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j;SFUND RECORDS CTR5133-00005SFUND RECORDS CENTER88224854Data Validation PackageforMERCURYEPA 7471ATABLE OF CONTENTSLABORATORY NAME:APPL Inc.Case Narrative3Chain of Custody and ARF4QC SummarySample Data/ /Calibration Dataj jRaw Data /APPL,IIMC.I02)

MERCURYEPA 7471ACase NarrativeA tjwc l03

CASE NARRATIVEMercury for Ecology and EnvironmentAPPL, Inc. State Certification No. 1312ARF Numbers:26739Project: KJ93103 Eagle OneSample Receipt Information:The sample group was received on January 07, 1998. The samples were assignedAnalytical Request Form (ARF) number 26739. The sample numbers andrequested analyses were compared to the chain of custody. No exceptions wereencountered.Sample Table for Metals AnalysesE & EIDEagle One-160Eagle mple PreparationThe analyses were performed within holding time. The Mercury analyses wereperformed using a Thermo Jarrell Atomic Absorption Spectrophotometer.AnalysisAll samples were analyzed within acceptable holding time. No problems wereencountered.Quality Control/AssuranceLaboratory DuplicateThe laboratory duplicate results met acceptance criteria.Spike RecoveryAn MS/MSD and an LCS were used for the spikes. All recoveries wereacceptable.Method blanksThe preparation blank contained no target analytes at or above reporting limits.04

CalibrationInitial CalibrationAll initial calibrations were performed according to the methods. All acceptancecriteria were met.Continuing CalibrationAll continuing calibrations were performed according to the method. Allacceptance criteria were met.CertificationI certify that this data package is in compliance with the terms and conditions ofthe contract, both technically and for completeness, for other than the conditions detailedabove. Release of the data contained in this hard copy data package has been authorizedby the Laboratory Manager or his designee, as verified by the following signature.05

MERCURYEPA 7471AChain of Custody and ARFAm,, awe.I06

'APPL - Analysis Request Form * —#26739—Client:Ecology & Env - San Francisco (ECOL-SF) Received by:Name:Ecology & Environment—MLDate Received: 01/07/98Time:Address: 500 Howard, Suite 202Date Sampled: 12/11/97Address: San Francisco, CA 94105Delivered by:Attn: Howard EdwardsShuttle Custody seals (Y/N):Client job # or location:PO# if available:Ph: (415) 981-2811KJ93103 Eagle OneNAChain of Custody (Y/N): YRAD Screen (Y/N):YpH (Y/N):NTurn Around Type:3 DAYChargesComments: HOLDING TIME UP 01/08/98FED. EXPRESSNChest Temp(s):2 V59773Time in/color:1055Project Manager:Diane AndersonQC Report Type:DVP4Samples chilled until placed in refrigerator/freezer (Y/N):09:55.ORANGE/ PURPLEYDue Date:- 01/07/98 C ,\ L \C;Sample DistributionFROM E&E START BOA CONTRACTFage 1#2673907'

EN VI HONMENTAL PROTECTION AGENCYREGION 975 Hawthorne Street'Office of EnforcementCHAIN OF CUSTODY RECORDPROJ NO."Si r? SAMPLERS:/ PROJECT NAME1[TNO.T . . - (Signature)STA.NO.DATE ' 'TIMECOMPOF////////CON TAINERSGO STATION LOCATIONcro/ ///V//A PTT/ / /OO7 // / /: i, 'i « : '. 1 ,'i,; \4.T//-/ikr-XLi/fjREMARKS\'I". \ 0-;f.V'",.1 11 2!;' \—.DX)/././"*'S . ,J*' 1-' % O-V/s-a§r/ /\—Relinquished by:(Signature)Date/TimeRelinquished by:(Signature)Date / TimeReceived by:(Signature)for Laboratory b y :ure)/ ' / 1/ 1// LRelinquished by:j(Signature)pfate /Timef/W/ ADate / TimeReceived by:(Signature)Remarks/'! ,'ir,rILDistribution: Original Accompanies ShTp'rifent; Copy 1,6 otjj fnafor Field Files/y925117

4 TnrTimi nq SamplerlinT1f.ECcLob7 ft. CO—:Phone:Name:Delivered J:Sample Date:Client ID: Lf -cJr-NoticeInitials:Date of call:Client Job:ZZ'VPODate expected;Due Date- —— f& L& oiLsT/r X* Icl»- Special Tnst-.ructions:cJ-hAs

BlICItlPT l:ORMCONTAINERPLPLLLTIER500ML250MI.LITER - I IM03500ML -IIN03250ML -1IM03PL LITER -112S0PL 500ML - I-I2S0'L 250ML - N2S0 ICYANIDESULFIDE"OCVOAS- l-ICLVOAS - NA2S203VOAS - NPOIL & GREASEAMBER LITERo SOIL SLEEVE102 JAROOZ JARI60Z JAR320Z JARSUBCONTRACT:QA/QC SAMPLEARE IE,' T."SC )

