Manufacturing Process Of Adhesives, Glues And Resins

Transcription

Formulation andManufacturing Process ofAdhesives, Gluesand Resins(Glues of Animal Origin, Fish Glues, Animal Glues,Amino Resin Adhesives, Epoxy Resin Adhesives,Phenolic Resin Adhesives, Rosin Adhesives, AlkydResins, Hydrocarbon Resins, Polyurethane Resins)

An adhesive or glue is a material, usually in a liquid or semi liquid state,that adheres or bonds items together. Adhesives come from eithernatural or synthetic sources. The types of materials that can be bondedare vast but they are especially useful for bonding thin materials.Adhesives cure (harden) by either evaporating a solvent or by chemicalreactions that occur between two or more constituents. Animal glues areessentially high polymer proteins; these glues find application in a widerange of industrial uses. Fish glue as the name indicates, is obtained asthe byproduct of the fish skin industry, was the first liquid glue thatreached commercial importance and was forerunner of all householdglues.www.entrepreneurindia.co

Resins are used in the manufacture of adhesives, paints andnumber of other products. Polyesters are thermosetting andthermoplastic resins for various applications. Due to high cost theyare used with other resins for the application of adhesives.Polyamide resins used in adhesives can be divided into four usedclasses; thermoset adhesives, nylon epoxy adhesives, thermosetplastic adhesives and thermoplastic thermoset adhesives. Theadhesives industry has found its place in many industries and willsurely spread to many other fields. It is used in building, es.Thefutureadvancement and consumption are practically beyond mentalcomprehension.www.entrepreneurindia.co

Even today, as ones surroundings are observed, the use of adhesives,glues and resins are associated with almost every product that ismarketed. While use of all adhesives has increased, the greatest gain hasoccurred in the synthetic resin category. The synthetic resin adhesive isthe most important for packaging uses. Pressure sensitive adhesive is afast growing segment of the industry. This field includes productsdesigned for the industrial trade but which can, by minor modification, bemarketed through the hardware dealer and variety store. Adhesives forthis growing market range from the simplest glues and mucilage forfurniture making and repair, to metal to metal bonding for frameconstruction.www.entrepreneurindia.co

Adhesives are the most adaptable bonding agents available in the market,which remained unaffected by the recent global slowdown due to theirapplication in a wide variety of end-user industries. The major orkingandconstruction industry. India adhesives market has recorded strong growthduring the period FY’2010-FY’2015 and is expected to sustain its rapidgrowth during the next five years.The adhesive industry was dominated by a few industrialized countries.Now, a significant portion of new demand is being generated by emergingcountries such as China. The next major growth country could be India.Market fragmentation continues as new adhesive demand is generatedfrom a supply and demand standpoint.www.entrepreneurindia.co

The demand growth is also supported by the emergence of new marketapplications that result from changing substrates and evolving assemblyprocesses. Increasing use of adhesives in automotive manufacturingcontributes to overall growth in the global adhesive resins market. Theconstruction sector, automotive market, and medical adhesives markethave all seen growth or resurgence that is contributing to a projectedincrease in the world-wide market for adhesive resins. Adhesives offerdistinct advantages over mechanical fastening, sewing, and thermalbonding. Adhesives can bind diverse materials, distribute stress evenlyacross a joint and reduce cost. In addition, adhesive bonds are oftenmore aesthetically pleasing and contribute to the value of consumerproducts.www.entrepreneurindia.co

Asia-Pacific is the biggest and the fastest growing region dueto the growing demand for adhesive resins in India, China,Japan, South Korea, and Australia. North America is amatured market and is expected to grow with a CAGR till2020. The adhesive resin market demand, in terms of valueand volume, depicts the current and future projectionsaccording to the parallel economic and industrial outlook.www.entrepreneurindia.co

Some of the fundamentals of the book are glues of animal origin, fishglues, manufacture of animal glues, casein glues and adhesives, spraydried melamine formaldehyde resins, epoxy resin adhesives, specialtyepoxy resins & derivatives, polychloroprene resin adhesives, phenolicresin adhesives, resorcinolic adhesives, ethylene copolymer hot meltadhesives, isocyanate adhesives, polyamide adhesives, rosin adhesives,silicone adhesives and sealants, applications in pressure sensitiveadhesives, starch adhesives, acrylic adhesives and sealants, pressuresensitive adhesives, amorphous polypropylene and petroleum resin,alkyd resins, use of alkyds in trade sales finishes, etc.The present book covers manufacturing aspects of various adhesives,glues and resins. This will be very helpful to new entrepreneurs,technocrats, technical institutes and existing units.www.entrepreneurindia.co

