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ZG 90 Cold Zinc Galvanise AerosolSAFETY DATA SHEETACCORDING TO EC-REGULATIONS 1907/2006 (REACH), 1272/2008 (CLP) & 453/20101. SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING1.11.21.31.4Product identifierProduct NameTrade NamePart No.CAS No.EINECS No.REACH Registration No.Relevant identified uses of the substance ormixture and uses advised againstIdentified use(s)Uses advised againstDetails of the supplier of the Safety Data SheetCompany IdentificationTelephoneFaxE-mailEmergency telephone numberEmergency Phone No.ZG 90 Cold Zinc Galvanise Aerosol.ZG 90 Cold Zinc Galvanise Aerosol.1785Mixture.Mixture.None assigned.Surface coating.None known.Action Can Ltd.,Dixon Close,Old Boston Trading Estate,Haydock, St. Helens,Merseyside. WA11 9SF.01942 71366701942 716235info@actioncan.com01942 713667 (Mon - Fri: 9am to 5pm)2. SECTION 2: HAZARDS IDENTIFICATION2.12.2Classification of the substance or mixtureRegulation (EC) No. 1272/2008 (CLP)Aerosol 1; Extremely flammable aerosol.Pressurised container: May burst if heated.Eye Irrit. 2; Causes serious eye irritation.STOT SE 3; May cause drowsiness or dizziness.Aquatic Chronic 2; Toxic to aquatic life with long lastingeffects.Repeated exposure may cause skin dryness or cracking.Label elementsProduct NameHazard pictogram(s)According to Regulation (EC) No. 1272/2008 (CLP)ZG 90 Cold Zinc Galvanise Aerosol.Signal word(s)Revision: 1GHS02Danger.Page: 1/9GHS07GHS09Date: 11/06/2014
ZG 90 Cold Zinc Galvanise AerosolHazard statement(s)H222: Extremely flammable aerosol.H229: Pressurised container: May burst if heated.H319: Causes serious eye irritation.H336: May cause drowsiness or dizziness.H411: Toxic to aquatic life with long lasting effects.EUH066: Repeated exposure may cause skin dryness orcracking.P210: Keep away from heat, hot surfaces, sparks, openflames and other ignition sources. No smoking.P211: Do not spray on an open flame or other ignitionsource.P251: Do not pierce or burn, even after use.P280: Wear protective gloves/protective clothing/eyeprotection/face protection.P410 P412: Protect from sunlight. Do not expose totemperatures exceeding 50 C/ 122 F.P305 P351 P338: IF IN EYES: Rinse cautiously with waterfor several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing.Precautionary statement(s)2.3Other hazardsNone.2.4Additional InformationFor full text of H/P phrases see section 16.3. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTSProduct as supplied: Aerosol.3.1 MixturesEC Classification No. 1272/2008Hazardous%W/Wingredient(s)Dimethyl etherCAS No.EC No.50 – 80115-10-6204-065-8REACHRegistrationNo.None assignedZinc Dust SuperFinen-butyl acetate 257440-66-6231-175-3None assigned2.5-10123-86-4204-658-1None assignedButanone2.5-1078-93-3201-159-0None assignedEthyl acetate 2.5141-78-6205-500-4None assignedToluene 2.5108-88-3203-625-9None assignedAluminium 2.57429-90-5231-072-3None assignedRevision: 1Page: 2/9Hazard pictogram(s) and Hazardstatement(s)GHS02, Flam. Gas 1; H220,GHS04, Press. Gas: Liquefied gas;H280GHS09, Aquatic Acute 1; H400,Aquatic Chronic 1; H410GHS02, Flam. Liq. 3; H226, GHS07,STOT SE 3; H336, EUH066GHS02, Flam. Liq. 2; H225, GHS07,Eye Irrit. 2; H319, STOT SE 3;H336, EUH066GHS02, Flam. Liq. 2; H225, GHS07,Eye Irrit. 2; H319, STOT SE 3;H336, EUH066GHS02, Flam. Liq. 2; H225, GHS07,Skin Irrit. 2; H315, STOT SE 3;H336, GHS08, Asp. Tox. 1; H304,Repr. 2; H361d, STOT RE 2; H373GHS02, Pyr. Sol. 1; H250, Waterreact. 2; H261Date: 11/06/2014
ZG 90 Cold Zinc Galvanise AerosolSolvent naphtha(petroleum), lightarom. 2.564742-95-6265-199-0None assignedGHS02, Flam. Liq. 3; H226GHS07, Acute Tox. 4; H332, SkinIrrit. 2; H315, Eye Irrit. 