Green Chemistry Experiments For Remote Locations

Transcription

Workshop White PaperGreen Chemistry Experiments forRemote LocationsBelém, Pará, BrazilNovember 4-6, 2016With thanks to:

2ContentsExecutive summary . 31. Introduction . 41.1 Green Chemistry today . 41.2 Background to Sustainable Development in Brazil . 51.3 Green Chemistry Awareness in Brazil . 61.4 Green Chemistry Education Initiatives . 71.5 Why is this topic important? . 82. Chemistry education in Brazil . 92.1 Overview of the education system . 92.2 Examples of high school education experiences in cities and rural locations . 113. Teaching Green Chemistry in Remote Locations . 163.1 Teaching green chemistry in the Amazon. 163.2 Teaching green chemistry in the islands of Pará . 173.3 Existing green chemistry experiments . 173.4 Sources of information for green chemistry activities. 204. Key Challenges . 205. Next Steps . 216. Support Needed . 25Attachment 1: Pictures of Belém, Pará, Brazil . 26Attachment 2: Public high schools in Belém - infrastructure . 28Attachment 3: Different buildings of the Escola do Bosque . 31Attachment 4: Equipment made with day-to-day materials . 34

3Executive summaryBrazil is a large and diverse country. It has characteristics favorable to embedding greenchemistry education in schools and universities, including its rich biodiversity and vastavailability of natural resources, However, it also presents many challenges including thediverse culture and educational approaches in different regions of the country and thechallenging context in many schools, which lack laboratories and experimental classes. Theworkshop “Green Chemistry Experiments for Remote Locations”, a partnership between theAmerican Chemical Society and the Brazilian Green Chemistry School, brought togetherteachers, professors and researchers from Brazilian schools and universities withinternational experts to discuss possible strategies to help spread a practical greenchemistry education in Brazil. Challenges identified by participants included: The need to develop a curriculum that enable educators to utilize activities relevant tolocal contexts and the knowledge of students The lack of a community of practice for educators in green chemistry Educational development or co-production with teachers and students – identify keypeople that can involve other people is very important Ensuring that green chemistry is integrated into the training of chemistry teachers Improving the working environment, infrastructure and access to materials andresources for teachersTo overcome these challenges three programmes were proposed as starting points forembedding green chemistry in education in Brazil:1. Embed green chemistry in teaching degree education2. Developing a network of Green Chemistry Ambassadors by selecting and traininghighly-engaged educators from States across Brazil3. Developing an online platform to share tailored and translated educational materialsfor use by educators across Brazil4. Developing an online training course for educators and students using blended andinteractive materialsThe knowledge shared throughout the workshop and the proposed initiatives not only cantransform the landscape of green chemistry in Brazil, but also serve as inspiration forprojects that work on the theme in other countries with which Brazil has similarities,especially in Latin America and the Caribbean and Africa.

41. IntroductionChemistry is at the core of nearly all human activities and is vital to economic developmentand to the creation of new strategies to achieve a sustainable future. Green chemistry orsustainable chemistry aims to foster processes and products that are socially beneficial andutilize resources sustainably. Brazil has a wide range of characteristics that can enable it tobe at the forefront of sustainable chemistry as it is rich in biodiversity and natural resources,with intense solar radiation, plenty of water, and varied climatic conditions throughout thecountry.1.1 Green Chemistry today(by Norma Sbarbati Nudelman, University of Buenos Aires, Argentine)Green chemistry was defined as a set of principles to design a safer product, with a processpreventing the use of toxic reagents and producing the smaller amounts of waste materials.However, today, sustainable chemistry goes beyond those goals including other issues,such as: the energy economy, the emission’s reduction, the atom economy, the use ofrenewable energies, the reduction in fossil fuels and organic solvents, the use of naturalproducts as alternative sources, the E-factor greenness of an industrial process, thesustainable use of agrochemicals, biofuels and biocatalysts, etc. Processes designed bygreen routes help in the promotion of resource and energy utilization efficiently. It involveslow level of waste, and is inherently safe making the processes economicThe experience of the Argentine Academy of Sciences in offering theoretical-practicalcourses on these subjects for secondary school teachers goes back to more than 10 yearsago. The first one at a Latin American scale took place in 2004, and since then more than 40theoretical-practical courses/workshops have been offered. Teachers and students are veryenthusiastic for this kind of environmentally friendly chemistry. The workshops also includeexperiments on green chemistry that can be done with very low-cost and easily accessibleresources, and visits to local industrial plants.Recent initiatives alert on the urgency of applying more environmentally friendly chemicalsand processes to mitigate climate change of anthropogenic origin. Some of them are: theletter from the Academies to the WS of Rio 20; the FAO’s Program for Food Security to allby 2030; some of the United Nations 17 Sustainable Development Goals 2016-2030; the“Laudato Sii” P. Francis encyclical; the COP21, and the agreement on climate change(Paris, Nov 2015) , and the “Children as agent of change”’ initiative in the 2015 Workshop inthe Vatican organized by the Pontifical Academy of Science; and the 20th Annual Green

