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Safety Data SheetRevision Number: 004.0Issue date: 08/30/20171. PRODUCT AND COMPANY IDENTIFICATIONProduct name:LOCTITE 567 TB 250ML ENProduct type:Anaerobic SealantRestriction of Use:None identifiedCompany address:Henkel Canada CorporationMeadowpine Boulevard 2515Mississauga, Ontario L5N 6C3IDH number:2087069Item number:2087069Region:CanadaContact information:Telephone: 1 (905) 814-6511MEDICAL EMERGENCY Phone: Poison Control Center1-877-671-4608 (toll free) or 1-303-592-1711TRANSPORT EMERGENCY Phone: CHEMTREC1-800-424-9300 (toll free) or 1-703-527-3887Internet: www.henkelna.com2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWWARNING:CAUSES SKIN IRRITATION.MAY CAUSE AN ALLERGIC SKIN REACTION.CAUSES SERIOUS EYE IRRITATION.HAZARD CLASSHAZARD CATEGORY22A1SKIN IRRITATIONEYE IRRITATIONSKIN SENSITIZATIONPICTOGRAM(S)Precautionary id breathing vapors, mist, or spray. Wash affected area thoroughly after handling.Contaminated work clothing should not be allowed out of the workplace. Wear protectivegloves, eye protection, and face protection.IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for severalminutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation orrash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take offcontaminated clothing.Not prescribedDispose of contents and/or container according to Federal, State/Provincial and localgovernmental regulations.Classification complies with Canadian Hazardous Products Regulations (WHMIS 2015) and is consistent with the provision of the UnitedNations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).See Section 11 for additional toxicological information.3. COMPOSITION / INFORMATION ON INGREDIENTSIDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 1 of 6
Hazardous Component(s)CAS NumberWeight %*3,3,5 Trimethylcyclohexyl methacrylateEthene, homopolymerEthene, tetrafluoro-, homopolymerTitanium dioxideSilica, amorphous, fumed, crystal-freePropane-1,2-diolCumene 3-67-7112945-52-557-55-680-15-998-82-820 - 305 - 105 - 101-51-51-50.1 - 10.1 - 1* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.4. FIRST AID MEASURESInhalation:Not available.Skin contact:Not available.Eye contact:Not available.Ingestion:Not available.Symptoms:See Section 11.5. FIRE FIGHTING MEASURESExtinguishing media:Water spray (fog), foam, dry chemical or carbon dioxide.Special firefighting procedures:Wear self-contained breathing apparatus and full protective clothing, such asturn-out gear. In case of fire, keep containers cool with water spray.Unusual fire or explosion hazards:Uncontrolled polymerization may occur at high temperatures resulting inexplosions or rupture of storage containers.Hazardous combustion products:Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics.Toxic fluorine compounds. Ketones.6. ACCIDENTAL RELEASE MEASURESUse personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotectedpersonnel.Environmental precautions:Do not allow product to enter sewer or waterways.Clean-up methods:Remove all sources of ignition. Evacuate and ventilate spill area; dike spill toprevent entry into water system; wear full protective equipment during cleanup. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,universal binder, sawdust). Scrape up as much material as possible. Store in apartly filled, closed container until disposal. Refer to Section 8 "ExposureControls / Personal Protection" prior to clean up.IDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 2 of 6
7. HANDLING AND STORAGEHandling:Use only with adequate ventilation. Prevent contact with eyes, skin andclothing. Do not breathe vapor and mist. Wash thoroughly after handling.Keep container closed. Refer to Section 8.Storage:Keep in a cool, well ventilated area away from heat, sparks and open flame.Keep container tightly closed until ready for use.Shelf Life Statement: Not available.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEmployers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposurecontrols and protective equipment for each task performed.Hazardous Component(s)ACGIH TLVOSHA PELAIHA WEELOTHERNoneNone15 MPPCF TWARespirable fraction.15 mg/m3 TWATotal dust.50 MPPCF TWATotal dust.5 mg/m3 TWARespirable fraction.5 mg/m3 PELRespirable fraction.15 mg/m3 PELTotal dust.NoneNoneNoneNoneNoneNoneNone10 mg/m3 TWATotal dust.5 mg/m3 TWARespirable fraction.10 mg/m3 TWA15 mg/m3 PELTotal dust.15 MPPCF TWARespirable fraction.15 mg/m3 TWATotal dust.50 MPPCF TWATotal dust.5 mg/m3 TWARespirable fraction.NoneNone10 mg/m3 TWAInhalable dust.3 mg/m3 TWARespirable fraction.20 MPPCF TWA0.8 mg/m3 TWANoneNonePropane-1,2-diolNoneNoneCumene hydroperoxideNoneNone50 ppm TWA50 ppm (245mg/m3) PEL(SKIN)3,3,5 Trimethylcyclohexyl methacrylateEthene, homopolymerEthene, tetrafluoro-, homopolymerTitanium dioxideSilica, amorphous, fumed, crystal-freeCumene10 mg/m3 TWAInhalable particles.3 mg/m3 TWARespirableparticles.10 mg/m3 TWAAerosol.1 ppm (6 mg/m3)TWA(SKIN)NoneNoneNoneNoneEngineering controls:Provide adequate local exhaust ventilation to maintain worker exposure belowexposure limits.Respiratory protection:Use NIOSH approved respirator if there is potential to exceed exposurelimit(s).IDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 3 of 6
