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DPNS/DOE QS 013:2017ICS xxxxxxxPetroleum products – CME-blended industrial diesel oil - Specification
PHILIPPINE NATIONAL STANDARDDPNS/DOE QS 013:2017ForewordThis Philippine National Standard PNS/DOE QS 013:2017, Specification for CMEblended industrial diesel oil was prepared by the Department of Energy throughthe Technical Committee on Petroleum Products and Additives (DOE/TCPPA)and was approved for adoption as Philippine National Standard by the Bureau ofPhilippine Standards .This standard was made in line with the DOE’s policy and program of updating thefuel quality specification of CME-blended industrial diesel oil in terms of currentrequirement of the industry, its users and manufacturers and also by endeavoringto harmonize internationally/regional environmental standards for fuels.This standard is an update/review of PNS/DOE QS 004:2012 with revision madeto come up with a separate PNS for industrial diesel oil distinct from the PNS forautomotive diesel oil and updating of test method.Further, this is consistent with the continuing program of the government towardsthe use of cleaner fuels and promoting the use of indigenous and renewableenergy resources with the end view of reducing dependence on imported oil.This standard cancels and replaces PNS/DOE QS 004:2012.This entire standard is subject for review and/or revision when necessary.
PHILIPPINE NATIONAL STANDARDDPNS/DOE QS 013:2017Petroleum products – CME-blended industrial diesel oil – Specification1ScopeThis standard specifies the requirements for CME-blended diesel oil suitable forvarious types of industrial diesel engines.2ReferencesThe titles of the standard publications referred to in this standard are listed on theinside back cover.3DefinitionsFor the purpose of this standard, the following definitions apply:3.1base diesel oilrefers to diesel oil that shall be blended with CME to produce CME-blended dieseloil.3.2CMErefers to coconut methyl ester (CME), also defined as fatty acid methyl esters(FAME) derived from coconut oil whose alkyl groups range in varying percentagesfrom C8 to C18 suitable for compression ignition engines and other similar types ofengines.3.3diesel oilrefers to refined petroleum distillates, which may contain small amount ofhydrocarbon or non-hydrocarbon additives to improve ignition qualities or othercharacteristics, suitable for compression ignition engines and other suitable types ofengines.3.4CME-blended diesel oilsrefers to diesel oils blended with CME3.5Industrial diesel oil (IDO)refers to diesel oil used for off-road vehicles, marine vessels, direct equipment suchas pumps and compressors, and stationary equipment such as power generators,boilers and furnaces.2
DPNS/DOE QS 013: 20174RequirementsCME-blended industrial diesel oil shall conform to the chemical and physicalrequirements specified in Table 1.Annex 1 provides minimum reference specification for base diesel oilTable 1 – Chemical and physical requirements for CME-blended industrial diesel oilPropertyLimitsCarbon residue on 10%Distillation residue, % mass, max.0.35Conradson orRamsbottoms orMicroa1.7 – 2.2CME , content, % vol.Color, ASTM, min.5.0.Copper strip corrosion, 3 h at 50 C, max.No.1Density at 15 C, kg/L, max.0.880Distillation, 90% recovered, C, max.ReportFlash point, Pensky-Marten, C, min.551.7 – 5.5Kinematic viscosity, mm²/s at 40 CMethyl laurate (C12 ME), % mass, min.0.8Sulfur, %mass, max.0.30Water and sediment, % volume, max.0.10aTest MethodsAs per latest PNS/DOE QS 002 for B1003PNS ASTM D 189 orPNS ASTM D 524 orPNS ASTM D 4530EN 14078 orPNS/DOE TM 01 orPNS/DOE TM 02 orPNS ASTM D7371 orPNS ASTM D7806PNS ASTM D 1500PNS ASTM D 130 orPNS ISO 2160PNS ASTM D 1298 orPNS ASTM D 4052 orPNS ASTM D 7777PNS ASTM D 86PNS ASTM D 93PNS ASTM D 445PNS ASTM D 7042PNS/DOE TM 01PNS ASTM D 4294 orPNS ASTM D 2622 orPNS ASTM D5453PNS ASTM D7039PNS ASTM D 2709