5Chemistry & Engineering Conference: “Advancing Sustainable Solutions by Design”(Portland, USA June 2016). All of these initiatives show that sustainable development is notonly a matter of science; it is a catalyst for change, an innovative approach to problemsolving and a long-term solution to global sustainability challenges. And it requires a radicalredesign of our social behavior, and “bottom-up” voluntary actions: education is essential toachieve both goals.1.2 Background to Sustainable Development in BrazilNowadays, Brazil invests around 1.5% of its GNP on research and innovation. It has severaldistinguished research centers and universities and is placed 13th in the number of refereedscientific publications. However, on the other hand, Brazil owns less than 0.5% of the world’spatents and was placed 63rd in a recent international education test of science for 15 yearolds. Therefore, there is a contrast between state of the art science initiatives and a poorbasic education and technological innovation environment.Brazil’s GNP oscillates between 6th and 8th in the world and its chemical turnover showssimilar trends. However, the treat balance in chemicals is strongly negative and seems to beon the rise. Some internal markets for chemicals are attractive, such as cosmetics, agrochemicals, and food additives for animals.Petroleum extraction and production is also a relevant activity. Because of recent changes inBrazilian regulations on exploring the large deep and ultra-deep deposits, international oiland service companies are increasingly interested in investing in equipment and materialsthat can be used in the region.Other key investment opportunities relates to cellulose, oils, sugarcane, and others. Expertsestimate that in 2020, the Brazilian market for chemicals produced from renewable sourcescould represent as much as 10% of the local chemical industry.Brazilian energy is already mostly produced by renewable sources, specially hydropower. Inaddition, the country has successful programs on biofuels such as the ethanol program.The first car that used ethanol as a fuel in Brazil was launched in 1925. Today, nearly allnew cars can run either on ethanol or gas. Life cycle analysis indicate that automobilestotally running on ethanol are almost carbon neutral. It is worth noticing that sugarcane isproduced in regions that are distant from protected areas rich in biodiversity, and that there

6is already a built infrastructure for collection, storage and transport of materials andproducts.During the early decades of the twentieth century ethanol was employed in Brazil as a rawmaterial for the chemical industry (producing ethyl chloride, acetic acid, acetic anhydride anda number of other products). Unfortunately, as petroleum prices came down, some of theseinvestments became unattractive, but that does not overshadow the success of the ethanolprogram. Finally, lessons learned from the ethanol program have also been valuable for thebiodiesel production.In fact, Brazil has taken a leadership position when it comes to developing green chemistryprocesses and bio-based materials and pharmaceuticals. Brazil was a pioneer large-scaleproducer of biofuels, bio-based plastics and bio-derived insecticides.However, vital to this vision is both the development of scientists with the necessary skillsand knowledge to develop new research avenues and industries based on green chemistryand a wider public awareness to support the green economy.1.3 Green Chemistry Awareness in BrazilWhile the relation between nature and science has always been in the mind of those wholive in a country with such natural richness, the concern to organize and disseminateinitiatives to promote sustainable development become more visible in the 1990’s.Short after the Rio Conference on Development and Environment (Rio92), ACS took part ona meeting about chemistry of the Amazon, resulting on a publication about this issue.Another workshop discussed how nature can be a treasured source of high value chemicalsand debated the use of biodiversity for sustainable development investigation of bioactiveproducts and their commercial application.In the following decade, green chemistry definitely gained space in Brazil after a meeting inFortaleza, Ceará with the participation of the Green Chemistry Institute in 2007. One of theoutcomes of this meeting was to officially install the Brazilian Network on Green Chemistry.The Brazilian Green Chemistry School was created in 2010, aiming both to develop state ofthe art green chemistry research that can be useful for industries and to train humanresources in this area. It has also a key role on society appreciation and acceptance ofgreen chemistry and develops dissemination activities to create a sense of green processesand products.

