SAFETY DATA SHEET - Costco

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SAFETY DATA SHEETRevision Date: 24-Mar-2021Version: 31. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKINGProduct identifierProduct Label NameProduct Generic NameProduct codeOther means of identificationUPC Code(s)SynonymsKirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric Softener561848 (US) 1390211 (New)0-96619-56184-1; 0-96619-56184-1; 0-96619-33686-9; 0-96619-26401-8;0-96619-26400-1; 0-96619-23594-0; 0-96619-14261-3NoneRecommended use of the chemical and restrictions on useRecommended UseUses advised againstFabric conditioning liquid for clothes washing machines.Read label before useSupplier's detailsDistributorCostco Wholesale CorporationP.O. Box 34535,Seattle, WA 98124-1535 USA1-800-774-2678www.costco.comEmergency telephone numberEmergency telephoneChemtrec (US/CA) 1-800-424-9300 (24 hour)General-18007766702(Monday–Friday,8:30AM to6:00PM EST)Propharma: 1-800-565-5597 (24 hours)2. HAZARDS IDENTIFICATIONGlobally Harmonized System Safety Data Sheets (SDS) are required to be readily accessible to employees for all hazardouschemicals in the workplace. This SDS provides additional information for safe handling of the product and may contain healthhazard information not relevant to consumer use. For information regarding consumer application of this product, refer to theproduct label.ClassificationOSHA Regulatory StatusThis chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)Not a dangerous substance or mixture according to the Globally Harmonized System (GHS)GHS Label elements, includingprecautionary statementsEmergency OverviewThe product contains no substances which at their given concentration, are considered to be hazardous to healthAppearance OPAQUE LIQUIDPhysical state liquidOdor FloralPage 1 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerPrecautionary Statements - PreventionWash hands thoroughly after handlingPrecautionary Statements - ResponseGet medical advice/attention if you feel unwellPrecautionary Statements - StorageStore in a well-ventilated place. Keep container tightly closedPrecautionary Statements - DisposalDisposal should be in accordance with applicable regional, national and local laws and regulations.Hazards not otherwise classified (HNOC)Not applicableOther information Harmfultoaquaticlifewithlonglastingeffects HarmfultoaquaticlifeGeneral HazardsNo information available17.059% of the mixture consists of ingredient(s) of unknown toxicity3. COMPOSITION/INFORMATION ON INGREDIENTSChemical NameEthyl alcoholGlutaraldehydeCAS-No64-17-5111-30-8Weight %1-5 0.1Trade Secret*The exact percentage (concentration) of composition has been withheld as a trade secret4. FIRST AID MEASURESFirst aid measures for different exposure routesGeneral adviceGet medical attention immediately if symptoms occur.Eye contactRinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids.Consult a physician.Skin contactWash skin with soap and water.Toxic - InhalationMove to fresh air.IngestionClean mouth with water and drink afterwards plenty of water. If symptoms persist, call aphysician.Protection of First-aidersUse personal protective equipment.Most important symptoms/effects, acute and delayedMain SymptomsNone under normal use conditions.Indication of immediate medical attention and special treatment needed, if necessaryNotes to physicianTreat symptomatically.5. FIRE-FIGHTING MEASURESSuitable Extinguishing MediaUse extinguishing measures that are appropriate to local circumstances and the surrounding environment.Page 2 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerUnsuitable Extinguishing Media None.Specific hazards arising from the chemicalNone known.Not applicable.Hazardous CombustionProductsExplosion DataSensitivity to Mechanical Impact None.Sensitivity to Static Discharge None.Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and fullprotective gear.6. ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency proceduresPersonal precautionsAvoid contact with the skin and the eyes.Other informationRefer to protective measures listed in Sections 7 and 8.Advice for emergency respondersFor personal protection see section 8.Environmental precautionsSee Section 12 for additional Ecological Information.Environmental precautionsMethods and materials for containment and cleaning upMethods for ContainmentPrevent further leakage or spillage if safe to do so.Methods for cleaning upClean contaminated surface thoroughly. After cleaning, flush away traces with water.7. HANDLING AND STORAGEPrecautions for safe handlingAdvice on safe handlingHandle in accordance with good industrial hygiene and safety practice.Conditions for safe storage, including any incompatibilitiesTechnical measures/StorageconditionsPackaging materialIncompatible productsKeep container tightly closed in a dry and well-ventilated place. Keep out of the reach ofchildren.Keep consumer product in packaging product is initially sold in.None known based on information supplied.