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Book of Abstractsrd23 LectureConference onPhotochemistryOctober 8 - 10, 2012in Potsdam

Picture on cover page: Neues Palais, PotsdamCopyright: Karla Fritze, University of Potsdam

3Contents1 Organization1.1 General Information . . . . . . . . . . . . . . . . . . . . . . . . . . . .1.2 Travel Information . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5562 Exhibitors73 Program94 List of Posters125 Oral PresentationsMonday . . . . . . .Session 1 . . . .Session 2 . . . .Tuesday . . . . . . .Session 3 . . . .Session 4 . . . .Session 5 . . . .Session 6 . . . .Wednesday . . . . .Session 7 . . . .Session 8 . . . .1920202633333842464848536 Posters7 List of Authors.57121

4CONTENTS

51 Organization1.1General InformationScientific CommitteeLuisa de ColaMartin GoezHans-Gerd LöhmannsröbenHeinz MustrophWerner NauSven RauLocal CommitteeHans-Gerd LöhmannsröbenMichael U. KumkeSascha EidnerInformation on Abstracts and RegistrationGDCh Conference ServiceClaudia BirknerPhone: 49 (0)69 7917 366Fax: 49 (0)69 7917 1366E-mail: tg@gdch.deConference AddressUniversity of PotsdamInstitute of Chemistry(Physical Chemistry)Campus Golm, Haus 27Karl-Liebknecht-Str. 24-2514476 Potsdam, Germany

61.21 OrganizationTravel InformationLayout PlanPublic transportationNear to the conference venue is a train station “Potsdam Golm“, which is a regular stop of the RE1 (to and from Berlin main station), RB20 (to and from Potsdammain station) and RB21 (ply between between Berlin main station and Potsdam mainstation). Another possibility is to take the S-Bahn from Berlin to Potsdam main station and subsequently going by bus (605 – direction “Wissenschaftspark Golm” or 606“Alt-Golm”).By carTake the autobahn A10 and leave at Potsdam-Nord (exit 25) or at Leest (exit 24). Afterwards following directional signs to Golm or “Wissenschaftspark Golm”. The complex Golm is located opposite to the train station “Potsdam Golm”, Karl-LiebknechtStraße 24-25.

72 ExhibitorsWe kindly thank the following exhibitors ATTO-TEC GmbH Becker & Hickl GmbH Colibri Photonics GmbH Fraunhofer Institut für angewandte Polymerforschung (IAP) GWU-Lasertechnik Vertriebsges. mbH Hamamatsu Photonics Deutschland GmbH HORIBA Jobin Yvon GmbH Menlo Systems GmbH Nanosurf GmbH Optikexpertisen Dr. Volker Raab OPTIMARE Analytik GmbH & Co. KG PerkinElmer LAS (Germany) GmbH Photonik BB, JP-ProteQ TOPAG Lasertechnik GmbH

82 Exhibitors

93 Program (Updated on27/9/2012)Monday, October 8th , 2012page13:00 Opening remarks13:10 “Fluorescent sensors and logic gates”14:00 “Anion recognition in organic and aqueous mediausing artifical receptors”14:20 “9-Arylbenzo[b]quinolizinium derivatives as multicolor chemosensors”14:40 “Fluorescence dye dyads for single molecule superresolution microscopy”15:00 “Absolute fluorometry in the life and material sciences: characterization of fluorescent particles andnew quantum yield standards”15:20 “Quantum Dots as versatile biosensors for FRETbased multiplexed diagnostics”A.P. de SilvaE. Kataev2021H. Ihmels22D. Wöll23U. Resch-Genger24N. Hildebrandt25R.J. MeierC. SpiesF. Biedermann262728E. Sousa da Silva29O. Wenger30T. Kottke31U. Pischel3215:40 Coffee break16:10 “Optical chemical sensing and imaging”17:00 “Photophysics of photoacids based on pyrene”17:20 “Strongly fluorescent switchable perylene-bisdiimide(PDI) host-guest complexes with cucurbit[8]uril inwater”17:40 “Influence of solvents on the ground and excitedstates properties of 2-(1-Naphthyl)acetamide and 2Naphthoxyacetic acid18:00 “Influence of donor-acceptor-distance on photoinduced PCET”18:20 “Flavin acts as a red light sensor in an animal-likecryptochrome”18:40 “Photochromic Switching of a SpiropyranCucurbit[7]uril Supramolecular Complex”19:00 Poster session and refreshments

103 ProgramTuesday, October 9th , 20128:309:20“Non-linear optics of porphyrins”“Amplification of optical signals as result of molecular photoreactions by thermotropic self-organisationand phase separation”9:40 “Structural control of photoinduced dynamics in 4Himidazole ruthenium complexes”10:00 “Photolithography and fueling of molecular rotorswith singlet oxygen”10:20 “Photoprocesses in chemical education”M. SengeJ. Stumpe3334M. Wächtler35T. Linker36M. Tausch37K.-I. Sakai38A. Neubauer39R. Beranek40G. Seyfang41P. Klán42A. Hennig43C. Kerzig44S. Banerjee4510:40 Coffee break11:00 “Control of hydrogen bonding towards optical functionalization”11:50 “Spectroscopic studies of a photocatalytic system forhydrogen generation”12:10 “Novel artificial photosynthetic routes – two examples”12:30 “IR-Laser induced population transfer in NH3 – experimental test-scheme to prepare a chiral superposition state for the measurement of PV E betweenenantiomers of chiral molecules”12:55 Photograph and lunch break14:00 “Photochemistry of organic compounds on ice andsnow surfaces”14:50 “Quantification of surface functional groups by spectroscopic methods”15:10 “Unexpected facilitation of radical-anion photoionization by protonation”15:30 “Solving an anomaly of the resonance Raman spectrum of ß-carotene with Duschinsky rotation”15:50 Coffee break16:20 “Robust and sensitive FRET-systems involving Ru- W. Bannwarthcomplexes”17:10 Förster award lecture“Using Organic Photochemistry to Make Nanoparti- J.C. Scaianocles and Nanoparticles to Direct Organic Chemistry”4647

1118:00 General Meeting of the Division of Photochemistry,lecture hall20:00Conference dinner at “Drachenhaus”, Maulbeerallee 4a, 14469 PotsdamWednesday, October 10th , 20128:30“Covalent and non-covalent nanocomposites ofgraphene oxide and reduced graphene oxide with dyemolecules”9:20 “Design of functional NIR-photoinitiator systems forcoating applications”9:40 “Mechanism and reversibility of DNA compactionby photosensitive surfactants”10:00 “Slow spin transitions in Iron(II) complexes: on theway to bistable spinisomers”10:20 “Magnetic field effects in chemistry: how does an external magnetic field influence a chemical reaction?”A. Wojcik48B. Strehmel49Y. Zakrevskyy50G. Hörner51G. Grampp5211:00 “Photoprotection of human skin”B. Herzog11:50 “New techniques for high-speed, high-resolution B. Schmidtspectroscopy”12:40 “Photochemical synthesis of the anti-malarial drug D. Kopetzkiartemisinin in continuous flow”535410:40 Coffee break13:30 Concluding remarksM. Goez55

124 List of PostersPageP1P2P3P4P5P6P7P8P9P10All-optical reversible manipulation of microgel swelling usingphotosensitive surfactantZakrevskyy, Y., Richter, M., von Klitzing, R., Santer, S.Acyl-DBD dyes: Fluorescence lifetime probes for lipophilicmicroenvironmentsWawrzinek, R., Wessig, P., Möllnitz, K., Nikolaus, J., Schwarzer, R.,Müller, P., Herrmann A.5859Highly sensitive multiplexed FRET immunoassays usingspectral crosstalk correctionGeißler, D., Stufler, S., Löhmannsröben, H.-G., Hildebrandt, N.60The [2.2.2]heptamethinecyanine dye: A G-quadruplex selective ligandThomas, L., Ihmels, H.611,2,3-triazol-1,4-diyl-Fluoroionophores for K -, Na - andCa2 -IonsSchwarze, T., Müller, H.,Ast, S., Holdt, H.-J.62Active Micro-Optics for Spatial Polarization ControlRutloh, M., Schaal, F., Pruss, C., Osten, W., Rossbach, R., Jetter,M., Weidenfeld, S., Michler, P., Stumpe, nicNanocomposites For Holographic Optical and PhotonicElementsSakhno, O., Stumpe, J., Smirnova, T.64Conformational Control of Tetrapyrrole Cofactors in NatureSenge, M. O., MacGowan, S. A.65Semiconductor Quantum Dots in FRET-ImmunoassaysLiermann, K., Geißler, D., Stufler, S., Wegner, D., Löhmannsröben,H.-G.Efficiently Quenched Fluorescent NIR Probe for Detectionof Enzyme ActivitySloniec, J., Resch-Genger, U., Hennig, A.6667

13P11P12P13P14P15P16P17P18P19P20P21Light makes it work. Molecular reaction dynamics investigation at ultrafast time scale on NADPH:protochlorophyllideoxidoreductaseGarrone, A., Fey, S., Schäfer, J., Hermann, G., Dietzek, B.68Multi-Photon-Spectroscopy with Quantum Dots in Life ScienceHill, D. Meiling, T.T., Stufler, S., Löhmannsröben, H.-G.69Photochemical investigations of the interactions of annelatedquinolizinium derivatives with abasic-sites in DNABenner, K., Ihmels, H.70More Photons, Higher Sensitivity, Lower Artifacts, HigherThroughput – a Completely Computer-Controlled LaserFlash Photolysis SetupFehse, D., Goez, M.71Structural investigations of Eu3 doped CeO2 n nanocrystalsusing fluorescence line-narrowing spectroscopyPrimus, P.-A., Kumke, M.U.72Surface-Enhanced Raman Spectroscopy Using GoldNanoparticles Arranged on DNA Origami SubstratesBald, I., Prinz, J., Schreiber, B., Keller, A.73Determination of brightness values of luminescent particlesWürth, C., Behnke, T., Hoffmann, K., Resch-Genger, U.74Absolute photoluminescence quantum yield determination ofnear-infrared emissive quantum dotsHatami, S., Leubner, S., Lesnyak, V., Gaponik, N., Würth, C.,Grabolle M., Eychmüller, A., Resch-Genger, U.75Role of spacer layer in localized surface plasmon resonanceassisted random laserHeydari, E., Stumpe, J.76Gold nanoparticles: Plasmons and ExcitonsBomm, J., Stumpe, J.77Synthesis, Characterization and Applications of Thermosensitive Gold QDsBomm, J., Stumpe, J.78

14P22P23P24P25P26P27P28P29P304 List of PostersInfluence of the Particle Size on the Optical Properties ofCer-doped Yttrium Aluminum Garnet (YAG:Ce)Kaiser, M., Wuerth, C., Resch-Genger, U., Vorshove, M., Felbeck, T.,Kynast, U.79Aggregation Phenomena of Host and Guest Upon the Loading of Dendritic Core-Multishell Nanoparticles with Solvatochromic DyesFleige, M., Ziem, B., Grabolle, M., Haag, R., Resch-Genger, U.80Suitable Labels for Molecular Imaging – Influence of DyeHydrophilicity on the Spectroscopic Properties of IgG ConjugatesPauli, J., Licha, K., Berkemeyer, J., Grabolle, M., Resch-Genger, U.81Oligo(phenylenevinylene)s with Multiple Basic Sites: Optical Responses to Changes of the EnvironmentMoschel, S., Schmitt, V., Detert, H.82Photochromic properties of 10 ,30 ,30 -trimethyl-6-piperidino(indoline-20 ,3-3H-naphtho[2,1-b][1,4]-oxazinede Moraes, I.R., Schäfer, J., Dietzek, B.83Mixed valence solids with micro- and nano-shaped crystalsexhibiting salient photosensitivityXhaxhiu, K., Korpa, A., Deiseroth, H.-J., Schmidt-Grund, R., Bente,K.Visible light-driven photooxidation of water at hybrid photoanodesWang, L., Bledowski, M., Ramakrishnan, A., Khavryuchenko, O.V.,Beranek, R.Enhanced degradation of 4-chlorophenol at surface-modifiedTiO2 photocatalysts prepared via a visible-light photosynthetic routeNeubert, S., Ramakrishnan, A., Mei, B., Wang, L., Bledowski, M.,Strunk, J., Muhler, M., Beranek, R.Photocatalytic water reduction with ruthenium polypyridylchromophoresStaehle, R., Filipović, M., Losse, S., Vos, J.G., Ivanović-Burmazović,I., Rau, S.84858687

15P31P32P33P34P35P36P37P38P39P40P41Scanning Electrochemical Microscopy: Investigation of Oxygen Evolution from Nanostructured Iron Oxide FilmsBülter, H., Schmidt, I., Dosche, C., Wittstock, G., Mátéfi-Tempfli, S.,Mátéfi-Tempfli, M., Denuault, G.88Modified Carbon Nitrides for the Photocatalytic HydrogenEvolution from WaterRichter, D., Zaake-Hertling, H., Hey-Hawkins, E., Gläser, R.89Photochemical Cobalt-Catalysed [2 2 2] Cycloaddition reactions: Small changes with big effectsKral, K., Hapke, M., Checinski, M.90Cobalt- and photo-catalyzed [2 2 2] cycloaddition reactionsHapke, M., Fischer, F., Kral, K., Thiel, I., Jungk, P.91Nanocomposite photocatalysts for enhanced hydrogen generationSoldat, J., Marschall, R., Wark, M.92Conjugated Microporous Polymers for Heterogeneous PhotocatalysisZhang, K., Antonietti, M., Vilela, F.93Identification of DNA Photoproducts – Formation of IsocyanatesRolf, J., Buschhaus, L., Kleinermanns, K.94Excited-state properties in pH-switchable Ruthenium dyesWächtler, M., Bräutigam, M., Kupfer, S., Guthmuller, J., Popp, J.,Rau, S., Gonzaléz, L., Dietzek, B.95Novel molecular rod-constructs as probes for fluorescenceapplicationsWessig, P., Techen, A., Kumke, M.U., Czapla, S., Möllnitz, K.96A Potential Entry to Briarellins and Asbestinins by an [2 , R., Bach, T.97Enantioselective Catalytic Intramolecular [2 2] Photocycloaddition of 2-QuinolonesMaturi, M.M., Bach, T.98