Table of ContentsADHESIVES1. Glues of Animal OriginPropertiesMethods of ManufactureCommercial Grades and SpecificationsMethods of AnalysisSamplingProcedureIdentificationPhysical MeasurementsDetermination of Other Constituents2. Fish GluesIntroductionManufacturing ProcessPropertieswww.entrepreneurindia.co

Applications & er-or Cork-to-PlywoodPaper-to-SteelStraight Line Gluing3. Animal GluesIntroductionChemical CompositionManufacture of Animal GluesPropertiesLiquid Animal GluesFormulation & ApplicationsMethods of Application4. Casein Glues and ia.co

Casein Blend GluesLime free Casein AdhesivesApplicationsCasein Adhesives for Bonding PaperCasein Adhesive for Binding Dissimilar Materials5. Blood Albumen GluesIntroductionSolubility CategoriesPropertiesBlood-Soybean Flour CombinationsMold ResistanceApplication6. Amino Resin AdhesivesIntroductionManufacturing TechnologyUrea Adhesive for PlywoodUrea Adhesive for Particle Boardwww.entrepreneurindia.co

Spray Dried Melamine-formaldehyde ResinsFoundry ResinAniline-Formaldehyde Resinà Represents benzene ringSulfonamide-Formaldehyde ResinsApplicationsAdhesives for Hardwood PlywoodSand Core BinderWater Proof Corrugated BoardCompounding and Formulation7. Cyanoacrylate AdhesivesIntroductionBonding with CyanoacrylatesAdhesive PropertiesApplicationswww.entrepreneurindia.co

8. Epoxy Resin AdhesivesIntroductionChemistryEpoxy Novolac ResinsFlexible Epoxy ResinsEpoxidized OlefinsSpeciality Epoxy Resins & DerivativesEpoxy Esters of RosinEpoxy Esters of Styrenated RosinEpoxy Esters of Disproportionated RosinEpoxy Novolac EstersEpoxy Ester of Maleopimaric AcidCompoundingCuring atorsSpeciality AdditivesManufacture of Adhesiveswww.entrepreneurindia.co

9. Phenolic Resin AdhesivesIntroductionResole resinNovalac ResinsManufactureApplications and FormulationsContact AdhesivesAdhesive CompoundingNitrile/Phenolic Contact AdhesivesStructural AdhesivesVinyl/PhenolicEpoxy/PhenolicHot Melt AdhesivesHot Melt Vinyl Film to Wood Laminating AdhesivesPressure Sensitive Adhesives (PSA)www.entrepreneurindia.co

10. Polychloroprene Resin AdhesivesIntroductionTypes of PolychloropreneApplications and FormulationsApplications11. Polyester Resin AdhesivesIntroductionLinear PolycarbonatesPolymerized OilsAlkyd ResinsUnsaturated Polyester AdhesivesAdhesives for Flexible Printed CircuitAllyl Ester Adhesives12. Polyethyleneimine in AdhesivesIntroductionApplicationsGeneral AdhesivesTie Coat Adhesiveswww.entrepreneurindia.co

13. Polysulfide Sealants and AdhesivesIntroductionPolysulfide SealantsChemistryCompoundingCuring AgentRetarderReinforcementAdhesion AdditivesPrimersImproved Heat ResistanceApplicationsAdhesives from Polysulfide Liquid PolymerEpoxy Resin Reactions14. Resorcinolic AdhesivesIntroductionResorcinol-Phenol Formaldehyde ResinsModified Resorcinol Resinswww.entrepreneurindia.co

Aspects of Adhesion MechanismFormulation of Glue MixturesLaminating15. Ethylene Copolymer Hot Melt ssure Sensitive TackHot Melt Adhesive FormulatingBook Binding AdhesivesCarton and Case Sealing AdhesivesCarpet ApplicationShoe AdhesivesPressure Sensitive Adhesives (PSA)Furniture Adhesives16. Furan Resin AdhesivesIntroductionwww.entrepreneurindia.co