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parametersExposure GuidelinesChemical NameEthyl alcohol64-17-5ACGIH TLVSTEL: 1000 ppmOSHA PELTWA: 1000 ppmTWA: 1900 mg/m3(vacated) TWA: 1000 ppm(vacated) TWA: 1900 mg/m3NIOSH IDLHIDLH: 3300 ppmTWA: 1000 ppmTWA: 1900 mg/m3Page 3 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerGlutaraldehyde111-30-8Ceiling: 0.05 ppm activated andinactivated(vacated) Ceiling: 0.2 ppm(vacated) Ceiling: 0.8 mg/m3Ceiling: 0.2 ppmCeiling: 0.8 mg/m3NIOSH IDLH: Immediately Dangerous to Life or HealthAppropriate engineering controlsEngineering MeasuresShowersEyewash stationsVentilation systems.Individual protection measures, such as personal protective equipmentEye/Face ProtectionSafety glasses with side-shields.Skin and body protectionNo special protective equipment required.Respiratory protectionNo special protective equipment required. If exposure limits are exceeded or irritation isexperienced, NIOSH/MSHA approved respiratory protection should be worn.Hygiene measuresHandle in accordance with good industrial hygiene and safety practice.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical and chemical propertiesPhysical stateAppearanceColorliquidOPAQUE LIQUIDblueOdorOdor thresholdValuesProperty3.500pHNo information availableMelting pointNo information availableBoiling point/boiling range 94 C / 201 FFlash PointNo information availableEvaporation rateNo information availableFlammability (solid, gas)Flammability Limits in AirNo information availableUpper Flammability LimitNo information availableLower Flammability LimitNo information availableVapor pressureNo information availableVapor density0.992Specific GravitySoluble in waterWater solubilityNo information availableSolubility in other solventsPartition coefficient: n-octanol/waterNo information availableNo information availableAutoignition temperatureNo information availableDecomposition temperature220.000 cpsViscosity, kinematicNo information availableViscosity, dynamicNo information availableExplosive propertiesNo information availableOxidizing PropertiesFloralNo information availableRemarks MethodpHSPECIFIC GRAVITY - 20CViscosity@12rpm, LV Spindle#1@25COther informationSoftening pointMolecular weightVOC Content(%)DensityBulk DensityNo information availableNo information availableNo information availableNo information availableNo information available10. STABILITY AND REACTIVITYPage 4 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerReactivityNot expectedChemical stabilityStable under recommended storage conditions.Possibility of hazardous reactionsNone under normal processing.Hazardous PolymerizationNone under normal processing.Conditions to AvoidExposure to air or moisture over prolonged periods.Incompatible MaterialsNone known.Hazardous Decomposition ProductsNone known.11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposureProduct InformationToxic - InhalationNot an expected route of exposure.Eye contactMay cause irritation.Skin contactProlonged contact may cause redness and irritation.IngestionMay be harmful if swallowed.Component InformationInformation on toxicological effectsDelayed and immediate effects as well as chronic effects from short and long-term exposureSkin corrosion/irritationEye damage/irritationSensitizationGerm cell mutagenicityCarcinogenicityNo known effect.No known effect.No known effect.No known effect.The table below indicates whether each agency has listed any ingredient as a carcinogen.Chemical NameACGIHIARCA3Group 1Ethyl alcohol64-17-5ACGIH: (American Conference of Governmental Industrial Hygienists)A3 - Animal CarcinogenIARC: (International Agency for Research on Cancer)Group 1 - Carcinogenic to HumansNTP: (National Toxicity Program)Known - Known CarcinogenOSHA: (Occupational Safety & Health Administration)X - PresentReproductive toxicityDevelopmental ToxicitySTOT - single exposureSTOT - repeated exposureChronic toxicityNTPKnownOSHAXNo known effect.No known effect.No known effect.No