Safety Data Sheet - .basf

Transcription

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 1/10(30786268/SDS GEN US/EN)1. IdentificationProduct identifier used on the labelGLYSANTIN G65 ECO pink BMB 25Recommended use of the chemical and restriction on useRecommended use*: Ready-to-use engine coolantsUnsuitable for use: None known* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part ofthe seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express orimplied, including by incorporation into or reference in the seller's sales agreement.Details of the supplier of the safety data sheetCompany:BASF CORPORATION100 Park AvenueFlorham Park, NJ 07932, USAFuel and Lubricant SolutionsE-mail address: RegXcellenceFuelLubes@basf.comEmergency telephone number24 Hour Emergency Response InformationCHEMTREC: 1-800-424-9300BASF HOTLINE: 1-800-832-HELP (4357)Other means of identificationChemical family:inhibitors2. Hazards IdentificationAccording to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200Classification of the productAcute Tox.STOT RE4 (oral)2Acute toxicitySpecific target organ toxicity — repeatedexposure

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 2/10(30786268/SDS GEN US/EN)Label elementsPictogram:Signal Word:WarningHazard Statement:H302H373Harmful if swallowed.May cause damage to organs (Kidney) through prolonged or repeatedexposure.Precautionary Statements (Prevention):P260Do not breathe dust/gas/mist/vapours.P270Do not eat, drink or smoke when using this product.P264Wash contaminated body parts thoroughly after handling.Precautionary Statements (Response):P314Get medical advice/attention if you feel unwell.P301 P312IF SWALLOWED: Call a POISON CENTER or doctor/physician if youfeel unwell.P330Rinse mouthPrecautionary Statements (Disposal):P501Dispose of contents/container in accordance with local regulations.Hazards not otherwise classifiedNo specific dangers known, if the regulations/notes for storage and handling are considered.3. Composition / Information on IngredientsAccording to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200ethylene glycolCAS Number: 107-21-1Content (W/W): 75.0 - 100.0%Synonym: 1,2-Ethanediol; Ethylene glycol4. First-Aid MeasuresDescription of first aid measuresGeneral advice:Immediately remove contaminated clothing. If the patient is likely to become unconscious, place andtransport in stable sideways position (recovery position). First aid personnel should pay attention totheir own safety.If inhaled:Keep patient calm, remove to fresh air, seek medical attention.

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 3/10(30786268/SDS GEN US/EN)If on skin:Wash affected areas with water while removing contaminated clothing. Seek medical attention.If in eyes:Wash affected eyes for at least 15 minutes under running water with eyelids held open.If irritation develops, seek medical attention.If swallowed:Rinse mouth immediately with water. Never induce vomiting or give anything by mouth if the victim isunconscious or having convulsions. Do not induce vomiting due to aspiration hazard. Seek medicalattention.Most important symptoms and effects, both acute and delayedSymptoms: Information, i.e. additional information on symptoms and effects may be included in theGHS labeling phrases available in Section 2 and in the Toxicological assessments available inSection 11., (Further) symptoms and / or effects are not known so farInformation on: ethylene glycolSymptoms: Overexposure may cause:, corneal injury, severe pain, skin irritation, coughing,respiratory disorders, dyspnea, nausea, headache, vomiting, dizziness, diarrhea, abdominal cramps---------------------------------Hazards: No applicable information available.Indication of any immediate medical attention and special treatment neededNote to physicianTreatment:Treat according to symptoms (decontamination, vital functions), noknown specific antidote.5. Fire-Fighting MeasuresExtinguishing mediaSuitable extinguishing media:water spray, dry powder, foamSpecial hazards arising from the substance or mixtureHazards during fire-fighting:harmful vapoursEvolution of fumes/fog. The substances/groups of substances mentioned can be released in case offire.Advice for fire-fightersProtective equipment for fire-fighting:Firefighters should be equipped with self-contained breathing apparatus and turn-out gear.Further information:The degree of risk is governed by the burning substance and the fire conditions. Contaminatedextinguishing water must be disposed of in accordance with official regulations.

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 4/10(30786268/SDS GEN US/EN)6. Accidental release measuresPersonal precautions, protective equipment and emergency proceduresUse personal protective clothing. Breathing protection required.Environmental precautionsContain contaminated water/firefighting water. Do not discharge into drains/surfacewaters/groundwater.Methods and material for containment and cleaning upFor small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).Dispose of absorbed material in accordance with regulations.For large amounts: Pump off product.Place absorbed material in the same container as the spilled substance/product for disposal.7. Handling and StoragePrecautions for safe handlingWear chemically resistant gloves in combination with specific activity training Wear suitable coverallsto prevent exposure to the skin.Protection against fire and explosion:Take precautionary measures against static discharges.Conditions for safe storage, including any incompatibilitiesThe product in undamaged packing need not be stored separately.Further information on storage conditions: Keep container tightly closed and dry; store in a coolplace.8. Exposure Controls/Personal ProtectionComponents with occupational exposure limitsethylene glycolACGIH, US:TWA value 25 ppm Vapor fraction ;ACGIH, US:STEL value 50 ppm Vapor fraction ;ACGIH, US:STEL value 10 mg/m3 Aerosol, inhalable. ;Personal protective equipmentRespiratory protection:Wear respiratory protection if ventilation is inadequate. Respiratory protection in case ofvapour/aerosol release.Hand protection:Wear chemically impervious protective gloves.Eye protection:Safety glasses with side-shields.

