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SAFETY DATA SHEET:ODORLESS MINERAL SPIRITSIN CASE OF TRANSPORTATION EMERGENCY CONTACT:CHEMTREC:(800) 424-9300----------------------ALL OTHER INQUIRIES:(770) 904-7042 // www.ciscochem.com266 Rue Cezzan Lavonia, GA 305531. IDENTIFICATIONOdorless Mineral SpiritsCAS # 68551-19-92. HAZARDS IDENTIFICATIONClassification of the substance or mixtureThis product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labelscontain all the information as required by the standard.Emergency OverviewDangerForm: LiquidPhysical state: LiquidColor: Colorless at room temperatureOdor: Mild, HydrocarbonOSHA Hazards : Combustible Liquid, Aspiration hazardClassificationFlammable liquids , Category 4Aspiration hazard , Category 1Signal word:DangerHazard Statements:Combustible liquidMay be fatal if swallowed and enters airwaysPrecautionary Statements:Prevention:Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/ eye protection/ face protection.Response:SDS: ODORLESS MINERALSPIRITSPage: 1
IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting.In case of a fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.Storage: Store in a well-ventilated place, keep cool. Store locked upDisposal: Dispose of contents/container to an approved waste disposal plant.Carcinogenicity:IARC:No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed humancarcinogen by IARC.NTP:No ingredient of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen byNTP.ACGIH:No ingredient of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen byACGIH.3. COMPOSITIONSynonyms :IsoalkanesIsoparaffinsAliphatic hydrocarbonMolecular formula :UVCBCOMPONENTC12-C14 IsoalkanesCAS #68551-19-9WEIGHT %100%4. FIRST AID MEASURESGENERAL ADVICE:Move out of dangerous area. Show this material safety data sheet to the doctor in attendance. Material may produce a serious,potentially fatal pneumonia if swallowed or vomited.IF INHALED:If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician.IN CASE OF SKIN CONTACT:If on skin, rinse well with water. If on clothes, remove clothes.IN CASE OF EYE CONTACT:Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eyeirritation persists, consult a specialist.IF SWALLOWED:Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Takevictim immediately to hospital.5. FIRE FIGHTING MEASURESFlash point61 C (142 F)Method Tag closed cupAutoignition temperature230 C (446 F)SDS: ODORLESS MINERALSPIRITSPage: 2
Suitable extinguishing mediaAlcohol-resistant foam. Carbon Dioxide (Co2) Dry ChemicalUnsuitable extinguishing mediaHigh volume water jetSpecial protective equipment for fire-fightersWear self-contained breathing apparatus for firefighting if necessaryFurther informationFor safety reasons in case of fire, cans should be stored separatelyin closed containments. Use a water spray to cool fully closedcontainers.Fire and explosion protectionDo not spray on an open flame or any other incandescent material.Keep away from open flames, hot surfaces and sources of ignitionHazardous decomposition productsCarbon Dioxides6. ACCIDENTAL RELEASE MEASURESPersonal precautions :Use personal protective equipment. Ensure adequate ventilation.Environmental precautions :Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakesor drains inform respective authorities.Methods for cleaning up :Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth,vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closedcontainers for disposal.7. HANDLING AND STORAGEHandlingAdvice on safe handlingAvoid formation of aerosol. Do not breathe vapors/dust. For personal protection see section 8. Smoking, eating and drinking shouldbe prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water inaccordance with local and national regulations.Advice on protection against fire and explosionDo not spray on an open flame or any other incandescent material. Keep away from open flames, hot surfaces and sources ofignition.StorageRequirements for storage areas and containersNo smoking. Keep container tightly closed in a dry and well- ventilated place. Observe label precautions. Electrical installations /working materials must comply with the technological safety standards.8. EXPOSURE CONTROLS AND PERSONAL PROECTIONIngredients with workplace control parametersIngedientsC12-C14 IsoalkanesValueTWAControl parameters1,200 mg/m3NoteRCPRCP Reciprocal Calculation ProcedureEngineering measuresAdequate ventilation to control airborned concentrations below the exposure guidelines/limits. Consider the potential hazards of thisSDS: ODORLESS MINERALSPIRITSPage: 3
material (see Section 2), applicable exposure limits, job activities, and other substances in the work place when designingengineering controls and selecting personal protective equipment. If engineering controls or work practices are not adequate toprevent exposure to harmful levels of this material, the personal protective equipment listed below is recommended. The user shouldread and understand all instructions and limitations supplied with the equipment since protection is usually provided for a limitedtime or under certain circumstances.Personal protective equipmentRespiratory protectionWear a supplied-air NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimaloxygen content of 19.5% by volume under normal atmospheric pressure. Wear a NIOSH approved respirator that providesprotection when working with this material if exposure to harmful levels of airborne material may occur, such as:. Air-PurifyingRespirator for Organic Vapors. Use a positive pressure, air-supplying respirator if there is potential for uncontrolled release,exposure levels are not known, or other circumstances where air-purifying respirators may not provide adequate protection.Hand ProtectionThe suitability for a specific workplace should be discussed with the producers of the protective gloves. Please observe theinstructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take intoconsideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.Eye ProtectionEye wash bottle with pure water. Tightly fitting safety goggles.Skin and body protectionChoose body protection according to the amount and concentration of the dangerous substance at the work place. Wear asappropriate:. Flame-resistant clothing. Footwear protecting against chemicals.Hygiene measuresWhen using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.9. PHYSICAL AND CHEMICAL PROPERTIESInformation on basic physical and chemical propertiesAppearanceFormLiquidPhysical StateLiquidColorColorless at room temperatureOdorMild, hydrocarbonSAFETY DATAFlash Point61 C (142 F)Method: Tag closed cupLower explosion limit0.68% (V)Upper explosion limit5.4% (V)Oxidizing propertiesnoSDS: ODORLESS MINERALSPIRITSPage: 4
Autoignition temperature230 C (446 F)Thermal decompositionno data availableMolecular formulaUVCBMolecular weightNot applicablepH7pour pointno data availableBoiling/Point & range179 - 210 C (354 - 410 F)Vapor pressure2.60 MMHG @ 38 C (100 F)Relative density0.76, 15.6 C (60.1 F)Water SolubilitynegligiblePartition coefficient:n-octanol/waterNo data availableViscosity, kinematic1.5 cSt @ 38 C (100 F)Relative vapor density3 (Air 1.0)Evaporation rate1Percent volatile 99%10. STABILITY AND REACTIVITYChemical stability : This material is considered stable under normal ambient and anticipated storage and handling conditions oftemperature and pressure.Possibility of hazardous reactionsConditions to avoidHeat, flames and sparksMaterials to avoidmay react with oxygen and strong oxidizing agents, such aschlorates, nitrates, peroxides, etc.Thermal decompositionNo data availableHazardous decomposition productsCarbon oxidesOther dataNo decomposition if stored and applied as directed11. TOXICOLOGICAL INFORMATIONAcute oral toxicityC12-C14 IsoalkanesLD50: 5000 milligram per kilogramSpecies: ratSDS: ODORLESS MINERALSPIRITSPage: 5
Method: OECD Test Guideline 401Information given is based on data obtained from similar substances.Acute inhalation toxicityC12-C14 IsoalkanesLC50: 5.3milligram per literExposure time: 4 hSpecies: ratTest atmosphere: vaporMethod: OECD Test Guideline 403Information given is based on data obtained from similar substances.Skin irritationC12-C14 IsoalkanesNo skin irritationInformation given is based on data obtained from similar substances.Eye irritationC12-C14 IsoalkanesNo eye irritationInformation given is based on data obtained from similar substances.SensitizationC12-C14 IsoalkanesClassification: Did not cause sensitization on laboratory animals.Information given is based on data obtained from similar substances.Repeated dose toxicityC12-C14 IsoalkanesSpecies: MonkeyApplication Route: InhalationDose: 0, 654 ppmExposure time: 4 wkNumber of exposures: 6 h/d, 3 d/wk NOEL: 654 ppmMethod: OECD Test Guideline 412Species: rat, male and female Sex: male and female Application Route: oral gavage Dose: 0, 25, 150, 1000 mg/kg/d Exposure time:4 wkNumber of exposures: dailyNOEL: 1000 mg/kg/dMethod: OECD Guideline 422Information given is based on data obtained from similar substances.Reproductive toxicityC12-C14 IsoalkanesSpecies: ratSex: maleApplication Route: oral gavageDose: 0, 750, 1500, 3000 mg/kg/bw/dNumber of exposures: dailyTest period: 90 dMethod: OECD Test Guideline 415NOAEL Parent: 3000 mg/kg/bw/dInformation given is based on data obtained from similar substances.Species: ratSex: femaleApplication Route: oral gavageDose: 0, 750, 1500 mg/kg/bw/dNumber of exposures: dailyTest period: 90 dMethod: OECD Test Guideline 415NOAEL Parent: 1500 mg/kg/bw/dSDS: ODORLESS MINERALSPIRITSPage: 6
NOAEL F1: 750 mg/kg/bw/dInformation given is based on data obtained from similar substances.Species: ratSex: male and femaleApplication Route: inhalation (vapor)Dose: 100, 300 ppmNumber of exposures: 6 h/d/5d/wkTest period: 8 wkMethod: OECD Guideline 421NOAEL Parent: 300 ppmNOAEL F1: 300 ppmInformation given is based on data obtained from similar substances.Developmental ToxicityC12-C14 IsoalkanesSpecies: ratApplication Route: InhalationDose: 100, 300 ppmExposure time: GD 6-15Number of exposures: 6 h/dNOAEL Teratogenicity: 300 ppmInformation given is based on data obtained from similar substances.Species: ratApplication Route: InhalationDose: 300, 900 ppmExposure time: GD 6-15Number of exposures: 6 h/dMethod: OECD Guideline 414NOAEL Teratogenicity: 900 ppmNOAEL Maternal: 900 ppmInformation given is based on data obtained from similar substances.Species: ratApplication Route: oral gavageDose: 0, 500, 1000, 1500 mg/kg/dExposure time: GD 6-15Number of exposures: DailyMethod: OECD Guideline 414NOAEL Teratogenicity: 1,000 mg/kgNOAEL Maternal: 500 mg/kgInformation given is based on data obtained from similar substances.Aspiration toxicityC12-C14 IsoalkanesMay be fatal if swallowed and enters airways.CMR effectsC12-C14 IsoalkanesCarcinogenicity: Limited evidence of carcinogenicity in animal studiesMutagenicity: Tests on bacterial or mammalian cell cultures did not show mutagenic effects., In vivo tests did not show mutageniceffectsTeratogenicity: Animal testing did not show any effects on fetal development.Reproductive toxicity: No adverse effects expectedIsoparaffin Solvent my degrease the skinSDS: ODORLESS MINERALSPIRITSPage: 7
12. ECOLOGICAL INFORMATIONTOXICITY TO FISHC12-C14 IsoalkanesLL50: 1,000 mg/lExposure time: 96 hSpecies: Oncorhynchus mykiss (rainbow trout) semi-static test Method: OECD Test Guideline 203 Information given is based ondata obtained from similar substances.TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATESC12-C14 IsoalkanesEL50: 1,000 mg/lExposure time: 48 hSpecies: Daphnia magna (Water flea)static test Method: OECD Test Guideline 202 Information given is based on data obtained from similar substances.Toxicity to algaeC12-C14 IsoalkanesEL50: 1,000 mg/lExposure time: 72 hSpecies: Pseudokirchneriella subcapitata (green algae) Growth inhibition Method: OECD Test Guideline 201 Information given isbased on data obtained from similar substances.Toxicity to fish (Chronic toxicity)C12-C14 IsoalkanesNOELR: 0.316 mg/l Exposure time: 28 dSpecies: Oncorhynchus mykiss (rainbow trout) Method: QSAR modeled dataBiodegradabilityC12-C14 Isoalkanesaerobic 31 %Testing period: 28 dMethod: OECD Test Guideline 301FInformation given is based on data obtained from similar substances.Expected to be inherently biodegradable.Results of PBT assessmentC12-C14 IsoalkanesNon-classified PBT substance, Non-classified vPvB substanceAdditional ecological informationC12-C14 IsoalkanesThis material is not expected to be harmful to aquaticorganisms.13. DISPOSAL CONSIDERATIONSThe information in this SDS pertains only to the product as shipped.Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of ahazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certainphysical properties and analysis for regulated components may be necessary to make a correct determination. If this material isclassified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility.ProductDo not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to aSDS: ODORLESS MINERALSPIRITSPage: 8
licensed waste management company.Contaminated packaging:Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, theempty drum.14. TRANSPORT INFORMATIONThe shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (seeregulatory definition).Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additionalshipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agreewith the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the SDS and thebill of lading.US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCY.Testing (ASTM D4206) has shown product does not sustain combustion.IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS)NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCYIATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION)NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCY.ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCY.RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS (EUROPE))NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCY.ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BYINLAND WATERWAYS)NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THISAGENCY.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code15. REGULATORY INFORMATIONNational legislationSARA 311/312 HazardsFire HazardCERCLA ReportableQuantityThis material does not contain any componenets with a CERCLA RQSARA 302 ReportableQuantityThis material does not contain any components with a SARA 302 RQSARA 302 ThresholdPlanning QuantitySARA 302: No chemicals in this material are subject tot he reporting requirementsof SARA Title III, Section 302SARA 3024 ReportableThis material does not contain any components with a section #) EHS RQSDS: ODORLESS MINERALSPIRITSPage: 9
QuantitySARA 313 IngredientsSARA 313: This material does not contain any chemical components with knownCAS numbers that exceed the threshold (De Minimis) reporting levels establishedby SARA Title III, Section 313Clean Air ActOzone-Depletion PotentialThis product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section602 (40 CFR 82, Subpt. A, App.A B).This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61).This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention(40 CFR 68.130, Subpart F).This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's(40 CFR 60.489).US State RegulationsPennsylvania Right To KnowNo components are subject to the Pennsylvania Right to Know Act.New Jersey Right to KnowNo components are subject to the New Jersey Right to Know ActCalifornia Prop 65 IngredientsThis product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductivedefects.Notification statusEurope REACHUnited States of America TSCACanada DSLAustralia AICSNewZealand NZIoCJapan ENCSKorea KECIPhilippines PICCSChina IECSCOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryNot in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventory16. OTHER INFORMATIONNFPA ClassificationHealth Hazard: 1 Fire Hazard: 1Further informationLegacy SDS NumberReactivity Hazard: 029020Significant changes since the last version are highlighted in the margin. This version replaces all previous versions.The information in this SDS pertains only to the product as shipped.The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at thedate of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,SDS: ODORLESS MINERALSPIRITSPage: 10
transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only tothe specific material designated and may not be valid for such material used in combination with any other materials or in anyprocess, unless specified in the text.KEY OR LEGEND TO ABBREVIATIONS USED IN THE SDSACGIH AMERICAN CONFERENCE OF GOVERNMENTINDUSTRIAL HYGIENISTSLD50AICSLOAEL LOWEST OBSERVED ADVERSEEFFECT LEVELAUSTRIALIA, INVENTORY OF CHEMICAL SUBSTANCESLETHAL DOSE 50%DSLCANADA, DOMESTIC SUBSTANCES LISTAGENCYNFPA NATIONAL FIRE PROTECTIONNDSL CANADA, NON-DOMESTIC SUBSTANCES LISTOCCUPATIONALNIOSH NATIONAL INSTITUTE FORSAFETY & HEALTHCNSCENTRAL NERVOUS SYSTEMNTPNATIONAL TOXICOLOGY PROGRAMCASCHEMICAL ABSTRACT SERVCIENZioC NEW ZEALAND INVENTORY OFCHEMICALSEC50EFFECTIVE CONCENTRATIONNOAEL NO OBSERVABLE ADVERSE EFFECT LEVELEC50EFFECTIVE CONCENTRATION 50%NOEC NO OBSERVED EFFECT CONCENTRATIONEGEST EOSCA GENERIC EXPOSURE SCENARIO TOOLOSHA OCCUPATIONAL SAFETY & HEALTHADMINISTRATIONEOSCA EUROPEAN OILFIELD SPECIALTY CHEMICALSASSOCPELEINECS EUROPEAN INVENTORY OF EXISTING CHEMICALSUBSTANCESPERMISSIBLE EXPOSURE LIMITPICCS PHILIPPINES INVENTORY OF COMMERCIALCHEMICAL SUBSTANCESMAKGERMANY MAXIMUM CONCENTRATION VALUESPRNTGHSACTGLOBALLY HARMONIZED SYSTEMRCRA RESOURCE CONSERVATION RECOVERY GREATER THAN OR EQUAL TOSTELIC50INHIBITION CONCENTRATION 50%SARA SUPERFUND AMENDMENTS ANDREAUTHORIZATION ACTIARCINTERNATIONAL AGENCY FOR RESEARCH ONTLVCANCERIECSC INVENTORY OF EXISTING CHEMICAL SUBSTANCESIN CHINATWAENCSKECIJAPAN, INVENTORY OF EXISTING AND NEWCHEMICALSUBSTANCESKOREA, EXISTING CHEMICAL INVENTORYSDS: ODORLESS MINERALSPIRITSTSCAPRESUMED NOT TOXICSHORT-TERM EXPOSURE LIMITTHRESHOLD LIMIT VALUETIME WEIGHTED AVERAGETOXIC SUBSTANCE CONTROL ACTUVCB UNKNOWN OR VARIABLE COMPOSITIONCOMPLEX REACTION PRODUCTS ANDBIOLOGICAL MATERIALSPage: 11
LESS THAN OR EQUAL TOLC50LETHAN CONCENTRATION 50%WHMIS WORKPLACE HAZARDOUS MATERIALSINFORMATION SYSTEMDate Created: 4/28/2015Date Updated: 2/5/2016SDS: ODORLESS MINERALSPIRITSPage: 12
ODORLESS MINERAL SPIRITS 1. IDENTIFICATION Odorless Mineral Spirits CAS # 68551-19-9 2. HAZARDS IDENTIFICATION Classification of the substance or mixture This product has been classified in accordance with the hazard communication standard 29 CFR 1910.1200; the SDS and labels contain all the information as required by the standard. Emergency .