DPNS/DOE QS 013: 20176SamplingCME-blended industrial diesel oil shall be sampled in accordance with PNS ASTM D4057.7Test methodsCME-blended industrial diesel oil shall be tested in accordance with the methodsspecified in Table 1.4
DPNS/DOE QS 013: 2017Annex 1 – Minimum reference specification for base diesel oilPropertyCarbon residue on 10%distillation residue, % mass, max.IDO0.35Conradson orRamsbottoms orMicroColor, ASTM, minTest MethodsPNS ASTM D 189 orPNS ASTM D 524 orPNS ASTM D 45305.0PNS ASTM D 1500Copper strip corrosion 3 h at50 C, max.No.1Density at 15 C, kg/L, max.0.880PNS ASTM D 1298 orPNS ASTM D 4052 orPNS ASTM D 7777Distillation, 90% recovered, C, max.ReportPNS ASTM D 86Flash point, Pensky-Marten, C, min.55PNS ASTM D 931.7 – 5.5PNS ASTM D 445Kinematic viscosity, mm²/s at 40 CPNS ASTM D 130 orPNS ISO 2160Sulfur, %mass, max.0.30PNS ASTM D 4294 orPNS ASTM D 2622 orPNS ASTM D5453 orPNS ASTM D7039Water and sediment, % volume, max.0.10PNS ASTM D 2709
DPNS/DOE QS 013:2017References:The following referenced documents are indispensable for the application of thisdocument. For dated references, only the edition cited applies. For undatedreferences, the latest edition of the referenced document (including anyamendments) applies.PNS ASTM D86:2016a (ASTM published 201 ) Standard Test Method forDistillation of Petroleum Products and Liquid Fuels at Atmospheric PressurePNS ASTM D93:2016a (ASTM published 201 ) Standard Test Methods for FlashPoint by Pensky-Martens Closed Cup TesterPNS ASTM D130:2015 (ASTM published 201 ) Standard Test Method forCorrosiveness to Copper from Petroleum Products by Copper Strip TestPNS ASTM D189:2006 (2014) (ASTM published 2006 reapproved 201 ) StandardTest Method for Conradson Carbon Residue of Petroleum ProductsPNS ASTM D445:2015a (ASTM published 201 ) Standard Test Method forKinematic Viscosity of Transparent and Opaque Liquids (and Calculation ofDynamic Viscosity)PNS ASTM D524:2015 (ASTM published 201 ) Standard Test Method forRamsbottom Carbon Residue of Petroleum ProductsPNS ASTM D1298:2012b (ASTM published 201 ) Standard Test Method forDensity, Relative Density, or API Gravity of Crude Petroleum and Liquid PetroleumProducts by Hydrometer MethodPNS ASTM D1500:2012 (ASTM published 201 ) Standard Test Method for ASTMColor of Petroleum Products (ASTM Color Scale)PNS ASTM D2622:2016 (ASTM published 201 ) Standard Test Method for Sulfurin Petroleum Products by Wavelength Dispersive X-ray Fluorescence SpectrometryPNS ASTM D2709:2019 (ASTM published 1996 reapproved 201 ) Standard TestMethod for Water and Sediment in Middle Distillate Fuels by CentrifugePNS ASTM D4052:2015 (ASTM published 201 ) Standard Test Method forDensity, Relative Density, and API Gravity of Liquids by Digital Density MeterPNS ASTM D4057:2012 (ASTM published 2012) Standard Practice for ManualSampling of Petroleum and Petroleum ProductsPNS ASTM D4294:2016e1 (ASTM published 201 ) Standard Test Method forSulfur in Petroleum and Petroleum Products by Energy Dispersive X-rayFluorescence SpectrometryPNS ASTM D 4530:2015 (ASTM published 201 ) Standard Test Method forDetermination of Carbon Residue (Micro Method)PNS ASTM D5453:2016e1 (ASTM published 201 ) Standard Test Method forDetermination of Total Sulfur in Light Hydrocarbons, Spark Ignition Engine Fuel,Diesel Engine Fuel, and Engine Oil by Ultraviolet Fluorescence