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 5/10(30786268/SDS GEN US/EN)Body protection:Body protection must be chosen based on level of activity and exposure., Protective coverall and/orimpermeable apron and boots as necessary.General safety and hygiene measures:Wearing of closed work clothing is required additionally to the stated personal protection equipment.No eating, drinking, smoking or tobacco use at the place of work.9. Physical and Chemical PropertiesForm:Odour:Odour threshold:Colour:pH value:pour point:Melting temperature:Freezing point:boiling temperature:Sublimation point:Flash point:Flammability:Lower explosion limit:Upper explosion limit:Autoignition:Vapour pressure:Density:Relative density:Vapour density:Partitioning coefficient noctanol/water (log Pow):Self-ignitiontemperature:Thermal decomposition:Viscosity, dynamic:Viscosity, kinematic:Solubility in water:Solubility (quantitative):Solubility (qualitative):Molar mass:Evaporation rate:Other Information:liquidof glycolnot determinedpink8.5(measured with the undilutedsubstance) -15 CNo applicable information available.No applicable information available.160 C( 1,013 hPa)No applicable information available. 120 Chardly combustibleFor liquids not relevant forclassification and labelling. The lowerexplosion point may be 5 - 15 Cbelow the flash point.For liquids not relevant forclassification and labelling. 200 C0.2 mbar( 20 C)1.1260 g/cm3( 20 C)No applicable information available.No applicable information available.No applicable information available.(ASTM D1287)(DIN ISO 3016)(ASTM D1120)(ISO 2592)(derived from flashpoint)(DIN 51794)(DIN 51757)not self-ignitingNo decomposition if used as directed.No applicable information available.approx. 30 mm2/s(DIN 51562)( 23 C)solubleNo applicable information available.solublesolvent(s): polar solvents,No applicable information available.not determinedIf necessary, information on other physical and chemicalparameters is indicated in this section.

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 6/10(30786268/SDS GEN US/EN)10. Stability and ReactivityReactivityNo applicable information available.Corrosion to metals:No corrosive effect on metal.Oxidizing properties:not fire-propagatingChemical stabilityThe product is stable if stored and handled as prescribed/indicated.Possibility of hazardous reactionsNo hazardous reactions when stored and handled according to instructions.The product is chemically stable.Conditions to avoidAvoid open flames.Incompatible materialsstrong oxidizing agents, strong bases, strong acidsHazardous decomposition productsDecomposition products:Hazardous decomposition products: No hazardous decomposition products known.Thermal decomposition:No decomposition if used as directed.11. Toxicological informationPrimary routes of exposureRoutes of entry for solids and liquids are ingestion and inhalation, but may include eye or skincontact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a routeof entry for liquefied gases.Acute Toxicity/EffectsAcute toxicityAssessment of acute toxicity: Of moderate toxicity after single ingestion.OralType of value: LD (human)Value: approx. 1,600 mg/kgInhalationNo applicable information available.DermalNo applicable information available.Assessment other acute effects

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 7/10(30786268/SDS GEN US/EN)Based on available data, the classification criteria are not met.Irritation / corrosionAssessment of irritating effects: Not irritating to eyes and skin.SkinSpecies: rabbitResult: non-irritantEyeSpecies: rabbitResult: non-irritantSensitizationAssessment of sensitization: Skin sensitizing effects were not observed in animal studies. Humandata do not fully exclude a skin sensitizing potential.Aspiration HazardNo aspiration hazard expected.Chronic Toxicity/EffectsRepeated dose toxicityAssessment of repeated dose toxicity: Repeated exposure may affect certain organs.Information on: ethylene glycolAssessment of repeated dose toxicity: The substance may cause damage to the kidney afterrepeated ingestion. The substance may cause damage to the kidney after repeated skin contact withhigh doses.----------------------------------Genetic toxicityAssessment of mutagenicity: Based on the ingredients, there is no suspicion of a mutagenic effect.CarcinogenicityAssessment of carcinogenicity: The whole of the information assessable provides no indication of acarcinogenic effect.None of the components in this product at concentrations greater than 0.1% are listed by IARC;NTP, OSHA or ACGIH as a carcinogen.Reproductive toxicityAssessment of reproduction toxicity: Based on the ingredients, there is no suspicion of a toxic effecton reproduction.TeratogenicityAssessment of teratogenicity: Based on available data, the classification criteria are not met.Information on: ethylene glycolAssessment of teratogenicity: Developmental toxicity was observed after oral ingestion of high dosesin studies with rats and mice, but this effect was not seen in a study with rabbits. Mechanistic studiesshow that the rabbit is the relevant species for the classification for human health. As such, andsince ethylene glycol is not a developmental toxicant in the rabbit, no classification is warranted.However, the relevance of this result for humans is unclear.---------------------------------Other Information