COOLERCOOL]RECEIPT FORMNumber of Coolers:Date Received: Z7/ -PROJECTUSE OTHER SIDE OF THIS FORM TO NOTE DETAILS CONCE/G CHECK-IN PROBLEMS.C-O-C #A. PRELIMINARY EXAMINATION PHASE: Date Cooler Opened:by (print)1.Did cooler come with a shipping slip (air bill, etc.)?-S7-QTTiS yNCIf Yes, enter carrier name and air bill number here:YE3'" ND Were custody seals on outside of cooler?How manv?Name on seal?Date on Seal?j.Were custody seals unbroken and intact at the date and time of arrival?4.Did you screen sample for radioactivity using the Geiger Counter0( TES NO5.Were custody papers sealed in a plastic bag &. taped inside to the lid0( . YES NO6.Were custody papers filled out properly (ink, signed, etc.)?(T. YESJ) NO7.Did you sign custody papers in the appropriate place08.Was project identifiable from custody papers0 If YES. enter project name at die top of Litis form9.If required, was enough ice used?10. Shutde temDeraturefsi:dType of ice:YESpO j-SY2ZOSerial number of certified thermometer used:11. Have designated person initial here to acknowledge receipt of coolerB.LOG-IN PHASE:Date samples were logged-inby (print)Did all botdes arrive unbroken & were labels in good condition?. P ,S -.Vr .Were all botde labels complete (ID, date, time, signature, preservadve, etc.)?N'0Did all botde labels agree with custody papers?NOWere correct containers used for the tests indicated?( Were correct preservarives added to samples?YES NOWas a sufficient amount of sample sent for tests indicated?L , YF'v- NOWere bubbles absent in volatile samples? If NO, list by sample IDYESri NO10. Was the project manager called and status discussed? If YES, give details on die back of this form11. Who was called?YES jNOBv whom?11(date)YES NO

MERCURYEPA 7471AQC SummaryAPPI.IMC.)12

E&ENAMEHg BY METHOD 7471AQCG: 010798-7471A-1DATE: 01/08/98TRUERESULTARF#26739% 7S S159787S S2(mg/kg)0.74690.79891.55311.5401SPIKED AT 4ppb98.4%RPD 6.7%(SPIKED AT 0.667mg/kg)(SPIKED AT 0.667mg/kg)121%119%LCSW/Sample spike recovery acceptance limit. ( 20%)Sample spike recovery acceptance limit. ( 25%)LCSW/ Matrix duplicate RPD acceptance limit. ( 20%)13RPD 0.84%

Metals AnalysisEcology & EnvironmentAPPL Inc.500 Howard, Suite 2024203 West Swift AvenueSan Francisco, CA 94105Fresno, CA 93722Attn: Howard EdwardsProject: KJ93103 Eagle OneSample ID: EAGLE ONE-160APPL ID: AP59786Sample Collection Date: 12/11/97ARF: 26739MethodAnalyteResultPQLUnitsPrep DateAnalysis Date(Concentrations and Limits have been adjusted to reflect 4.3 Percent Moisture.)7471AMercury (Hg)0.730.10mg/kg1/7/981/8/9815Printed: 1/6/98 4:27:44 PM

Metals AnalysisEcology & EnvironmentAPPL Inc.500 Howard, Suite 2024203 West Swift AvenueSan Francisco, CA 94105Fresno, CA 93722Attn: Howard EdwardsProject: KJ93103 Eagle OneSample ID: EAGLE ONE-155APPL ID: AP59787Sample Collection Date: 12/11/97ARF: 26739AnalyteMethodResultPQLUnitsPrep DateAnalysis Date(Concentrations and Limits have been adjusted to reflect 2.4 Percent Moisture.]7471AMercury (Hg)0.720.10mg/kg1/7/981/8/98iIBPrinted: 1/8/98 4:27:44 PM

MERCURYEPA 7471ACalibration DataAPPl, IIIMC/117

E&EHg BY METHOD 7471AQCG: 010798-7471A-1DATE: 01/08/98ARF#26739Hg RUN LOG 9787S59787SD59787S S159787S S2CCV-2CCB-2QCG: 010798-7471A-1QCG: 010798-7471A-1QCG: 010798-7471A-1QCG: 010798-7471A-1QCG: 010798-7471A-1QCG: 010798-7471A-1QCG: 8/9801/08/9801/08/9801/08/98

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MERCURYEPA 7471ARaw DataAW.JMC.121

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Wet Lab AnalysisEcology & EnvironmentAPPL Inc.500 Howard, Suite 2024203 West Swift AvenueSan Francisco, CA 94105Fresno, CA 93722Attn: Howard EdwardsProject: KJ93103 Eagle OneSample ID: EAGLE ONE-160APPL ID: AP59786Sample Collection Date: 12/11/97ARF: 26739MethodAnalyteCLP MOISTMoistureResult4.3PQL225UnitsPrep Date%1/7/98Initials:wyAnalysis Date1/7/98Printed: 1/&98 9:58:31 AM

Wet Lab AnalysisEcology & EnvironmentAPPL Inc.500 Howard, Suite 2024203 West Swift AvenueSan Francisco, CA 94105Fresno, CA 93722Attn: Howard EdwardsProject: KJ93103 Eagle OneSample ID: EAGLE ONE-155APPL ID: AP59787Sample Collection Date: 12/11/97ARF: 26739MethodAnalyteCLP MOISTMoistureResultPQL2.4?62UnitsPrep Date%1/7/98Analysis Date1/7/98

APPL, Inc.Wet Chemistry LabQC SummaryClient: Ecology EnvironmentARF#: 26739Method CLP3/9QAnalyte: % MOISTUREMatrix Duplicate (Batch 8-CLP3/90-1010798-CLP3/90-1„Acceptable limit for a matrix duplicate is RPD 20.SA spike amount%R %recoverySR sample recoveryRPD relative % differenceSSR sample spike recoveryQCG quality control groupPage 127

Calibration Data j_j_ Raw Data / APPL, IIMC. I 02 . A tjwc l MERCURY EPA 7471A Case Narrative 03 . CASE NARRATIVE . VOAS- l-ICL VOAS - NA2S203 VOAS - NP OIL & GREASE AMBER LITER SOIL SLEEVE 102 JAR OOZ JAR I60Z JAR 320Z JAR SUBCONTRACT: QA/QC SAMPLE BlICItlPT l:ORM ARE IE ,' T."SC )