SAFETY DATA SHEET - Sika

Transcription

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29SECTION 1. PRODUCT AND COMPANY IDENTIFICATIONProduct name:Product code: 100000023370Type of product: liquidSika Boom CleanerManufacturer or supplier's detailsCompany: Sika (NZ) Ltd.85-91 Patiki RoadAvondaleAuckland AKL 1026Telephone: 64 9 820 2900Emergency telephone num: 0800 734 607berTelefax: 64 9 828 4091E-mail address: info@nz.sika.comSECTION 2. HAZARDS IDENTIFICATIONGHS Classification2.1.2 Flammable aerosols: Category A6.1 Acute toxicity (Oral): Category E6.3 Skin irritation: Category B6.4 Eye irritation: Category AGHS label elementsHazard pictograms:Signal word: DangerHazard statements: H222 Extremely flammable aerosol.H303 May be harmful if swallowed.H316 Causes mild skin irritation.H319 Causes serious eye irritation.Precautionary statements: Prevention:P210 Keep away from heat/sparks/open flames/hot surfaces.No smoking.P211 Do not spray on an open flame or other ignition source.P251 Pressurized container: Do not pierce or burn, even afteruse.P264 Wash skin thoroughly after handling.P280 Wear protective gloves/ eye protection/ face protection.Response:P305 P351 P338 IF IN EYES: Rinse cautiously with water1/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing.P312 Call a POISON CENTER or doctor/ physician if you feelunwell.P332 P313 If skin irritation occurs: Get medical advice/ attention.P337 P313 If eye irritation persists: Get medical advice/ attention.Storage:P410 P412 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F.Other hazards which do not result in classificationNone known.SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTSSubstance / Mixture: MixtureHazardous componentsChemical 7-63-0106-97-874-98-6Concentration (%) 30 - 50 30 - 50 20 - 30 10 - 20SECTION 4. FIRST AID MEASURESGeneral advice: Move out of dangerous area.Consult a physician.Show this safety data sheet to the doctor in attendance.If inhaled: Move to fresh air.In case of skin contact: Take off contaminated clothing and shoes immediately.Wash off with soap and plenty of water.If symptoms persist, call a physician.In case of eye contact: Immediately flush eye(s) with plenty of water.Remove contact lenses.Keep eye wide open while rinsing.If eye irritation persists, consult a specialist.If swallowed: Clean mouth with water and drink afterwards plenty of water.Do not give milk or alcoholic beverages.Never give anything by mouth to an unconscious person.Most important symptomsand effects, both acute anddelayed: Excessive lachrymationLoss of balanceVertigoSee Section 11 for more detailed information on health effectsand symptoms.May be harmful if swallowed.Causes mild skin irritation.2/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29Causes serious eye irritation.irritant effectsNotes to physician: Treat symptomatically.SECTION 5. FIREFIGHTING MEASURESSuitable extinguishing media: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.Unsuitable extinguishingmedia: WaterHazardous combustion products: No hazardous combustion products are knownSpecific extinguishing methods: Use water spray to cool unopened containers.Special protective equipmentfor firefighters: In the event of fire, wear self-contained breathing apparatus.SECTION 6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures: Use personal protective equipment.Deny access to unprotected persons.Environmental precautions: If the product contaminates rivers and lakes or drains informrespective authorities.SECTION 7. HANDLING AND STORAGEAdvice on protection againstfire and explosion: Keep away from heat/sparks/open flames/hot surfaces. Nosmoking. Do not spray on a naked flame or any incandescentmaterial. Take precautionary measures against electrostaticdischarges.Advice on safe handling: Do not breathe vapours or spray mist.Avoid exceeding the given occupational exposure limits (seesection 8).Do not get in eyes, on skin, or on clothing.For personal protection see section 8.Smoking, eating and drinking should be prohibited in the application area.Take precautionary measures against static discharge.Open drum carefully as content may be under pressure.Follow standard hygiene measures when handling chemicalproductsHygiene measures: Handle in accordance with good industrial hygiene and safetypractice.When using do not eat or drink.3/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29When using do not smoke.Wash hands before breaks and at the end of workday.Conditions for safe storage: BEWARE: Aerosol is pressurized. Keep away from direct sunexposure and temperatures over 50 C. Do not open by forceor throw into fire even after use. Do not spray on flames orred-hot objects.Store in original container.Keep in a well-ventilated place.Observe label precautions.Store in accordance with local regulations.SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTIONComponents with workplace control .Value type(Form ofexposure)WES-TWAControl parameBasisters / Permissibleconcentration67-64-1500 ppmNZ OEL1,185 mg/m3Further information: Exposure can also be estimated by biologicalmonitoringWES-STEL1,000 ppmNZ OEL2,375 mg/m3Further information: Exposure can also be estimated by biologicalmonitoringTWA250 ppmACGIHSTEL500 ppmACGIH67-63-0WES-TWA400 ppmNZ OEL983 mg/m3WES-STEL500 ppmNZ OEL1,230 mg/m3106-97-8WES-TWA800 ppmNZ OEL1,900 mg/m3STEL1,000 ppmACGIHPersonal protective equipmentRespiratory protection: Use respiratory protection unless adequate local exhaustventilation is provided or exposure assessment demonstratesthat exposures are within recommended exposure guidelines.The filter class for the respirator must be suitable for the maximum expected contaminant concentration(gas/vapour/aerosol/particulates) that may arise when handling the product. If this concentration is exceeded, selfcontained breathing apparatus must be used.Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handlingchemical products if a risk assessment indicates this is necessary.Eye protection: Safety eyewear complying with an approved standard shouldbe used when a risk assessment indicates this is necessary.4/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0Skin and body protectionSDS Number: 100000023370: Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place.SECTION 9. PHYSICAL AND CHEMICAL PROPERTIESAppearance: liquidColour: clearOdour: aromaticOdour Threshold: No data availablepH: No data availableMelting point/range / Freezingpoint: No data availableBoiling point/boiling range: No data availableFlash point: Not applicableEvaporation rate: No data availableFlammability: No data availableUpper explosion limit: No data availableLower explosion limit: No data availableVapour pressure: 8300 hPa (6226 mmHg)Relative vapour density: No data availableDensity: ca. 0.78 g/cm3 (20 C (68 F) ())Solubility(ies)Water solubility: No data availableSolubility in other solvents: No data availablePartition coefficient: noctanol/water: No data availableAuto-ignition temperature: No data availableDecomposition temperature: No data availableViscosityViscosity, dynamic: ca. 2.1 mPa.s (25 C)Viscosity, kinematicRevision Date: 2019/05/29: 20.5 mm2/s (40 C)5/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Explosive properties: No data availableMolecular weight: No data availableRevision Date: 2019/05/29SECTION 10. STABILITY AND REACTIVITYReactivity: No dangerous reaction known under conditions of normal use.Chemical stability: The product is chemically stable.Possibility of hazardous reactions: Stable under recommended storage conditions.Conditions to avoid: Heat, flames and sparks.Incompatible materials: No data availableNo decomposition if stored and applied as directed.SECTION 11. TOXICOLOGICAL INFORMATIONAcute toxicityMay be harmful if swallowed.Components:acetone:Acute oral toxicity: LD50 Oral (Rat): 5,800 mg/kgAcute inhalation toxicity: LC50 (Rat): 76 mg/lExposure time: 4 hTest atmosphere: vapourAcute dermal toxicity: LD50 Dermal (Rabbit): 20,000 mg/kgpropan-2-ol:Acute oral toxicity: LD50 Oral (Rat): 5,000 mg/kgAcute inhalation toxicity: LC50 (Rat): 20 mg/lExposure time: 4 hTest atmosphere: vapourAcute dermal toxicity: LD50 Dermal (Rabbit): 5,000 mg/kgSkin corrosion/irritationCauses mild skin irritation.Serious eye damage/eye irritationCauses serious eye irritation.Respiratory or skin sensitisationSkin sensitisation: Not classified based on available information.Respiratory sensitisation: Not classified based on available information.6/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29Chronic toxicityGerm cell mutagenicityNot classified based on available information.CarcinogenicityNot classified based on available information.Reproductive toxicityNot classified based on available information.STOT - single exposureNot classified based on available information.STOT - repeated exposureNot classified based on available information.Aspiration toxicityNot classified based on available information.SECTION 12. ECOLOGICAL INFORMATIONEcotoxicityComponents:acetone:Toxicity to fish: LC50 (Fish): 5,000 mg/lExposure time: 96 hToxicity to daphnia and otheraquatic invertebrates: EC50 (Daphnia (water flea)): 12.700 mg/lExposure time: 48 hToxicity to algae: ErC50 (Pseudokirchneriella subcapitata (green algae)): 530mg/lExposure time: 96 hPersistence and degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableOther adverse effectsProduct:Additional ecological information: There is no data available for this product.SECTION 13. DISPOSAL CONSIDERATIONSDisposal methodsWaste from residues: Do not contaminate ponds, waterways or ditches with chemical or used container.7/9