7The United Nations Conference on Sustainable Development (Rio 20) in 2012 brought a lotof media attention for sustainable development and gave a very important incentive for theBrazilian green chemistry programs.1.4 Green Chemistry Education InitiativesIn the 2010’s, green chemistry was included for the first time in the program of the chemistryweeks that happen yearly in universities and schools across Brazil. The initiative started withthe National Science & Technology Week 2011, coinciding with the International Year forChemistry, which theme was “Chemistry for a better world”. In the first year, the initiativereached over 25,000 students only in Rio de Janeiro.One of the activities offered by worldwide institutions in this opportunity was the distributionof a kit for kids to measure water pH in their local areas. Results were gathered to build amap with information about water around the world. In Brazil, the kits proved to be verypopular, as they were simple, colorful, relevant to students, and relevant to their local area.As a result, Brazil was the country that registered the biggest number of tests with this kit,which demonstrates the enthusiasm and desire to do practical chemistry and chemistry ofrelevance.In the following years, the Brazilian Green Chemistry School developed an increased varietyof outreach activities. They were simple and low cost, besides relevant to the localcommunities. Most programs had also a thematic focus, for instance, carbon dioxide, globalwarming, climate change, water acidification, processes for CO2 capturing, bio-basedplastics, and solvents.One of the strategies used by the Brazilian Green Chemistry School to make activitiesfeasible was stablishing partnerships with local companies such as Oxiteno, leader in themanufacture of surfactants and specialty chemicals. The company developed kits todemonstrate how they produce nail polishers and creams using non-toxic components. Theactivities were then taken to schools and events were students were excited to take part,working with lab clothes and laboratory glasses, mixing substances to make creams andthen testing them on their skin.The Oxiteno partnership helped to raise awareness of the innovation that was happening inBrazil, to show the relevance of this kind of innovation for industries and to demonstrate thedevelopment of sustainable materials in chemistry as a career option for students.

8Additionally, this program also created training opportunities for undergraduate students todevelop science communication skills.Besides working together with companies, another strategic partnership that had to bestablished in order to foster green chemistry education in Brazil was obviously workingtogether with schools. Between 2013-2014, the Brazilian Green Chemistry School developedpartnerships with high schools and technical schools. The main strategy was to bring groupsof students aged 14-17 inside the university to visit facilities such as a biorefinarydemonstration plant. They were very enthusiastic and very engaged.Building from this experience, a series of conferences was organized to share and multiplythe results.‘Teaching green chemistry in schools’ workshops were held in the Brazilian ChemistryEducation and Chemistry Congresses in 2014 and 2016. In these opportunities, not only theBrazilian Green Chemistry School presented its projects, but also heard from otherprofessors and teachers about their own experiences.Green chemistry courses for teachers were offered in different states of Brazil, includingAmazonas, Pará, Goiás, and Rio de Janeiro. However, there are still many regions to reach.1.5 Why is this topic important?Chemistry teachers and professors are key actors to engaging a new generation aroundchemistry throughout Brazil and to embed a culture of green chemistry. Over the past fiveyears, the Brazilian Green Chemistry School at the Federal University of Rio de Janeiro hasbeen developing practical workshops in collaboration with professors and students andtaken them to public schools and universities across the country.Green chemistry education offers an enticing opportunity to develop a new approach forBrazil to embed low-cost, non-toxic chemistry experiments into Brazilian schools that arerelevant to students’ everyday lives and demonstrate how they can utilize science to helpbuild a safer and more sustainable future for their communities and the planet.However, recently it has been observed that several schools are closing their labs andstopping practical experiments because of rising costs and limited availability of the properinstallations. This is a serious problem since lab work is an essential part of teachingchemistry and inspiring students.

9During the workshop “Green Chemistry Experiments for Remote Locations” internationalexperts, local experts and school teachers were gathered to discuss and disseminatesimple, low cost and locally relevant green chemistry experiments and activities that willengage students and ensure that a new generation of chemists is trained in green chemistry.2. Chemistry education in Brazil2.1 Overview of the education system1(Presented by Agnaldo Arroyo , Faculty of Education, University of São Paulo)The Brazilian Educational System has two mainlevels: basic education and higher education.Basic education is mandatory and extends fromkindergarten to high school students (4-17 yearold students). Higher Education is optional andincludes undergraduatestudies and post-graduate courses. In the public sphere, basiceducation is mainly a responsibility of localgovernments, with the federal governmentmainly responsible for Higher Education. Thereare, however, examples of public high schoolslinked to the federal government, as well asuniversities under the responsibility of stategovernments. In parallel to the public system,there are private schools at all levels ofeducation.While chemistry concepts are presented to 8th and 9th graders (or even earlier), Chemistry asa school discipline appears only in high school curriculum. Although part of the schools havescience laboratories, only a few actually use them for experimental practices – some schoolsuse the laboratories on regular theoretical classes, and others do not use them at all.According to data from the Brazilian government, 99% of public schools and 98% of privateschools have at least one computer. However, it is worth noting that those computers areoften used for administrative activities and are not available for teachers and students. The1Data can be found at 015 (PDF in Portuguese).