16P42P43P44P45P46P47P48P49P50P51P524 List of PostersEnantioselective [2 2] Photocycloadditions Catalyzed byChiral Oxazaborolidine Based Lewis AcidsBrimioulle, R., Guo, H., Bach, T.99Spectroscopic characterization of novel cell-penetrating peptide analogous for drug carrier applicationsGehne, S., Sydow, K., Dathe, M., Kumke, droxybenzo[a]pyrene and Monoclonal Antibodies usingFluorescence Line Narrowing SpectroscopyKlier, D., Eisold, U., Kumke, M.U.101Quantum Optics and PhotochemistryVester, M., Finkler, B., Jung, G.102Optical and Electrochemical Investigation of Trigonal Dendrimers Based on TriarylaminesZieschang, F., Lambert, C.103Photochemically Generated Singlet Oxygen as MechanisticProbe for the Interaction of PolyacenesKlaper, M., Linker, T.104Controlling the Reactivity of Polyacenes Towards their PhotooxidationFudickar, W., Linker, T.105Cyanine dyes – Are they still suitable for new fluorescentprobes?Drewitz, A., Brauns, C., Gutmann, E., Reiner, K., Keil, D., Ernst,S., Senns, B., Mustroph, H.106Photochemistry of Functional NIR-Photoinitiator SystemsBrömme, T., Horst, J., Pinto, P.S., Strehmel, B.107Teaching an old dog new tricks: Quantum state selective detection of molecular chlorine by high-resolution cavity ringdown spectroscopyForsting, T., Maul, C.108Laser Ionization of Aromatic Compounds at AtmosphericPressureBrendler, C., Riebe, D., Ritschel, T., Beitz, T., Löhmannsröben, H.G.109

17P53P54P55P56P57P58P59P60P61P62P63Light induced effects in azobenzene-containing star-like liquid crystalsTomczyk, J., Sobolewska, A., Stumpe, J.110Talbot Imaging Phenomena on Polymer Particle ArraysGörnitz, E., Stumpe, J.111Photophysical Properties of Hydroxyacridizinium Ions: ANovel Class of Water-Soluble PhotoacidsSchäfer, K., Ihmels, H., Bohne, C.112DNA photoreacts by Norrish α-cleavage to IsocyantesBuschhaus, L., Rolf, J., Kleinermanns, K.113Photohysics of Protochlorophyllide a – a natural precursorin the biosynthesis of chlorophyllDietzek, B., Schmitt, M., Popp, J., Hermann, G.114Holographic inscription of surface structures suitable for organic DFB lasers using light induced mass transport in anazobenzene containing materialDöring, S., Rabe, T., Rosenhauer, R., Rutloh, M., Stumpe, J.115Photo-Crosslinking of Copolyimide Films with Maleimide asCrosslinkerHunger, K., Buschhaus, L., Kleinermanns, K.116Ab initio electronic wave packet dynamics and charge separation in organo-metallic moleculesRamakrishnan, R., Raghunathan, S., Nest, M.117Electron Transfer Dynamics from Meso-Tetrakis(p-Carboxyphenyl) Porphyrin into Colloidal TiO2 and AuTiO2 NanoparticlesRenganathan, R., Kathiravan, A.118Quantum chemical calculations and open-system density matrix simulations for self-assembled monolayers of molecularswitches on surfacesUtecht, M., Floss, G., Klamroth, T., Saalfrank, P.119UV light induced hydrogen transfer in guanosine-guanosineaggregatesBraun, M., Hunger, K., Buschhaus, L., Kovalenko, S. A., Improta,R., Kleinermanns, K.120

184 List of Posters

Optikexpertisen Dr. Volker Raab OPTIMARE Analytik GmbH & Co. KG PerkinElmer LAS (Germany) GmbH Photonik BB, JP-ProteQ TOPAG Lasertechnik GmbH. 8 2 Exhibitors. 9 . Rau, S., Gonzal ez, L.,