Eye/face protection:Safety goggles or safety glasses with side shields. Full face protection shouldbe used if the potential for splashing or spraying of product exists. Safetyshowers and eye wash stations should be available.Skin protection:Use chemical resistant, impermeable clothing including gloves and either anapron or body suit to prevent skin contact. Neoprene gloves.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state:Color:Odor:Odor threshold:pH:Vapor pressure:Boiling point/range:Melting point/ range:Specific gravity:Vapor density:Flash point:Flammable/Explosive limits - lower:Flammable/Explosive limits - upper:Autoignition temperature:Flammability:Evaporation rate:Solubility in water:Partition coefficient (n-octanol/water):VOC content:Viscosity:Decomposition temperature:Paste, LiquidOff whiteMildNot available.Not available.Not available. 149 C ( 300.2 F)no methodNot available.1.15Not available. 93 C ( 199.4 F)Not available.Not available.Not available.Not applicableNot available.Not available.Not available.0.13 % (ASTM D5403)Not available.Not available.10. STABILITY AND REACTIVITYStability:Stable under normal conditions of storage and use.Hazardous reactions:None under normal processing. Polymerization may occur at elevated temperature or in thepresence of incompatible materials.Hazardous decompositionproducts:Oxides of carbon and nitrogen, aldehydes, acids and undetermined organics. Toxic fluorinecompounds. Ketones.Incompatible materials:Strong oxidizing agents. Strong reducing agents. Free radical initiators. Inert gases. Oxygenscavengers.Reactivity:Not available.Conditions to avoid:Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away fromincompatible materials.11. TOXICOLOGICAL INFORMATIONRelevant routes of exposure:Skin, Inhalation, Eyes, IngestionIDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 4 of 6
Potential Health Effects/SymptomsInhalation:Skin contact:Eye contact:Ingestion:Inhalation of vapors or mists of the product may be irritating to the respiratory system.Causes skin irritation. May cause allergic skin reaction.Causes serious eye irritation.May cause gastrointestinal tract irritation if swallowed.Hazardous Component(s)LD50s and LC50sImmediate and Delayed Health Effects3,3,5 Trimethylcyclohexyl methacrylateEthene, homopolymerEthene, tetrafluoro-, homopolymerNoneNoneNoneTitanium dioxideNoneNo RecordsNo Target OrgansNo Target OrgansIrritant, Respiratory, Some evidence ofcarcinogenicityNuisance dustSilica, amorphous, fumed, crystal-freePropane-1,2-diolNoneOral LD50 (Rabbit) 18 g/kgOral LD50 (Mouse) 23.9 g/kgOral LD50 (Rat) 30 g/kgIrritantCumene hydroperoxideInhalation LC50 (Mouse, 4 h) 200 mg/lCumeneOral LD50 (Rat) 2.91 g/kgOral LD50 (Rat) 1,400 mg/kgInhalation LC50 (Rat, 4 h) 8000 ppmHazardous Component(s)3,3,5 Trimethylcyclohexyl methacrylateEthene, homopolymerEthene, tetrafluoro-, homopolymerTitanium dioxideSilica, amorphous, fumed, crystal-freePropane-1,2-diolCumene hydroperoxideCumeneAllergen, Central nervous system, Corrosive,Irritant, MutagenCentral nervous system, Irritant, LungOSHA CarcinogenNTP CarcinogenIARC CarcinogenNoNoNoNoNoNoNoReasonably Anticipated to bea Human Carcinogen.NoNoNoGroup 2BNoNoNoNoNoNoNoNoNoNoGroup 2BNo(Specifically Regulated)12. ECOLOGICAL INFORMATIONEcological information:Not available.13. DISPOSAL CONSIDERATIONSInformation provided is for unused product only.Recommended method of disposal:Follow all local, state, federal and provincial regulations for disposal.14. TRANSPORT INFORMATIONThe transport information provided in this section only applies to the material/formulation itself, and is not specific to anypackage/configuration.Canada Transportation of Dangerous Goods - GroundProper shipping name:Not regulatedHazard class or division:NoneIdentification number:NonePacking group:NoneInternational Air Transportation (ICAO/IATA)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNoneIDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 5 of 6
Water Transportation (IMO/IMDG)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNone15. REGULATORY INFORMATIONCanada Regulatory InformationCEPA DSL/NDSL Status:One or more components are not listed on, and are not exempt from listing on either theDomestic Substances List or the Non-Domestic Substances List.United States Regulatory InformationTSCA 8 (b) Inventory Status:All components are listed or are exempt from listing on the Toxic Substances Control ActInventory.16. OTHER INFORMATIONThis safety data sheet contains changes from the previous version in sections: 2Prepared by:Sheila Gines, Regulatory Affairs SpecialistIssue date:08/30/2017DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, HenkelCorporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methodsHenkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methodsmentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property andpersons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particularpurpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damagesof any kind, including lost profits.IDH number: 2087069Product name: LOCTITE 567 TB 250ML ENPage 6 of 6
Product name: LOCTITE 567 TB 250ML EN IDH number: 2087069 Product type: Anaerobic Sealant Item number: 2087069 Restriction of Use: None identified Region: Canada Company address: Contact information: Henkel Canada Corporation Meadowpine Boulevard 2515 Mississauga, Ontario L5N 6C3 Telephone: 1 (905) 814-6511 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671