DPNS/DOE QS 013:2017PNS ASTM D7039:2015a (ASTM published 201 ) Standard Test Method for Sulfurin Gasoline, Diesel Fuel, Jet Fuel, Kerosine, Biodiesel, Biodiesel Blends, andGasoline-Ethanol Blends by Monochromatic Wavelength Dispersive X-rayFluorescence SpectrometryPNS ASTM D7042:2016e3 (ASTM published 201 ) Standard Test Method forDynamic Viscosity and Density of Liquids by Stabinger Viscometer (and theCalculation of Kinematic Viscosity)PNS ASTM D7371:2014 (ASTM published 201 ) Standard Test Method forDetermination of Biodiesel (Fatty Acid Methyl Esters) Content in Diesel Fuel OilUsing Mid Infrared Spectroscopy (FTIR-ATR-PLS Method)PNS ASTM D7777-13 (ASTM published 201 ) Standard Test Method for Density,Relative Density, or API Gravity of Liquid Petroleum by Portable Digital DensityMeterPNS ASTM D7806:2013 (ASTM published 201 ) Standard Test Method forDetermination of the Fatty Acid Methyl Ester (FAME) Content of a Blend ofBiodiesel and Petroleum-Based Diesel Fuel Oil Using Mid-Infrared SpectroscopyPNS ISO 2160:2012 (ISO published 1998) Petroleum Products – Corrosiveness toCopper – Copper Strip TestEN 14078:2003 (modified), Liquid Petroleum Products – Determination of FattyAcid Methyl Ester (FAME) Content in Middle Distillates – Infrared SpectrometryMethodPNS/DOE TM 01:2015 – Determination of Ester and Lauric Acid Content in FattyAcid Methyl Esters (FAME) by Gas ChromatographyPNS//DOE TM 02:2009 - Separation of Fatty Acid Methyl Esters (FAME) fromFAME-Blended Diesel Oil by Liquid Adsorption Chromatography andCharacterization by Gas ChromatographyAbbreviationsPNS-Philippine National StandardASTM-American Society for Testing and MaterialsISO-International Standard OrganizationEN-Euro Norm (Regional Standard of European Countries)
Department of EnergyTechnical Committee on Petroleum Products and AdditivesChairpersons1Melita V. ObilloAlvin David T. Lim*Ricardo S. Infante*Department of Energy2Jean N. RoseteEdwin Romel Navaluna*Department of Environment andNatural ResourcesMembersPetroleum Manufacturers Sector:NGO/Consumer Sector:3Ronald Q. ChiongCristina Banogon*Petron Corporation11 Alexander P. LoinazFilipino Car Foundation/Coalition of Clean Air (CCA)4Stephen CruzJaime T. Diago*Pilipinas Shell Petroleum Corp.12 Edgardo G. AlabastroAir and Waste Management AssociationAcademe Sector:Petroleum Marketers Sector:5Ronald DagumanChevron (Phils.), Inc.6Bernadette RaymundoTanya Samillano*Independent Philippine PetroleumCompanies Association (IPPCA)7Heidi SaleraEmmanuel Monsalud*Total Phils. Corporation13 Rafael F. DiazFlorello C. Galindo*Asian Institute of Petroleum Studies, Inc.14 Karl N. VergelUniversity of the Philippines, NationalCenter for Transportation StudiesGovernment Agencies:15 Amelia M. de GuzmanVirginia S. Llamo*Energy Research & Testing LaboratoryServices, DOEEnd-Users:Car Manufacturers Sector:8Benjie DionelaPaul Agustin*Chamber of Automotive Manufacturerof the Phils., Inc.16 Myra MagabilinBureau of Philippine Standards, DTI17 Hermelina H. BionCorazon G. Magpantay*Industrial Technology DevelopmentInstitute, DOSTMotorcycle Sector:Invitees:918 Mario M. MarasiganRenewable Energy Management Bureau,DOEMagnus MateoDexter Espinaz*Motorcycle Development ProgramParticipants Association Inc.Agricultural Machineries Sector:10 Joel PanagsaganChris C. Rubiano*Agricultural Machinery Manufacturersand Distributors Association19 Whitman L. Uy-MatiaoPrivate Sector20 Willy ToledoPrivate Sector21 Joselito MagalonaJetti Petroleum Inc.SecretariatOil Industry Standards & Monitoring Division,Oil Industry Management BureauDepartment of Energy* Alternate
2 PHILIPPINE NATIONAL STANDARD DPNS/DOE QS 013:2017 Petroleum products - CME-blended industrial diesel oil - Specification 1 Scope This standard specifies the requirements for CME-blended diesel oil suitable for
