Safety Data Sheet - Chemoventory.tcc.fl.edu

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Safety Data SheetRevision Number: 005.1Issue date: 06/08/20151. PRODUCT AND COMPANY IDENTIFICATIONProduct name:LOCTITE SF 7625 RUST TREATMENTknown as Loctite(R) Extend(R) RustTreaRust converterNone identifiedProduct type:Restriction of Use:Company address:Henkel CorporationOne Henkel WayRocky Hill, Connecticut 06067IDH number:234928Item number:30539Region:United StatesContact information:Telephone: (860) 571-5100MEDICAL EMERGENCY Phone: Poison Control Center1-877-671-4608 (toll free) or 1-303-592-1711TRANSPORT EMERGENCY Phone: CHEMTREC1-800-424-9300 (toll free) or 1-703-527-3887Internet: www.henkelna.com2. HAZARDS IDENTIFICATIONEMERGENCY OVERVIEWDANGER:CONTENTS UNDER PRESSURE.EXTREMELY FLAMMABLE AEROSOL.HARMFUL IF SWALLOWED.CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.MAY CAUSE DROWSINESS OR DIZZINESS.HAZARD CLASSFLAMMABLE AEROSOL.ACUTE TOXICITY ORALSKIN CORROSIONSERIOUS EYE DAMAGESPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSUREHAZARD CATEGORY141B13PICTOGRAM(S)Precautionary StatementsPrevention:Response:Storage:Disposal:IDH number: 234928Keep away from heat, sparks, open flames, hot surfaces - no smoking. Do not spray on anopen flame or other ignition source. Do not pierce or burn, even after use. Do not breathe mistor spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.Use only outdoors or in a well-ventilated area. Wear protective gloves, eye protection, and faceprotection.If SWALLOWED: Immediately call poison control or physician if you feel unwell. IFSWALLOWED: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediatelyall contaminated clothing. IF INHALED: Remove person to fresh air and keep comfortable forbreathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Immediately call a poison control center or physician.Wash contaminated clothing before reuse.Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50 C/122 F.Dispose of contents and/or container according to Federal, State/Provincial and localProduct name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 1 of 6

governmental regulations.Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of theUnited Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).See Section 11 for additional toxicological information.3. COMPOSITION / INFORMATION ON INGREDIENTSHazardous Component(s)CAS NumberPercentage*2-ButoxyethanolAcetoneButyral resinFormic acid3,4,5-Trihydroxybenzoic acid111-76-267-64-1Proprietary64-18-6149-91-730 - 6030 - 605 - 105 - 100.1 - 1* Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections.4. FIRST AID MEASURESInhalation:Move to fresh air. If breathing is difficult, give oxygen. If not breathing, giveartificial respiration. Seek medical advice.Skin contact:Remove contaminated clothing and footwear. Wash with soap and water. Ifsymptoms develop and persist, get medical attention. Wash clothing beforereuse.Eye contact:Immediately flush eyes with water for at least 15 minutes, while holdingeyelids open. Seek medical attention at once.Ingestion:Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult adoctor.Symptoms:See Section 11.5. FIRE FIGHTING MEASURESExtinguishing media:Carbon dioxide. Dry chemical. foamSpecial firefighting procedures:Use water spray to keep fire exposed containers cool and disperse vapors.Wear self-contained breathing apparatus and full protective clothing, such asturn-out gear.Unusual fire or explosion hazards:Closed containers may rupture (due to build up of pressure) when exposed toextreme heat. Vapours may accumulate in low or confined areas, travelconsiderable distance to source of ignition, and flash back.Hazardous combustion products:Oxides of carbon. Hydrocarbons6. ACCIDENTAL RELEASE MEASURESUse personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotectedpersonnel.Environmental precautions:Do not allow material to contaminate ground water system. Do not let productenter drains. Absorb spill with inert material. Shovel material into appropriatecontainer for disposal.Clean-up methods:Absorb the spilled material with an inert absorbent (nonflammable) material.IDH number: 234928Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 2 of 6

7. HANDLING AND STORAGEHandling:Avoid breathing mists or aerosols of this product. Keep away from sources ofignition - no smoking. Avoid contact with eyes, skin and clothing.Storage:Store in a cool, dry area. Keep containers closed when not in use.8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEmployers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposurecontrols and protective equipment for each task performed.Hazardous Component(s)ACGIH TLV2-Butoxyethanol20 ppm TWA750 ppm STEL500 ppm TWANone5 ppm TWA10 ppm STELNoneAcetoneButyral resinFormic acid3,4,5-Trihydroxybenzoic acidOSHA PEL50 ppm (240 mg/m3)PEL(SKIN)1,000 ppm (2,400mg/m3) PELNone5 ppm (9 mg/m3)PELNoneAIHA ngineering controls:Provide adequate local exhaust ventilation to maintain worker exposure belowexposure limits.Respiratory protection:Use NIOSH approved respirator if there is potential to exceed exposurelimit(s).Eye/face protection:Safety goggles or safety glasses with side shields. Full face protection shouldbe used if the potential for splashing or spraying of product exists.Skin protection:Use impermeable gloves and protective clothing as necessary to prevent skincontact.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state:Color:Odor:Odor threshold:pH:Vapor pressure:Boiling point/range:Melting point/ range:Specific gravity:Vapor density:Flash point:Flammable/Explosive limits - lower:Flammable/Explosive limits - upper:Autoignition temperature:Evaporation rate:Solubility in water:Partition coefficient (n-octanol/water):VOC content:Viscosity:Decomposition temperature:IDH number: 234928Aerosol, LiquidTranslucentAcetoneNot available.Not available.Not available.Not available.Not available.1.0000Not available. -17.7 C ( 0.14 F) ; This product exhibits no flashback when tested forflame extension.1.1 %57 %Not available.Not available.Not available.Not available.50.4 %Not available.Not available.Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 3 of 6

