remove sources of ignition, sweep up the material, use absorbentmaterial like sand or saw dust, collect in closed containers, wash area with water because thesurface may be slippery.Small spills: Wash area with plenty of water and dispose the material in accordance with all local, state andfederal regulations. Avoid heat, sparks, open flame and other sources of ignition. Avoid contact withskin, eyes and clothing.Environmental precautions: Do not allow product to enter lakes, rivers or streams. The product is harmful to fish.See section 12 for ecological information.Methods and Materials for Containment and Cleaning up:Use absorbent material and collect in closed containers, wash with plenty water, and conduct to sanitarytreatment facility.SECTION 7 – HANDLING AND STORAGEPrecautions for safe handling: Use with adequate ventilation. Avoid contact with skin, eyes and clothing. Donot eat, drink, or smoke when using the product. Do not mix with acids and other cleaning products.Recommendations on the conditions for safe storage: Keep out of reach of children. Keep containers closedwhen not in use. Store in a cool, dry area. Keep away from heat, sparks or open flame.MULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451Rev. 1Page 3 of 7

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTIONExposure limits:Hazardous IngredientsChemical/Common NameCAS NumberACGIH TLVOSHA PEL/NIOSHRELPine oil8002-09-3TLV: Not estab.NDLauric acid, sodium salt (dodecanoic acid,sodium salt)629-25-4Not listedNot listedAppropriate engineering controls:Eye washersVentilation requirementsGeneral ventilation X Local ventilationUnnecessary in normal cond.Work practices: Handle according to good industrial hygiene and safety practices.SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIESAppearance:Color and odor:Clear liquidLight yellow and characteristic pine oil smellBoiling point ( C):95.0Flash point ( C):Melting or freezing point:NDNDDecomposition temperature:NDFire point ( C):NAAuto ignition temperature ( C):NDDensity (g/ml):0.99 – 1.01Vapor density:NDVolatility:NDVapor pressure (mmHg @ 20 C):NDUpper explosion limit (%):NAViscosity (cPs):NASolubility in others:NDMolecular weight:Percent volatile 100 C:Lower explosion limit (%):pH:Solubility in water:Partition coefficient:n-octanol / waterNA95.0NA12.0 – 12.45CompleteNDOdor threshold:NDSECTION 10 – STABILITY AND REACTIVITYReactivity:May react with acidic and other cleaning products.Chemical stability:Stable XUnstableUnder recommended storage conditionsMULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451Rev. 1Page 4 of 7

Possibility of hazardous reactions:Not under normal handling of product.Conditions to avoid:None known.Incompatible zardous decomposition products:Carbon dioxide and carbon monoxide may be produced.Hazardous polymerization:Will not occur XMay occurSECTION 11 – TOXICOLOGICAL INFORMATIONInformation on the likely routes of exposureContact viaAcuteChronicIngestionMay cause irritation to intestinal mucous.NAInhalationNone under normal use conditionsNone under normal use conditionsSkinMay cause skin irritation.Repeated or prolonged contact maycause an allergic skin reaction.EyesCauses eye irritation.NASymptoms:Redness of eyes and/or skin.Chronic effects from short and long-term exposure:CarcinogenicMutagenicTheratogenicIncuded inNOM 010STPSIncluded inother referencesNational Toxicology Program (NTP) Report on Carcinogens: Not listed.International Agency for Research on Cancer (IARC) Monographs: Not listed.OSHA: Not listed.Complementary informationChemical NameLD50 OralAnimal SpeciesPine oil3,200 mg/kgRatLauric acid, sodium salt(dodecanoic acid, sodium salt)1,008.7 mg/kgRat (intraperitoneal)MULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451Rev. 1Page 5 of 7

SECTION 12 – ECOLOGICAL INFORMATIONEcotoxicity: Harmful to aquatic life (fish and other aquatic invertebrates). Do not allow product to enter lakes,rivers or streams.Persistence and degradation in environment: Product is readily biodegradable.Test of bioaccumulation: No information availableOther adverse effects : No information availableSECTION 13 – DISPOSAL CONSIDERATIONSWaste disposal methods: Dispose in accordance with all applicable local, state and federal regulations.Contaminated packaging: Do not reuse empty containers.SECTION 14 – TRANSPORT INFORMATIONRegulationProper Shipping acking GroupNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedNot regulatedLand TransportationDOT (USA)Land TransportationTDG (Canada)Land TransportationADR (Europe)Air TransportationIATA (International)Water TransportationIMDG (International)SECTION 15 – REGULATORY INFORMATIONRCRA (40 CFR 261, Subpart D):New JerseySubstance List:Not applicable.This product contains the following componentssubject to reporting requirements: Pine oil.Clean Water Act:Pennsylvania Hazardous Substance ListNot applicable.Not applicable.Clean Air Act:Massachusetts Substance List:Not applicable.Not applicable.SARA Sections 301-304 (Threshold Planning Quantity- TPQ) 40 CFR 355:State Of Illinois Substance List:MULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451RighttoKnowRev. 1HazardousPage 6 of 7

Not applicable.Not applicable.Section 313 (Toxic Chemical Release Reporting) 40CFR 372:Michigan Critical Materials Register:Not applicable.Not applicable.CERCLA Section 102 (Reportable Quantity - RQ):Canada (WHMIS) - listed material:Not applicable.Not applicable.CaliforniaPropositionreproductive toxins65CarcinogensandTSCA Section 8(b) Inventory Status:All ingredients listed in this product are listed in theTSCA Inventory or are not required to be listed inthe TSCA Inventory.Not applicable.SECTION 16 – OTHER INFORMATIONHMIS Classification (USA)HealthFlammabilityPhysical HazardPersonal ProtectionNFPA Aerosol Level:NANA: Not ApplicableTLV: Threshold Limit ValuesND: Not Determined120BHMIS LetterRequired EquipmentASafety glasses.BSafety glasses, gloves.CSafety glasses, gloves, protective apron.DFace shield, gloves, protective apron.ESafety glasses, gloves, dust respirator.FGSafety glasses, gloves, protective apron, dust respirator.Safety glasses, gloves, vapor respirator.HSplash glasses, gloves, protective apron, vapor respirator.ISafety glasses, gloves, dust respirator, vapor respirator.Safety glasses, gloves, protective apron, dust respirator, vaporrespirator.Air line mask or hood, gloves, full suit, boots.JKCreation date:Last revision date:Next revision date:Created by:27/07/201724/07/2019Gerardo Urbina PachecoDISCLAIMERThe submission of this MSDS may be required by law, but this is not an assertion that the substance ishazardous when used in accordance with proper safety practices and normal handling procedures. Data suppliedis for use only in connection with occupational safety and health and not for consumer use. The informationcontained herein has been compiled from sources considered by Industrias AlEn to be dependable and isaccurate to the best of the Company’s knowledge. The information relates to the specific material designatedherein, and does not relate to the use in combination with any other material or any other process. IndustriasAlEn assumes no responsibility for injury to the recipient or third persons, for any damage to any property frommisuse of the controlled product.MULTIPURPOSE CLEANER PINALEN ORIGINAL – SDS FP-6050451Rev. 1Page 7 of 7

MULTIPURPOSE CLEANER PINALEN ORIGINAL - SDS FP-6050451 Rev. 1 Page 2 of 7 Precautionary Statements Prevention: Avoid contact with skin, eyes and clothing. Wash hands thoroughly after handling. Avoid release of large quantities to the environment. Storage: Keep out of reach of children. Keep