10same is true for internet connection: 95% of public schools and 99% of private schools haveit, but not all of them make the connection available to students and teachers. Added to thisis the poor quality of connection: in 52% of public schools and in 28% of private schools theinternet connection is lower than 2 Mbps.Besides regular high school courses, there are also in Brazil technical schools that educatestudents for a specific career (i.e. chemistry, pharmacy, electronics, agribusiness,biotechnology and so on), known as “technical schools”. These are mostly public and theresponsibility of the federal government. Their diploma is legally equivalent to one from highschool – that is, it allows students to apply for admission to a university. Usually technicalschools have better infrastructure than regular ones, and are a possible target group forexperimental chemistry programs.To become a chemistry teacher in Brazil, one has to take a chemistry undergraduate courseand choose a teaching course (a course that includes didactics, teaching methodology andother specific disciplines) to get an educational license. In 2008, there were only 15 of thesecourses in Brazil. In 2014, there were 58. However, many of them have empty places,indicating that offering the courses is not enough; an even bigger challenge is to attractstudents to take those courses. In addition, school dropout is also a problem.Brazilian students lack motivation to pursue chemistry education as a career. This can partlybe explained by the low salaries and difficult working environment science teachers facearound the country. Nevertheless, there is also the fact that many people had bad

11experiences with chemistry at school – “it is difficult”; “I don’t understand it”, “I can’t see itworking” – and thus decide not to continue to study it for a career.This suggests that any program or activity targeting green chemistry education must targetteachers, as multipliers of knowledge, but also engage with the challenges that they face.2.2 Examples of high school education experiences in cities and rurallocations2.1.1 Teaching chemistry in a federal high school in Rio de Janeiro(Presented by Luis Carlos Gomes, Colégio Pedro II)Luis Carlos Gomes is a chemistry teacher at Colégio Pedro II, a well-known and highly ratedpublic school in Rio de Janeiro city. It is linked to the Brazilian Ministry of Education and has179 years of history. Colégio Pedro II has 14 campuses (12 in the city of Rio de Janeiro and2 in smaller cities near Rio) and around 13,000 students from elementary school to highschool and on post-graduate courses (worth noticing, it does not have undergraduatecourses).Of the 14 campuses, 8 have high school students, all of which are equipped with a chemistrylab. Despite being privileged when it comes to infrastructure, Colégio Pedro II also faceschallenges. For example, the school has plenty of laboratory glassware, but no reagents. Ofthe reagents it does have, 2 tons are out-of-date and there is no money to discard themproperly – or to buy new ones. As teachers wait for the money, they try to keep the labsworking by borrowing materials from other federal institutions.As of 2017, Colégio Pedro II plans to have at least one laboratory activity per month forevery high school class. To achieve that, the school is surveying campuses demands andfinancial resources. Gomes believes that it is crucial that Colégio Pedro II forms strong tiesto the Brazilian Green Chemistry School, in order to bring sustainable practices and low costmaterials into their teaching. He wants to begin this approach by presenting this white paperto the Head of Colégio Pedro II’s Chemistry Department and to the school’s Dean.

122.2.2 Chemistry education in Belém, Pará(Presented by Jesus Brabo, Federal University of Pará)Belém is the capital of Pará (a state in the north Brazil) and was founded in 1616. It is nowhome to 1.4 million inhabitants. The city is criss-crossed by rivers and includes 39 islands.Belém is a mixture of modern apartment blocks, forestry conservation areas and poorneighbourhoods – with wooden houses and no sanitation, contrasting with modern areas(see Attachment 1).The city has 60,000 high school students, in 168 schools with each class having between 34and 40 students each. All of these students require chemistry education and are a potentialtarget for green chemistry activities. However, most classrooms are not properly equipped –they have school desks and white boards, but no books, no charts, no labs (seeAttachment 2)In regular schools students go to school either in the morning or afternoon (i.e. there are twoshifts of students per day) for a total of 20hours per week2. In these schools teachers reportschool dropout, student disinterest, and gaps of basic knowledge as the main difficulties. Asmany students come from low-income families, some of them end up leaving school to get ajob. Others leave because school is “too hard”. They have, for instance, math gaps thatmake learning chemistry a lot harder. Teachers report extra-curricular activities, such asvisits to local universities and industries, as useful tools to improve chemistry learning.Alongside the regular schools, Belém has three new public “integral” (full time) schools,where students go to school for the whole day (40 hours/week) with classroom teachingaugmented by workshops, laboratory practices and other activities. Teachers thatparticipated in the GII workshop criticized the fact that these schools often focus onpreparing students for the ENEM (Brazilian national high school evaluation) rather thanfocusing on a broader education. However, they also mentioned a project called “Químicadas sensações” (Chemistry of the sensations) where students learn to produce soaps,lotions, disinfectants, perfumes, candies and other products – an interdisciplinary programwith a clear focus on entrepreneurship.These “integral” schools, according to the teachers, have good results, and most studentsare able to join universities afterwards. Nevertheless, they also face challenges: lack of2In Brazil, during basic education, students are required to be inside the classroom for at least 800 hours peryear (there are 200 school days/year). Usually public schools have two shifts of students (morning/afternoon)from Monday to Friday.

13didactic and financial resources is one of them. A teacher exemplified this by explaining that,although her school was supposed to offer lunch for the students so they can stay all day, itoften does not have money to afford it, so sometimes students have to go home by midday.A teacher from the state of Amazonas, also in Northern Brazil, reported that “integral”schools in their region have good infrastructure but lack qualified human resources. Andtheir results are not better than regular schools outputs: since students go to school full time,they do not have time to take extra courses to prepare themselves for the ENEM3.Prof. Brabo added Belém is building new “integral” schools with recently establishedinfrastructure standards (including classrooms for 30 students each, laboratories etc.) whichwill be open by the start of the 2017 school year. One of the main challenges will be toestablish guidelines and legislation on the special activities those schools will have to offer(nowadays each school makes its own decisions about this).The teachers working environment also appeared as a major issue when it comes toimproving education in Brazil. Low salaries and fragile working contracts were mentioned.Also, in regular schools, teachers are paid for the time spent in classrooms, but not for thehours they spend outside classrooms preparing activities, tests and so on. Additionally,teachers are not interested in taking post-graduate courses because that would not increasetheir salaries so there is little opportunity or incentive to teachers to continue their ownprofessional development.According to Brabo, the Federal Institute of Pará, with 1,000 students, offers the bestchemistry education experience in Belém. It offers technical high school education, regularhigh school education and teaching education. Infrastructure is satisfactory and there are 17chemistry teachers, most of whom hold masters or PhD degrees.2.2.3 Brazilian Chemistry Olympiads(Presented by Luis Carlos Gomes, Colégio Pedro II)For the past 21 years, Brazil has held national and local editions of Chemistry Olympics. Theevent involves public and private high schools throughout the country and in 2016 had3The ENEM started in 1998 as a way of evaluating Brazilian high schools. Since then, some universities beganusing students’ individual ENEM scores to select undergraduate candidates. Later all federal universities inBrazil – and part of state universities and private ones – started using ENEM scores to rank candidates. That ledsome students to take extra preparatory courses outside school in order to improve their performance in theENEM.

14340,000 participants. The Brazilian Chemistry Olympics (BCO) have been playing animportant role on improving chemistry education. To engage students, the BCO approach aspecial topic each year, combining with the National Science & Technology Week (in 2016,the theme was “Science feeding Brazil”).Many schools have altered their chemistry curriculum in order to prepare their students toparticipate on the Olympics and achieve high scores in the exams. Other added extrachemistry classes, given by preservice chemistry teachers (undergraduate chemistrystudents received a scholarship to take part on the project).Consequently, BCO have brought thousands of high school students more close tochemistry and gathered interested teachers and school principals together with BCO’sorganizational team. Since 2015, the Olympics include a practical test, which has been anincentive to experimental practices in the schools, following the principles of greenchemistry, even in schools that are not equipped with a laboratory. Green chemistry is alsoan important topic of the theoretical tests, teasing an important shift on chemistry educationin high schools.The BCO team also offers special Olympics for younger students and participates on theorganization of the Brazilian Science Olympics, which cover both chemistry and physicstopics. Besides the National Olympics, each state organizes local editions. Brazilian studentsalso participate on the International Chemistry Olympics with good results – last year, thefour p

In the 2010’s, green chemistry was included for the first time in the program of the chemistry weeks that happen yearly in universities and schools across Brazil. The initiative started with the National Science & Technology Week 2011, coinciding with the International Year for Chemistry, which theme was “Chemistry for a better world”.