2; H319,STOT SE 3; H335GHS08, Asp. Tox. 1; H304GHS09, Aquatic Chronic 2; H4113.2 Additional InformationFor full text of H/P phrases see section 16.4. SECTION 4: FIRST AID MEASURES4.1Description of first aid measuresInhalationSkin ContactEye Contact4.24.3IngestionMost important symptoms and effects, bothacute and delayedIndication of any immediate medical attentionand special treatment neededIF INHALED: Remove person to fresh air and keepcomfortable for breathing. Call a POISON CENTER/doctor ifyou feel unwell.After contact with skin, wash immediately with plenty ofsoap and water.IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continuerinsing. If eye irritation persists: Get medicaladvice/attention.Unlikely route of exposure. IF SWALLOWED: Rinse mouth.May cause drowsiness or dizziness.Causes serious eye irritation.Repeated exposure may cause skin dryness or cracking.Unlikely to be required but if necessary treatsymptomatically.5. SECTION 5: FIRE-FIGHTING MEASURESPressurised container: May burst if heated.5.15.25.3Extinguishing MediaSuitable Extinguishing MediaUnsuitable Extinguishing MediaSpecial hazards arising from the substance ormixtureAdvice for fire-fightersRevision: 1In case of fire: Use water spray, dry powder or carbondioxide to extinguish.Do not use water jet.Heating may cause pressure rise with risk of bursting.Fire fighters should wear complete protective clothingincluding self-contained breathing apparatus. If it is safe todo so, containers should be removed from fire area becausethey are likely to rupture under fire conditions. Keep fireexposed containers cool by spraying with water.Page: 3/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise Aerosol6. SECTION 6: ACCIDENTAL RELEASE MEASURESThe product is an aerosol. It is unlikely to present spillage or leakage hazard. In case of rupture, released content shouldbe contained as any other solvent spill.6.1Personal precautions, protective equipmentand emergency procedures6.2Environmental precautions6.3Methods and material for containment andcleaning up6.4Reference to other sectionsEliminate sources of ignition. Ensure adequate ventilation.Stop leak if safe to do so. Avoid breathing vapours. Wearprotective gloves/eye protection/face protection.Do not allow to enter drains, sewers or watercourses.Spillages or uncontrolled discharges into watercourses mustbe alerted to the appropriate regulatory body.Collect mechanically and dispose of according to Section 13.Adsorb spillages onto sand, earth or any suitable adsorbentmaterial. Transfer to a lidded container for disposal orrecovery. Containers must not be punctured or destroyed byburning, even when empty.See Also Section: 8, 13.7. SECTION 7: HANDLING AND STORAGE7.1Precautions for safe handling7.2Conditions for safe storage, including anyincompatibilitiesStorage TemperatureStorage LifeIncompatible materialsSpecific end use(s)7.3Keep away from heat, hot surfaces, sparks, open flames andother ignition sources. No smoking. Do not spray on an openflame or other ignition source. Do not pierce or burn, evenafter use. Use only outdoors or in a well-ventilated area.Avoid breathing vapours. Wear protective gloves/eyeprotection/face protection.Wash hands and exposed skinafter use.Protect from sunlight. Store in a well-ventilated place. Keepcontainer tightly closed.Do not expose to temperatures exceeding 50 C/ 122 F.Stable under normal conditions.Strong oxidising agents, Acids.Surface coating.8. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION8.18.1.1Control parametersOccupational Exposure LimitsSUBSTANCEDimethyl ethern-butyl acetateButanoneEthyl acetateTolueneCAS No.115-10-6123-86-478-93-3141-78-6108-88-3LTEL (8 hr TWAppm)40015020020050LTEL (8 hr TEL(mg/m³)9589668991460384NoteWELWELWELWELWELWEL: Workplace Exposure Limit (UK HSE EH40)8.1.2Biological limit valueNot established.8.1.3PNECs and DNELsNot established.Revision: 1Page: 4/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise Aerosol8.28.2.1Exposure controlsAppropriate engineering controls8.2.2Personal protection equipmentEye/face protection8.2.3Provide adequate ventilation. Use only outdoors or in a wellventilated area.Wear eye protection with side protection (EN166).Skin protection (Hand protection/ Other)Wear suitable gloves if prolonged skin contact is likely. Wearimpervious gloves (EN374).Respiratory protectionWear suitable respiratory protective equipment. A suitablemask with filter type A (EN14387 or EN405) may beappropriate.Thermal hazardsNot applicable.Environmental Exposure ControlsAvoid release to the environment.9. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES9.19.2Information on basic physical and chemicalpropertiesAppearanceColourOdourOdour ThresholdpHMelting Point/Freezing PointInitial boiling point and boiling rangeFlash PointEvaporation rateFlammability (solid, gas)Upper/lower flammability or explosive limitsDensityVapour pressureVapour densityRelative densitySolubility(ies)Partition coefficient: n-octanol/waterAuto-ignition temperatureIgnition temperatureDecomposition TemperatureDynamic viscosityKinematic ViscosityExplosive propertiesOxidising propertiesOther informationOrganic solventsSolid ContentRevision: 1Aerosol.Grey.Characteristic.Not determined.Not determined.Not determined.-24 C-42 CNot applicable.Aerosol 1; Extremely flammable aerosol.3.0 – 18.6 Vol-%0.738 g/cm³@ 20 C5200 hPa @ 20 CNot available.Not determined.Insoluble in water.Not determined.The product is not self-igniting.235 CNot determined.Not determined.Not determined.Not explosive.Pressurised container: May burst if heated.Not oxidising.None.88.7%10.5%Page: 5/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise Aerosol10. SECTION 10: STABILITY AND al stabilityPossibility of hazardous reactionsConditions to avoidIncompatible materialsHazardous Decomposition Product(s)Stable under normal conditions.Stable under normal conditions.Stable under normal conditions.Heat and direct sunlight.Strong oxidising agents, Acids.Carbon monoxide, Carbon dioxide.11. SECTION 11: TOXICOLOGICAL INFORMATION11.1Information on toxicological effects11.1.1 MixturesAcute sitisationRepeated dose toxicityCarcinogenicityMutagenicityToxicity for reproductionOther informationLow oral toxicity.May cause drowsiness or dizziness.Causes serious eye irritation.Repeated exposure may cause skin dryness or cracking.Not classified.It is not a skin sensitiser.None anticipated.No evidence of carcinogenicity.There is no evidence of mutagenic potential.None anticipated.None.12. SECTION 12: ECOLOGICAL INFORMATION12.112.212.312.4ToxicityPersistence and degradabilityBioaccumulative potentialMobility in soil12.512.6Results of PBT and vPvB assessmentOther adverse effectsToxic to aquatic life with long lasting effects.The product is readily biodegradable.The product has low potential for bioaccumulation.Insoluble in water. The product is predicted to have lowmobility in soil.Not classified as PBT or vPvB.None.13. SECTION 13: DISPOSAL CONSIDERATIONS13.1Waste treatment methods13.2Additional InformationRevision: 1Recycle only completely emptied packaging. Containersmust not be punctured or destroyed by burning, even whenempty. Non-emptied aerosol: Dispose of wastes in anapproved waste disposal facility. Do NOT landfill.Disposal should be in accordance with local, state ornational legislation. Do not allow to enter drains, sewers orwatercourses.Page: 6/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise Aerosol14. SECTION 14: TRANSPORT INFORMATION14.114.214.314.414.514.614.714.8UN numberUN Proper Shipping NameADR/RID/ADN/IMDGICAO/IATATransport hazard class(es)ADR/RID/ADNIMDG/ICAO/IATAPacking GroupEnvironmental hazardsSpecial precautions for userTransport in bulk according to Annex II ofMARPOL73/78 and the IBC CodeAdditional InformationIMDG CodeLimited Quantity (LQ)UN 1950AEROSOLS.AEROSOLS, FLAMMABLE.22.1None.Classified as a Marine Pollutant.None.Not applicable.F-D, S-U1L15. SECTION 15: REGULATORY INFORMATION15.1Safety, health and environmentalregulations/legislation specific for the substanceor mixture15.1.1 EU regulationsAuthorisations and/or restrictions on useCandidate List of Substances of Very High Concernfor AuthorisationREACH: ANNEX XVII Restrictions on themanufacture, placing on the market and use ofcertain dangerous substances, preparations andarticlesREACH: ANNEX XIV List of substances subject toauthorisationCommunity Rolling Action Plan (CoRAP);Draft 26/03/201415.1.2 National regulationsTechnical Instructions (air)15.2GermanyChemical Safety AssessmentAll chemicals are not listed.Listed: Toluene (CAS No.: 108-88-3)All chemicals are not listed.Listed: Toluene (CAS No.: 108-88-3)None known.ClassShare in %NK88.7WGK 1 (Slightly hazardous for water.)Not available.16. SECTION 16: OTHER INFORMATIONThe following sections contain