10. STABILITY AND REACTIVITYStability:StableHazardous reactions:Will not occur.Hazardous decompositionproducts:Irritating organic vapours. Oxides of carbon.Incompatible materials:Acids and bases. Oxidizing agents.Reactivity:Not available.Conditions to avoid:Keep away from heat, spark and flame.11. TOXICOLOGICAL INFORMATIONRelevant routes of exposure:Skin, Inhalation, Eyes, IngestionPotential Health Effects/SymptomsInhalation:Skin contact:Eye contact:Ingestion:Hazardous Component(s)2-ButoxyethanolAcetoneButyral resinFormic acid3,4,5-Trihydroxybenzoic acidHazardous Component(s)2-ButoxyethanolAcetoneButyral resinFormic acid3,4,5-Trihydroxybenzoic acidVapours may cause drowsiness and dizziness.Causes skin burns.Causes serious eye damage.Harmful if swallowed.LD50s and LC50sImmediate and Delayed Health EffectsOral LD50 (RAT) 560 mg/kgOral LD50 (RABBIT) 0.32 g/kgOral LD50 (RAT) 1.48 g/kgDermal LD50 (RABBIT) 400 mg/kgInhalation LC50 (RAT, 4 h) 486 ppmInhalation LC50 (RAT, 4 h) 450 ppmOral LD50 (RABBIT) 5,340 mg/kgOral LD50 (RAT) 5,800 mg/kgOral LD50 (RAT) 9,800 mg/kgDermal LD50 (RABBIT) 20,000 mg/kgInhalation LC50 (RAT, 8 h) 50.1 mg/lInhalation LC50 (RAT, 4 h) 76 mg/lNoneOral LD50 (RAT) 730 mg/kgInhalation LC50 (RAT, 15 min) 15 mg/lInhalation LC50 (RAT, 4 h) 7.4 mg/lOral LD50 (RABBIT) 5.0 g/kgBlood, Central nervous system, Irritant,Kidney, LiverBlood, Central nervous system, Irritant,ReproductiveNo RecordsCentral nervous system, Corrosive, Irritant,Kidney, MetabolicIrritant, Central nervous systemNTP CarcinogenIARC CarcinogenNoNoNoNoNoNoNoNoNoNoOSHA Carcinogen(Specifically Regulated)NoNoNoNoNo12. ECOLOGICAL INFORMATIONEcological information:IDH number: 234928Not available.Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 4 of 6

13. DISPOSAL CONSIDERATIONSInformation provided is for unused product only.Recommended method of disposal:Not available.Hazardous waste number:D001: Ignitable.14. TRANSPORT INFORMATIONThe transport information provided in this section only applies to the material/formulation itself, and is not specific to anypackage/configuration.U.S. Department of Transportation Ground (49 CFR)Proper shipping name:Aerosols, flammableHazard class or division:2.1Identification number:UN 1950Packing group:NoneDOT Hazardous Substance(s):AcetoneInternational Air Transportation (ICAO/IATA)Proper shipping name:Hazard class or division:Identification number:Packing group:Aerosols, flammable2.1UN 1950NoneWater Transportation (IMO/IMDG)Proper shipping name:Hazard class or division:Identification number:Packing group:Additional information:AEROSOLS2.1UN 1950NoneIMDG-Code: Segregation group 1- Acids15. REGULATORY INFORMATIONUnited States Regulatory InformationTSCA 8 (b) Inventory Status:TSCA 12 (b) Export Notification:CERCLA/SARA Section 302 EHS:CERCLA/SARA Section 311/312:CERCLA/SARA Section 313:CERCLA Reportable quantity:California Proposition 65:All components are listed or are exempt from listing on the Toxic Substances Control ActInventory.None above reporting de minimisNone above reporting de minimisImmediate Health, Delayed Health, Fire, Sudden ReleaseThis product contains the following toxic chemicals subject to the reporting requirements ofsection 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40CFR 372). 2-Butoxyethanol (CAS# 111-76-2).Acetone (CAS# 67-64-1) 5,000 lbs. (2,270 kg)Formic acid (CAS# 64-18-6) 5,000 lbs. (2,270 kg)This product contains a chemical known in the State of California to cause cancer. Thisproduct contains a chemical known to the State of California to cause birth defects or otherreproductive harm.Canada Regulatory InformationCEPA DSL/NDSL Status:All components are listed on or are exempt from listing on the Canadian DomesticSubstances List.16. OTHER INFORMATIONThis safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.IDH number: 234928Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 5 of 6

Prepared by:Catherine Bimler, Regulatory Affairs SpecialistIssue date:06/08/2015DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, HenkelCorporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methodsHenkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methodsmentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property andpersons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particularpurpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damagesof any kind, including lost profits.IDH number: 234928Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust TreaPage 6 of 6

IDH number: 234928 Product name: LOCTITE SF 7625 RUST TREATMENT known as Loctite(R) Extend(R) Rust Trea Page 6 of 6 Prepared by: Catherine Bimler, Regulatory Affairs Specialist Issue date: 06/08/2015 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume .