DRILLING PRODUCTS DESCRIPTIVE - Iowa State University

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DRILLING PRODUCTS DESCRIPTIVEDEBRA BAC TERRITORY SALES MANAGERdebra.bac@cetco.com 847.212.0852March 21, 20141DRILLING PRODUCTS

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CETCO INTRODUCTIONCETCO is a wholly-owned subsidiary ofAMCOL International CorporationAbout AMCOLNYSE “ACO”Founded in 1927Operating in 26 Countries2,200 EmployeesGlobal Supply ChainServing Diverse MarketsCosmetics, Well Drilling,Pet Products, Metalcasting,Oilfield Services, Transportation,Detergents, Landfill lining3DRILLING PRODUCTS

WORLDWIDE CAPABILITYMore than 40 offices in 26 countriesR&D TeamDegrees:Bachelors : 35Masters : 6Ph.D.’s : 14Disciplines:Chemistry: 37Biochemists: 4Polymer science: 6Colloid science: 5Geologists: 3Locations:35 based in U.S.12 based in Europe8 based in AsiaActive patents:103 US (60 CETCO)350 World Patents4DRILLING PRODUCTS

CETCO DIVISIONSRemediation TechnologiesInnovative ProgramsLand and Water SolutionsEnvironmental ExpertiseVapor Intrusion BarriersSolidification/StabilizationServing Construction, NSF Liners, WaterTreatment, & Sediment Capping markets5DRILLING PRODUCTSLining TechnologiesIndustry Leader in GCL’sExpert Technical StaffValue EngineeringSpec ReviewServing Landfill, Mining, Power,Wastewater, and Civil/Highway markets

CETCO DIVISIONSBuilding MaterialsCustom Fit SolutionsNew and Remedial ConstructionActive and Passive WaterproofingHydroshield Quality Assurance ProgramEngineering SupportServing Greenroof, Plaza Decks,Foundation, & Parking Deck markets6DRILLING PRODUCTSDrilling ProductsThe Newest SolutionsField Engineering ExpertiseCost Effective SolutionsAdvanced Polymer ScienceBentonite TechnologyServing Environmental, Geothermal,Horizontal, and Foundation drilling markets

MARKETS SERVEDNon-Oil & Gas DrillingEnvironmental DrillingFoundation DrillingGeotechnical DrillingGeothermal HeatPump GroutingHorizontal DirectionalDrillingMining & Exploration7DRILLING PRODUCTSMonitoring WellDrillingSlurry SolidificationSlurry WallsWaterwellAbandonmentWaterwell DrillingWaterwell GroutingWaterwellRehabilitation

WYOMING SODIUM BENTONITE: ITS ORIGINLarge volumes in western U.S.Bighorn BasinFormed during Cretaceous PeriodFormed by volcanic ashInland seaMost bentonite companies havemining operations in this region8DRILLING PRODUCTS

BENTONITE MININGTopsoilMining of bentonite is performed at the surfaceSubsoilBentonite reserves are located below theoverburden and range from 2-7 feet thickOverburdenAMCOL uses a mining process known asbackcasting where reclamation is concurrentlydone by using the overburden and soils fromsubsequent pits to fill the ones before themBy using this approach, the mine is reclaimedas quickly as possible and “livespreading” thetopsoil provides the best seed-bed possibleBentoniteOnce the bentonite is exposed and cleaned,further testing is done to confirm the gradeOften bentonite is field dried to save energy9DRILLING PRODUCTS

BENTONITE MINING10DRILLING PRODUCTS

100 TON HAUL WAGONSTRANSPORT THE BENTONITE11DRILLING PRODUCTS

PROCESSING FACILITIESBELLE FOURCHE, SDCOLONY, WYLOVELL, WYOnce the quality of the bentonite has beenconfirmed it is transported to processing facilities12DRILLING PRODUCTS

MANUFACTURING PLANTLOVELL, WY13DRILLING PRODUCTS

WYOMING SODIUM BENTONITEHigh swelling clayAbility to adsorb large quantities ofwaterComposed of many stacks ofplatelets like a stack of cardsExpands up to 20 times its volumeOne inch3 covers 66 football fieldsOne inch high contains between35,000-40,000 layers (stressesgood mixing)14DRILLING PRODUCTS

CALCIUM BENTONITE & OTHER SODIUM BENTONITESCalcium bentonite is found all over the world southeastern USCalcium bentonites are not the high swelling type, low swellingDue to the needle like structure, calcium bentonite does notprovide gel strength and fluid-loss control. No sealingCalcium bentonite is used as floor sweep and oil dry productsBentonite found in southwestern US is not as pure as thebentonite beds found in Wyoming and Montana. They cancontain other minerals such as gypsym15DRILLING PRODUCTS

OTHER SOURCES OF BENTONITELow swelling sodium/calcium bentoniteCaliforniaOregonUtahTexas16DRILLING PRODUCTS

COMPARISON WYOMING BENTONITE WITH OREGONBENTONITEGranular Products Dry Versus 48 Hour Swell in DI Water17DRILLING PRODUCTS

CALCIUM ortal/basf/ien/dt.jsp?setCursor 1 55402318DRILLING PRODUCTSSODIUM jects/radionuclide-wastecontainment/

DRILLING PRODUCTS & SERVICESDrilling FluidsGroutsSealantsPolymersFoams & AdditivesWell Rehabilitation ProductsOn-Site Engineering19DRILLING PRODUCTS

DRILLING FLUIDS20DRILLING PRODUCTS

EXTRA HELP WITH FLUID LOSS IN UNCONSOLIDATEDFORMATIONSIncreased Fluid Loss Control21DRILLING PRODUCTS

BARREL YIELDDescribes the number of barrels of a given viscosity bentoniteslurry that can be made from a 1 ton of claySUPER GEL-X or VELOXITY-PRO High Yield Bentonite 200-230 bblsHYDRAUL-EZ HDD specialty bentonite 165-185 bblsPREMIUM GEL or PUREGOLD GEL API grade 90 bblsExamples215 bbls x 42 gal 9,030 gallons of slurry185 bbls x 42 gal 7,770 gallons of slurry90 bbls x 42 gal 3,780 gallons of slurry22DRILLING PRODUCTS

POLYMERS AND ADDITIVES23DRILLING PRODUCTS

THREE BASIC TYPES OF POLYMERSSynthetic PolymerINSTA-VIS PLUSINSTA-VIS DRYACCU-VISModified Natural PolymerREL-PACREL-PAC XTRA-LOWSUPER PACSUPER PAC XTRA-LOWNatural PolymersSUSPEND-ITPUREGOLD CLEANDRILLVARIFLO QD24DRILLING PRODUCTS

IMPORTANT ADDITIVESDRILL-TERGECLAY CUTTERCLAY CUTTER DRYSUPER THINCETCO JOINT COMPOUNDPUREGOLD LUBEMAGMA FIBERMULTI-SEALMACRO-FILL25DRILLING PRODUCTS

WHY USE POLYMERS & ADDITIVES?To enhance desired qualities of SUPER GEL-X or VELOXITYPRO drilling fluidsTo adjust drilling fluids to soil conditionsTo increase efficiency in drilling operations and increaseoverall profits for drilling contractors26DRILLING PRODUCTS

FINE TO MEDIUM SANDSUPER GEL-X andREL-PAC XTRA-LOWDrilling FluidMINIMAL Fluid Loss27DRILLING PRODUCTSWater or drilling fluidwith poor fluid lossHIGH Fluid Loss

GROUTS & SEALANTS28DRILLING PRODUCTS

GROUTS & SEALANTS29DRILLING PRODUCTS

GROUTING & SEALING - PURPOSETo seal the annulus between the borehole and the well casingTo provide a low-permeability seal that will prevent the mixing of aquifersTo prevent the vertical migration of surface waterSealing MaterialsUsed in conjunction with groutUsed as a hole abandonment material30DRILLING PRODUCTS

GEOTHERMAL GROUTS31DRILLING PRODUCTS

CETCO ONLINE PRODUCT USAGE CALCULATORS32DRILLING PRODUCTS

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The information contained herein supersedes all previous versions, and is believed to beaccurate and reliable. For the most up-to-date information, please visit www.CETCO.com.CETCO accepts no responsibility for the results obtained through application of thisinformation. CETCO reserves the right to update information without notice.REV 4-201435DRILLING PRODUCTS

DRILLING PRODUCTS CETCO INTRODUCTION CETCO is a wholly-owned subsidiary of AMCOL International Corporation About AMCOL NYSE "ACO" Founded in 1927 Operating in 26 Countries 2,200 Employees Global Supply Chain Serving Diverse Markets Cosmetics, Well Drilling, Pet Products, Metalcasting, Oilfield Services, Transportation, Detergents, Landfill .