IntroductionAdvantages of Isocyanate AdhesivesDisadvantages of IsocyanatesApplicationsTypes and uses of Isocyanate based Adhesive System18. Lignin AdhesivesIntroductionFormulations19. Polyamide AdhesivesIntroductionClass I: Thermoset Adhesives Containing Liquid Polyamide CuringAdhesivesClass II: Nylon-Epoxy ResinsClass III: Thermoplastic Hot Melt Polyamide AdhesivesClass IV: Thermoplastic-Thermoset Adhesiveswww.entrepreneurindia.co

20. Polyimide AdhesivesIntroductionAdhesive and Bonding TechnologyFoam System21. Rosin nt AdhesivesEmulsion AdhesivesHot Melt AdhesivesMethods of manufacture22. Silicone Adhesives and SealantsIntroductionChemistryOxime silanePropertieswww.entrepreneurindia.co

Rheological CharacteristicsThermal StabilityWeathering CharacteristicsAdhesion 3. Tannin AdhesivesIntroductionFormulation24. Terpene Based AdhesivesIntroductionChemistryBeta-pinene resinsDipentene resinsAlpha-pinene resinsPhysical characteristics of resinswww.entrepreneurindia.co

Pressure sensitive adhesivesHot melt adhesivesAnalytical methodsCommercial resins and their usesCommercial productionApplications in pressure sensitive adhesivesApplications in hot melt adhesives25. Starch AdhesivesIntroductionUnmodified StarchesHigh Strength AdhesiveCheap Diluted AdhesiveNon-weather Proof Corrugated Board AdhesiveWater Resistant Corrugated Paper Box AdhesiveFinal MixtureAcid Modified or Thin Boiling Starch AdhesiveOxidised Starch AdhesivesDextrin Based AdhesivesPropertieswww.entrepreneurindia.co

26. Acrylic Adhesives and SealantsPolymerizationSolution PolymerizationProperties of the productEmulsion polymerizationProperties of the dispersionPropertiesFormulations and ApplicationsAdhesives to paper coated with PVDCDelayed tack adhesiveAdhesives for LaminatingLaminating Plasticized PVC film to textilesLaminating PVC film to particle boardLaminating plasticized PVC film to split leatherHigh temperature &pressure laminationFlocking AdhesivesBuilding AdhesivesAdhesives for plasticized PVC floor tilesAdhesives for ceramic tileswww.entrepreneurindia.co

Pressure-Sensitive AdhesivesFlame Resistant & Pressure Sensitive AdhesiveAcrylic SealantsAqueous Acrylic SealantsSolvent-Based Acrylic Sealants27. Pressure Sensitive AdhesivesAdhesive Strip for Antomotive TrimEva-Trialkyl Cyanurate Copolymer AdhesiveCarboxylate Polymer Based AdhesivesFumaric Diester Vinyl Acetate Polymer28. Hot melt tionsEthylene-vinyl Acetatewww.entrepreneurindia.co

Amorphous polypropylene and Petroleum ResinIsopropenyltoluene Copolymers as TackifiersChlorinated Polyphenyl, ChlorinatedPolyisoprene and Nitroso CompoundCarpet Backing FormulationOther Polyolefin CompositionsAmorphous Polyolefin and Styrene ButadieneBlock Copolymersï ¡-Methylstyrene Tert Butyl Styreneolefin terpolymersAlkoxystyrene-Acrylonitrile, CopolymersBoric Acid as Viscosity Stabiliser in EthylenePropylene AdhesivesThermoplastic Polymer and Chelate of AminoaceticAcidCoal Tar Pitch and Ethylene-Acrylic-Acid CopolymerWater-Moistenable Vinyl ia.co

RESINS1. Alkyd ationAddition reactions of unsaturated monobasicfatty acidsAddition reactions with other unsaturated alkyd ingredientsReactions during coating formation with dryingalkydsReactions during coating formation in alkyd blendsRaw materialsManufactureHealth and SafetyQuality Control and SpecificationsAnalysiswww.entrepreneurindia.co

CalculationsUsesUse of Alkyds in Trade-Sales FinishesMethods of AnalysisDetermination of CompositionChemical MethodsDetermination of Properties and Impurities2. Acrylic Modified Alkyd ResinsTraffic paintsIndustrial applicationsConclusion3. Alkyd-Amino Combinations Based on Neem OilAim of present investigationUses of oils in surface coatingsNeem oilAlkyd resinsAmino resinswww.entrepreneurindia.co