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 8/10(30786268/SDS GEN US/EN)The product has not been tested. The statements on toxicology have been derived from theproperties of the individual components.12. Ecological InformationToxicityAquatic toxicityAssessment of aquatic toxicity:There is a high probability that the product is not acutely harmful to aquatic organisms.Toxicity to fishLC50 (96 h) 100 mg/l, Leuciscus idusAquatic invertebratesEC50 (48 h) 100 mg/l, Daphnia magnaAquatic plantsEC50 (72 h) 100 mg/l, algaeMicroorganisms/Effect on activated sludgeToxicity to microorganismsInhibition of degradation activity in activated sludge is not to be anticipated during correctintroduction of low concentrations.Persistence and degradabilityAssessment biodegradation and elimination (H2O)The substance can be virtually eliminated from water in suitable effluent treatment plants bybiodegradation, stripping and mechanical separation.Bioaccumulative potentialAssessment bioaccumulation potentialNo data available.Mobility in soilAssessment transport between environmental compartmentsNo data available.Additional informationOther ecotoxicological advice:Do not release untreated into natural waters.The product has not been tested. The statement has been derived from the properties of theindividual components.13. Disposal considerationsWaste disposal of substance:

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2Page: 9/10(30786268/SDS GEN US/EN)Dispose of in accordance with national, state and local regulations. It is the waste generator'sresponsibility to determine if a particular waste is hazardous under RCRA.Container disposal:Dispose of in a licensed facility. Recommend crushing, puncturing or other means to preventunauthorized use of used containers.14. Transport InformationLand transportUSDOTNot classified as a dangerous good under transport regulationsSea transportIMDGNot classified as a dangerous good under transport regulationsAir transportIATA/ICAONot classified as a dangerous good under transport regulations15. Regulatory InformationFederal RegulationsRegistration status:ChemicalTSCA, USreleased; restriction on use / listedThis product contains a substance subject to a Significant New Use Rule (SNUR) or consent orderrestriction.40 CFR 721.11080EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicablefor this product.EPCRA 313:CAS Number107-21-1Chemical nameethylene glycolCERCLA RQ5000 LBSCAS Number107-21-1State regulationsState RTKNJPACAS Number107-21-1107-21-1Chemical nameethylene glycolChemical nameethylene glycolethylene glycolSafe Drinking Water & Toxic Enforcement Act, CA Prop. 65:WARNING: This product can expose you to chemicals including ETHYLENE GLYCOL (INGESTED),which is known to the State of California to cause birth defects or other reproductive harm. For moreinformation, go to www.P65Warnings.ca.gov.

Safety Data SheetGLYSANTIN G65 ECO pink BMB 25Revision date : 2021/11/16Version: 3.2NFPA Hazard codes:Health: 1Fire: 1Page: 10/10(30786268/SDS GEN US/EN)Reactivity: 0HMIS III ratingHealth: 1 Flammability: 1Special:Physical hazard: 016. Other InformationSDS Prepared by:BASF NA Product RegulationsSDS Prepared on: 2021/11/16We support worldwide Responsible Care initiatives. We value the health and safety of ouremployees, customers, suppliers and neighbors, and the protection of the environment. Ourcommitment to Responsible Care is integral to conducting our business and operating our facilities ina safe and environmentally responsible fashion, supporting our customers and suppliers in ensuringthe safe and environmentally sound handling of our products, and minimizing the impact of ouroperations on society and the environment during production, storage, transport, use and disposal ofour products.GLYSANTIN G65 ECO pink BMB 25 is a registered trademark of BASF Corporation or BASF SEIMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINEDHEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT ISPROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECTPROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TODETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIORTO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDINGWARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, AREMADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SETFORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USEDWITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASESHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDEREDA PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLYUNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATIONFURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NOOBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATIONGIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.END OF DATA SHEET

Fuel and Lubricant Solutions E-mail address: RegXcellenceFuelLubes@basf.com Emergency telephone number 24 Hour Emergency Response Information CHEMTREC: 1-800-424-9300 BASF HOTLINE: 1-800-832-HELP (4357) Other means of identification Chemical family: inhibitors 2. Hazards Identification