SAFETY DATA SHEETSika Boom CleanerSDS Number: 100000023370Version 1.0Revision Date: 2019/05/29Send to a licensed waste management company.Contaminated packaging: Empty remaining contents.Dispose of as unused product.Do not re-use empty containers.Do not burn, or use a cutting torch on, the empty drum.SECTION 14. TRANSPORT INFORMATIONInternational RegulationsIATA-DGRUN/ID No.Proper shipping nameClassPacking groupLabelsPacking instruction (cargoaircraft)Packing instruction (passenger aircraft)::::::UN 1950Aerosols, flammable2.1Not assigned by regulationFlammable gas203:203IMDG-CodeUN numberProper shipping name::UN 1950AEROSOLSClassPacking groupLabelsEmS CodeMarine pollutant:::::2.1Not assigned by regulation2.1F-D, S-UnoTransport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot applicable for product as supplied.National RegulationsNZS 5433UN numberProper shipping nameClassPacking groupLabels:::::UN 1950AEROSOLS2.1Not assigned by regulation2.1Special precautions for userThe transport classification(s) provided herein are for informational purposes only, and solelybased upon the properties of the unpackaged material as it is described within this Safety DataSheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations.SECTION 15. REGULATORY INFORMATIONSafety, health and environmental regulations/legislation specific for the substance or mixtureInternational Chemical Weapons Convention (CWC): Not applicableSchedules of Toxic Chemicals and Precursors8/9

SAFETY DATA SHEETSika Boom CleanerVersion 1.0SDS Number: 100000023370Revision Date: 2019/05/29HSNO Approval NumberHSR002515HSNO ControlsCertified handler certificate not required.HSW tracking not required.Refer to WORKSAFE user guide to the HSW regulations for further information.The components of this product are reported in the following inventories:NZIoC: On the inventory, or in compliance with the inventorySECTION 16. OTHER INFORMATIONThe information contained in this Safety Data Sheet corresponds to our level of knowledge atthe time of publication. All warranties are excluded. Our most current General Sales Conditions shall apply. Please consult the product data sheet prior to any use and processing.9/9

Sika Boom Cleaner SDS Number Version 1.0 : 100000023370 Revision Date 2019/05/29 2 / 9 for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P332 P313 If skin irritation occurs: Get medical advice/ atten-tion.