known effect.Ethanol has been shown to be carcinogenic in long-term studies only when consumed asalcoholic beverage. Ethanol has been shown to be a reproductive toxin only whenconsumed as an alcoholic beverage.Page 5 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerNo known effect.Aspiration hazardNumerical measures of toxicity - Product Information17.059% of the mixture consists of ingredient(s) of unknown toxicityUnknown acute toxicityThe following values are calculated based on chapter 3.1 of the GHS document .13699 mg/kgATEmix (oral)14312 mg/kgATEmix (dermal)12. ECOLOGICAL INFORMATIONEcotoxicity1.0913001% of the mixture consists of components(s) of unknown hazards to the aquatic environmentPersistence and degradabilityNo information available.BioaccumulationNo information available.MobilityChemical NameEthyl alcohol64-17-5Glutaraldehyde111-30-8Partition coefficient-0.320.22No information availableOther adverse effects13. DISPOSAL CONSIDERATIONSWaste treatmentWaste Disposal MethodsDisposal should be in accordance with applicable regional, national and local laws andregulations.Contaminated packagingDo not re-use empty containers.California Hazardous Waste CodesThis product contains one or more substances that are listed with the State of California as a hazardous waste.Chemical NameEthyl alcohol64-17-5Glutaraldehyde111-30-8California Hazardous Waste StatusToxicIgnitableToxic14. TRANSPORT INFORMATIONDOTNot regulatedTDGNot regulatedMEXNot regulatedICAONot regulatedPage 6 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerIATANot regulatedIMDGNot regulatedRIDNot regulatedADRNot regulatedADNNot regulated15. REGULATORY INFORMATIONInternational ECSCKECLPICCSAICSLegend:TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical SubstancesENCS - Japan Existing and New Chemical SubstancesIECSC - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical SubstancesUS Federal RegulationsSARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain anychemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.SARA 311/312 Hazard CategoriesAcute Health HazardChronic Health HazardFire HazardSudden Release of Pressure HazardReactive HazardYesNoNoNoNoClean Water ActThis product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40CFR 122.42).CERCLAThis material, as supplied, does not contain any substances regulated as hazardous substances under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments andReauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state levelpertaining to releases of this material.US State RegulationsCalifornia Proposition 65This product contains the following Proposition 65 chemicals:Chemical NameEthyl alcohol - 64-17-5California Prop. 65CarcinogenDevelopmentalPage 7 / 8

Revision Date 24-Mar-2021Kirkland Signature Ultra Soft Premium Fabric Softener Refreshing ScentLiquid Fabric SoftenerChronic toxicityEthanol has been shown to be carcinogenic in long-term studies only when consumed asalcoholic beverage Ethanol has been shown to be a reproductive toxin only whenconsumed as an alcoholic beverageU.S. State Right-to-Know RegulationsChemical NameWater7732-18-5Ethyl alcohol64-17-5Glutaraldehyde111-30-8New JerseyMassachusettsPennsylvaniaXXXXXXXU.S. EPA Label informationEPA Pesticide Registration Number Not applicable16. OTHER INFORMATIONNFPAHealth hazard 1Flammability 0Instability 0HMISHealth hazard 1Flammability 0Physical Hazard 0Physical and chemicalhazards Personal protection X24-Mar-2021Revision DateRevision NoteNew product codeDisclaimerThis (M)SDS is intended to provide a brief summary of our knowledge and guidance regarding the use of this material.The information contained here has been compiled from sources considered by our company to be dependable and mmunication regulations.This information is offered in good faith. Each user of this material needs to evaluate the conditions of use and design theappropriate protective mechanisms to prevent employee exposures, property damage or release to the environment. Weassume no responsibility for injury to the recipient or third persons or for any damage to any property resulting frommisuse of the product.End of Material Safety Data SheetPage 8 / 8

Toxic - Inhalation Move to fresh air. Ingestion Clean mouth with water and drink afterwards plenty of water. If symptoms persist, call a physician. Protection of First-aiders Use personal protective equipment. Most important symptoms/effects, acute and delayed Main Symptoms None under normal use conditions.