Experiments & ResultsPreparation of alkyd resinAlkyd resin preparationPreparation of amino resinTesting of performances of resin samplesDiscussionAnalysis of neem oilPreparation of alkyd from neem oilPreparation of urea formaldehyde resinPreparation of thiourea formaldehyde resinPreparation of various samples (mixtures)Performances of various resin samplesScratch hardnessConclusion4. Amino ResinsIntroductionRaw materialsChemistry of resin formationwww.entrepreneurindia.co

Typical resin formulations and techniquesUrea formaldehyde resinsHigh solids urea-formaldehyde adhesive resinProtective coating resin with high mineral spiritstoleranceMethylated urea formaldehyde textile resinsUrea-formaldehyde particle board adhesiveMelamine-formaldehyde resinsButylated melamine protective coating resinChlorine resistant melamine resinTrimethoxymethyl melamineHexamethoxymethyl melamineMelamine resin molding powderMelamine resin acid colloidControl of the extent of the reactionFree formaldehyde estimationViscosity testsSolubility testsCure testswww.entrepreneurindia.co

Urea versus melamine resinsPackage stabilityCompetitive product analysisChemical modification for water soluble productsChemical modification for oil soluble productsEthyleneureaMethylated uron textile resinsUron resinsGlyoxal resinsMiscellaneous resinsAmino resins in the paper industryFormulations for regular and HE colloidsToxcityMethods of AnalysisCompetitive Product Analysis5. Carbohydrate Modified Phenol-formaldehyde ResinsIntroductionResearch on Carbohydrate Modified Resinswww.entrepreneurindia.co

Carbohydrate-Modified Base-Catalyzed PF resinsBonding Veneer PanelsBonding Flakeboard PanelsCarbohydrate-Modified PF Resins Cured atNeutral ConditionsBonding Veneer PanelsColor of BondlineConclusions6. Epoxy ResinsIntroductionSynthesis of Resin IntermediatesCycloaliphatic epoxiesEpoxidized polyolefinsEpoxidised oils and fatty acid estersAliphatic-cycloaliphatic glycidyl type resinsEpoxy novolac resinsResins from phenols other than bisphenol AResins from aliphatic polyolsResins from long chain acidswww.entrepreneurindia.co

Fluorinated epoxy resinsEpoxy resins from methylepichlorohydrinMiscellaneous epoxy resinsEpoxy estersWater borne epoxy resins and derivativesDiluents and modifiersEpoxide reactions and curing mechanismsCuring of epoxy esters7. Hydrocarbon ResinsTypes of Hydrocarbon ResinsRaw MaterialsProperties of Hydrocarbon ResinsMethods of ManufactureCommercial Resin Types and SpecificationsMethods of AnalysisAnalysis of Raw MaterialsDetermination of Chemical PropertiesDetermination of Physical Propertieswww.entrepreneurindia.co

8. Polyurethane ResinsChemistryRaw materialsIsocyanatesTolylene diisocyanate (TDI)4,4' diphenylmethane diisocyanate (MDI)Hexamethylene diisocyanate (HDI)Other diisocyanates used in coating systemsHydroxy componentHazards of isocyanatesClassification of polyurethanesUrethane oils and urethane alkydsMoisture-cured urethanesDrying epreneurindia.co

Film properties and usesTypical formulationsManufactureBlocked isocyanate systemsTwo-component catalyst-cured polyurethanesTwo-component polyol type polyurethanes9. Phenolic ResinsThe Chemistry of Phenolic ResinsThe Structure of Phenolic ResinsFormation of phenol alcoholsFormation of methylene bridgesFormation of dibenzyl ethersFormation of quinone methidesRaw MaterialsPhenolsAldehydesHexamethylenetetramine (HMTA)Fillers for Phenolic Moulding Powderswww.entrepreneurindia.co

Types of fillerThermal DegradationModified and Thermal-resistance ResinsEtherification reactionsEsterification reactionsHeavy metal modified resinsChemical ResistanceResistance to microorganismOil Soluble Phenolic ResinsComposite Wood MaterialMoulding CompoundsHeat and sound insulation materialsIndustrial laminates and paper impregnationCoatingsFoundry resinsPhenolic resin as ion-exchange resinAbrasive materialsFriction materialsPhenolic resin in rubbers and adhesiveswww.entrepreneurindia.co

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Hot Melt Vinyl Film to Wood Laminating Adhesives Pressure Sensitive Adhesives (PSA) www.entrepreneurindia.co 10. Polychloroprene Resin Adhesives Introduction Types of Polychloroprene Applications and Formulations Applications 11. Pol