revisions or new statements: 1-16.LEGENDLTELSTELDNELPNECPBTvPvBADNADRRevision: 1Long Term Exposure LimitShort Term Exposure LimitDerived No Effect LevelPredicted No Effect ConcentrationPersistent, Bioaccumulative and Toxicvery Persistent and very BioaccumulativeEuropean transport by inland waterwaysAccord européen relatif au transport international des marchandises dangereuses par route(European Agreement concerning the International Carriage of Dangerous Goods by Road)Page: 7/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise AerosolICAOIMDGIATARIDWGKAcute Tox. 4Aerosol 1Aquatic Acute 1Aquatic Chronic 1Aquatic Chronic 2Asp. Tox. 1Eye Irrit. 2Flam. Gas 1Flam. Liq. 2Flam. Liq. 3Press. GasPyr. Sol. 1STOT RE 2STOT SE 3Skin Irrit. 2Repr. 2Water-react. 2International transport by airInternational Maritime Code for Dangerous GoodsInternational Air Transport AssociationEuropean transport by railWassergefährdungsklasse (Germany)Acute toxicity Category 4Aerosol Category 1Hazardous to the aquatic environment Acute Category 1Hazardous to the aquatic environment Chronic Category 1Hazardous to the aquatic environment Chronic Category 2Aspiration hazard Category 1Serious eye damage/irritation Category 2Flammable gas Category 1Flammable Liquid Category 2Flammable Liquid Category 3Gases under pressurePyrophoric solid Category 1Specific target organ toxicity — repeated exposure Category 2Specific target organ toxicity — single exposure Category 3skin corrosion/irritation Category 2Reproductive toxicity Category 2Substance or mixture which in contact with water emits flammable gas Category 2Hazard Statement(s) and Precautionary Statement(s)H220Extremely flammable gas.H222Extremely flammable aerosol.H225Highly flammable liquid and vapour.H226Flammable liquid and vapour.H229Pressurised container: May burst if heated.H250Catches fire spontaneously if exposed to air.H261In contact with water releases flammable gases.H280Contains gas under pressure; may explode if heated.H304May be fatal if swallowed and enters airways.H315Causes skin irritation.H319Causes serious eye irritation.H331Toxic if inhaled.H332Harmful if inhaled.H335May cause respiratory irritation.H336May cause drowsiness or dizziness.H361dSuspected of damaging fertility or the unborn child.H372Causes damage to organs through prolonged or repeated exposure.H373May cause damage to organs through prolonged or repeated exposure.H400Very toxic to aquatic life.H410Very toxic to aquatic life with long lasting effects.H411Toxic to aquatic life with long lasting effects.EUH066Repeated exposure may cause skin dryness or cracking.P261Avoid breathing vapours.P264Wash (hands and exposed skin) thoroughly after handling.P271Use only outdoors or in a well-ventilated area.P273Avoid release to the environment.P312Call a POISON CENTER/doctor if you feel unwell.P391Collect spillage.P304 P340IF INHALED: Remove person to fresh air and keep comfortable for breathing.P337 P313If eye irritation persists: Get medical advice/attention.P403 P233Store in a well-ventilated place. Keep container tightly closed.Revision: 1Page: 8/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise AerosolHazard formation contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in goodfaith, but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose.Action Can Ltd. gives no warranty as to the fitness of the product for any particular purpose and any implied warranty orcondition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law. Action Can Ltd.accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product, ifproved), resulting from reliance on this information. Freedom under Patents, Copyright and Designs cannot be assumed.Annex to the extended Safety Data Sheet (eSDS)No information available.Revision: 1Page: 9/9Date: 11/06/2014
ZG 90 Cold Zinc Galvanise Aerosol Revision: 1 Page: 6/9 Date: 11/06/2014 10. SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity Stable under normal conditions. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Stable under normal conditions. 10.4 Conditions to avoid Heat and direct sunlight. 10.5 Incompatible materials Strong oxidising agents, Acids.
