Material Safety Data Sheet - Fastener Group

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Material Safety Data SheetRevision Number: 004.1Issue date: 01/07/20141. PRODUCT AND COMPANY IDENTIFICATIONProduct name:Product use:LOCTITE 243 THREADLOCKERAnaerobic AdhesiveCompany address:Henkel Corporation2515 Meadowpine BoulevardMississauga, Ontario L5N 6C3IDH number:1329837Item number:1329837Region:CanadaContact information:Telephone: 905.814.6511MEDICAL EMERGENCY Phone: Poison Control Center1-877-671-4608 (toll free) or 1-303-592-1711TRANSPORT EMERGENCY Phone: CHEMTREC1-800-424-9300 (toll free) or 1-703-527-3887Internet: www.henkelna.com2. HAZARDS IDENTIFICATIONPhysical MERGENCY OVERVIEWWHMIS hazard class:D.2.BCAUSES EYE IRRITATION.MAY CAUSE ALLERGIC SKIN REACTION.MAY CAUSE SKIN AND RESPIRATORY TRACT IRRITATION.Relevant routes of exposure:Skin, Inhalation, EyesPotential Health EffectsInhalation:Skin contact:Eye contact:Ingestion:May cause respiratory tract irritation.May cause allergic skin reaction. May cause skin irritation with discomfort or rash.Contact with eyes will cause irritation. Pain and discomfort. Excess tearing.May be harmful if swallowed.Existing conditions aggravated byexposure:Eye, skin, and respiratory disorders.See Section 11 for additional toxicological information.3. COMPOSITION / INFORMATION ON INGREDIENTSHazardous componentsCAS NUMBER%Polyglycol dimethacrylateTetramethylene dimethacrylateAdipic acid polymer with neopentylglycol, 1,4-butanedioland 1,3-propanediyl diacrylateAmorphous fumed silicaPropane-1,2-diolPolyamide 2-81-710 - 3010 - 30208945-12-410 - 30101-37-15 - 098-82-81-51-51-50.1 - 10.1 - 1IDH number: 1329837Product name: LOCTITE 243 THREADLOCKERPage 1 of 5

4. FIRST AID MEASURESInhalation:Move to fresh air. If not breathing, give artificial respiration. If breathing isdifficult, give oxygen. If symptoms develop and persist, get medical attention.Skin contact:Wash with soap and water. Remove contaminated clothing and footwear.Wash clothing before reuse. If symptoms develop and persist, get medicalattention.Eye contact:Flush with copious amounts of water, preferably, lukewarm water for at least15 minutes, holding eyelids open all the time. Get medical attention.Ingestion:Do not induce vomiting. Keep individual calm. Get medical attention.5. FIRE FIGHTING MEASURESFlash point: 93 C ( 199.4 F)Autoignition temperature:Not available.Flammable/Explosive limits - lower:Not available.Flammable/Explosive limits - upper:Not available.Extinguishing media:Foam, dry chemical or carbon dioxide.Special firefighting procedures:Wear self-contained breathing apparatus and full protective clothing, such asturn-out gear.Unusual fire or explosion hazards:NoneHazardous combustion products:Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organicfragments.Sensitivity to Mechanical Impact:Not available.Sensitivity to static discharge:Not available.6. ACCIDENTAL RELEASE MEASURESUse personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotectedpersonnel.Environmental precautions:Do not allow product to enter sewer or waterways.Clean-up methods:Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,universal binder, sawdust). Store in a partly filled, closed container untildisposal.7. HANDLING AND STORAGEHandling:Avoid contact with eyes, skin and clothing. Avoid breathing vapors or mists ofthis product. Wash thoroughly after handling.Storage:For safe storage, store at or below 38 C (100.4 F)Keep in a cool, well ventilated area away from heat, sparks and open flame.Keep container tightly closed until ready for use.For information on product shelf life contact Henkel Canada Customer Service at 800-263-5043.IDH number: 1329837Product name: LOCTITE 243 THREADLOCKERPage 2 of 5

8. EXPOSURE CONTROLS / PERSONAL PROTECTIONEmployers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposurecontrols and protective equipment for each task performed.Hazardous componentsACGIH TLVOSHA PELAIHA WEELOTHERPolyglycol dimethacrylateTetramethylene dimethacrylateAdipic acid polymer with neopentylglycol, 1,4butanediol and 1,3-propanediyl diacrylateAmorphous fumed nePolyamide resin1-Acetyl-2-phenylhydrazineNoneNoneNoneNone50 ppm (245mg/m3) PEL(SKIN)None10 mg/m3 ene50 ppm TWANoneNoneNoneEngineering controls:Local exhaust ventilation is recommended when general ventilation is notsufficient to control airborne contamination.Respiratory protection:Use a NIOSH approved air-purifying respirator with an organic vapor cartridge.Eye/face protection:Safety goggles or safety glasses with side shields.Skin protection:Use impermeable gloves and protective clothing as necessary to prevent skincontact. Neoprene, Butyl-rubber, or nitrile-rubber gloves.9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state:Color:Odor:Odor threshold:pH:Vapor pressure:Boiling point/range:Melting point/ range:Specific gravity:Vapor density:Flash point:Flammable/Explosive limits - lower:Flammable/Explosive limits - upper:Autoignition temperature:Evaporation rate:Solubility in water:Partition coefficient (n-octanol/water):VOC content:LiquidBlueCharacteristicNot available.Not available. 0.1 mm hg (27 C (80.6 F)) 149 C ( 300.2 F)Not available.1.09Not available. 93 C ( 199.4 F)Not available.Not available.Not available.Not available.SlightNot available.1.09 %; 11.88 g/lIDH number: 1329837Product name: LOCTITE 243 THREADLOCKERPage 3 of 5

10. STABILITY AND REACTIVITYStability:StableHazardous reactions:Will not occur.Hazardous decomposition products:Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. Irritating organicfragments.Incompatible materials:Strong oxidizing agents. Reducing agents. Strong alkalis. Oxygen scavengers.Other polymerization initiators. Heavy metals.Conditions to avoid:See "Handling and Storage" (Section 7) and "Incompatibility" (Section 10).11. TOXICOLOGICAL INFORMATIONToxicologically synergistic products:Not available.Refer to the following for Irritancy of Product, Sensitization to Product, Carcinogenicity, Reproductive Toxicity, Teratogenicity,and Mutagenicity.Hazardous Component(s)OSHA CarcinogenNTP CarcinogenIARC CarcinogenPolyglycol dimethacrylateTetramethylene dimethacrylateAdipic acid polymer with neopentylglycol,1,4-butanediol and ,3-propanediyl diacrylateAmorphous fumed silicaPropane-1,2-diolPolyamide oNoNoNoNoNoNoNoNoNoNoNoNoNoNoNoNoNoGroup 2BNoNoNoNoNoHazardous componentsLD50s and LC50sHealth Effects/Target OrgansNoneNoneAllergen, IrritantIrritant, AllergenPolyglycol dimethacrylateTetramethylene dimethacrylateAdipic acid polymer with neopentylglycol,1,4-butanediol and ,3-propanediyl diacrylateAmorphous fumed silicaPropane-1,2-diolPolyamide resin1-Acetyl-2-phenylhydrazineCumene(Specifically Regulated)NoneNo RecordsNoneNo Target OrgansNoneNo RecordsNoneOral LD50 (RABBIT) 18 g/kgOral LD50 (RAT) 30 g/kgNoneNo Target OrgansIrritantNo RecordsAllergen, Blood, Kidney, Mutagen, Someevidence of carcinogenicityNoneOral LD50 (RAT) 2.91 g/kgOral LD50 (RAT) 1,400 mg/kgInhalation LC50 (RAT, 4 h) 8,000 mg/lCentral nervous system, Irritant, Lung12. ECOLOGICAL INFORMATIONEcological information:Not available.IDH number: 1329837Product name: LOCTITE 243 THREADLOCKERPage 4 of 5

13. DISPOSAL CONSIDERATIONSInformation provided is for unused product only.Recommended method of disposal:Follow all local, state, federal and provincial regulations for disposal.14. TRANSPORT INFORMATIONThe shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification maybe different for bulk packaging.Canada Transportation of Dangerous Goods - GroundProper shipping name:Not regulatedHazard class or division:NoneIdentification number:NonePacking group:NoneInternational Air Transportation (ICAO/IATA)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNoneWater Transportation (IMO/IMDG)Proper shipping name:Hazard class or division:Identification number:Packing group:Not regulatedNoneNoneNone15. REGULATORY INFORMATIONCanada Regulatory InformationCEPA DSL/NDSL Status:All components are listed on or are exempt from listing on the Canadian DomesticSubstances List.United States Regulatory InformationTSCA 8 (b) Inventory Status:All components are listed or are exempt from listing on the Toxic Substances Control ActInventory.16. OTHER INFORMATIONThis material safety data sheet contains changes from the previous version in sections: 9 and 16This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), andthe MSDS contains all the information required by the CPR.Prepared by: Diane Annis, Sr. Regulatory Affairs SpecialistDISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, HenkelCorporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methodsHenkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methodsmentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property andpersons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particularpurpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damagesof any kind, including lost profits.IDH number: 1329837Product name: LOCTITE 243 THREADLOCKERPage 5 of 5

Product name: LOCTITE 243 . the MSDS contains all the information required by the CPR. Prepared by: Diane Annis, Sr. Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose .